Impact of wettability alteration on two‐phase flow characteristics of sandstones: A quasi‐static description

[1] We describe a two-phase pore network simulator of drainage and imbibition which integrates a realistic representation of pore connectivity and morphology, a quasi-static description of fluid displacement mechanisms, and a sound representation of the wetting properties of a sedimentary rock and of their alteration. The simulator works with 3-D disordered networks of cylindrical ducts with triangular, square, and circular cross sections obtained directly from the analysis of microfocused computed tomography (CT) images of rock samples. All pore-level displacement mechanisms (piston type, snap off, and cooperative pore body filling) are considered with arbitrary receding and advancing contact angles. Bond invasion percolation description is used in primary drainage, while bond site invasion percolation with ordinary percolation on a dual network and compact cluster growth is used in secondary imbibition. In this paper, we resolve how to calculate the relative permeability of nonaqueous phase liquid (NAPL) in the quasi-static approximation of imbibition and illustrate spatial distribution of the clusters of trapped NAPL using our generalization to disordered networks of the Hoshen-Kopelman cluster-labeling algorithm. To understand the impact of wettability alteration on the capillary pressure and relative permeability functions, we perform a series of drainage and imbibition simulations by changing the range of advancing contact angles. Our study indicates that in imbibition, transport properties of a permeable solid are quite sensitive to the hysteresis between the receding and advancing contact angle. This sensitivity reflects competition among the different displacement mechanisms, which shapes the relative permeabilities, capillary pressures, and the distribution of the trapped NAPL.

[1]  M. Blunt Flow in porous media — pore-network models and multiphase flow , 2001 .

[2]  Martin J. Blunt,et al.  Effects of Heterogeneity and Wetting on Relative Permeability Using Pore Level Modeling , 1997 .

[3]  Shouxiang Ma,et al.  Effect of contact angle on drainage and imbibition in regular polygonal tubes , 1996 .

[4]  X. Jing,et al.  Pore Network Modelling of Electrical Resistivity and Capillary Pressure Characteristics , 2000 .

[5]  Tadeusz W Patzek,et al.  Verification of a Complete Pore Network Simulator of Drainage and Imbibition , 2001 .

[6]  M. Blunt Physically-based network modeling of multiphase flow in intermediate-wet porous media , 1998 .

[7]  Coen J. Ritsema,et al.  How water moves in a water repellent sandy soil: 1. Potential and actual water repellency , 1994 .

[8]  J. Bear Dynamics of Fluids in Porous Media , 1975 .

[9]  Sally J. Marshall,et al.  The X-ray tomographic microscope: Three-dimensional perspectives of evolving microstructures , 1994 .

[10]  F. Dullien,et al.  1 – Pore Structure , 1992 .

[11]  Morrel H. Cohen,et al.  Quantitative methods for microgeometric modeling , 1982 .

[12]  Michael A. Celia,et al.  A Functional Relationship Between Capillary Pressure, Saturation, and Interfacial Area as Revealed by a Pore‐Scale Network Model , 1996 .

[13]  M. Sahimi Flow phenomena in rocks : from continuum models to fractals, percolation, cellular automata, and simulated annealing , 1993 .

[14]  Robert E. Tarjan,et al.  Finding Minimum Spanning Trees , 1976, SIAM J. Comput..

[15]  N. Morrow,et al.  Effect of Crude-Oil-Induced Wettability Changes on Oil Recovery , 1986 .

[16]  Tadeusz W Patzek,et al.  Extension of Hoshen–Kopelman algorithm to non-lattice environments , 2003 .

[17]  O. I. Yordanov,et al.  Classification of radar signatures by autoregressive model fitting and cluster analysis , 1989 .

[18]  F. Dullien Porous Media: Fluid Transport and Pore Structure , 1979 .

[19]  Tadeusz W Patzek,et al.  Shape Factor Correlations of Hydraulic Conductance in Noncircular Capillaries. , 2001, Journal of colloid and interface science.

[20]  Rosana G. Moreira,et al.  Spatial distribution of oil after deep-fat frying of tortilla chips from a stochastic model , 1996 .

[21]  Steven Robert McDougall,et al.  The impact of wettability on waterflooding: Pore-scale simulation , 1995 .

[22]  T. Patzek,et al.  Shape Factor and Hydraulic Conductance in Noncircular Capillaries. , 2001, Journal of colloid and interface science.

[23]  D. Or,et al.  Adsorption and capillary condensation in porous media: Liquid retention and interfacial configurations in angular pores , 1999 .

[24]  J. Mariani,et al.  Transient synaptic redundancy in the developing cerebellum and isostatic random stacking of hard spheres , 1996, Biological Cybernetics.

[25]  D. Wilkinson,et al.  Percolation with trapping , 1986 .

[26]  Cass T. Miller,et al.  Pore‐Scale Modeling of Nonwetting‐Phase Residual in Porous Media , 1995 .

[27]  Martin J. Blunt,et al.  Three-dimensional modeling of three phase imbibition and drainage , 1998 .

[28]  R. Salathiel Oil Recovery by Surface Film Drainage In Mixed-Wettability Rocks , 1973 .

[29]  I. Fatt The Network Model of Porous Media , 1956 .

[30]  Stig Bakke,et al.  Petrophysical laboratory measurements for basin and reservoir evaluation , 1996 .

[31]  S. Powers,et al.  Wettability of porous media after exposure to synthetic gasolines , 1995 .

[32]  Martin J. Blunt,et al.  Development of a pore network simulation model to study nonaqueous phase liquid dissolution , 2000 .

[33]  P. Spanne,et al.  Computed microtomography of reservoir core samples , 1995 .

[34]  Avery H. Demond,et al.  Effect of cationic surfactants on organic liquid-water capillary pressure-saturation relationships , 1994 .

[35]  Simulation of catalyst fouling at the particle and reactor levels , 1996 .

[36]  Raoul Kopelman,et al.  Percolation and cluster distribution. I. Cluster multiple labeling technique and critical concentration algorithm , 1976 .

[37]  W. Anderson Wettability Literature Survey- Part 1: Rock/Oil/Brine Interactions and the Effects of Core Handling on Wettability , 1986 .

[38]  T. W. Patzek,et al.  Regular ArticleShape Factor and Hydraulic Conductance in Noncircular Capillaries: I. One-Phase Creeping Flow , 2001 .

[39]  T. Patzek,et al.  Three-Phase Hydraulic Conductances in Angular Capillaries , 2003 .

[40]  Martin J. Blunt,et al.  Relative permeabilities from two- and three-dimensional pore-scale network modelling , 1991 .

[41]  W. V. Pinczewski,et al.  Invasion Percolation on Correlated and Elongated Lattices: Implications for the Interpretation of Residual Saturations in Rock Cores , 2001 .

[42]  Anthony R. Kovscek,et al.  A pore-level scenario for the development of mixed-wettability in oil reservoirs , 1993 .

[43]  N. Wardlaw,et al.  The influence of wettability and critical pore-throat size ratio on snap—off , 1986 .

[44]  Roland Lenormand,et al.  Role Of Roughness And Edges During Imbibition In Square Capillaries , 1984 .

[45]  Arthur W. Rose,et al.  Porous media: Fluid transport and pore structure (2nd Ed.) , 1993 .

[46]  S. Powers,et al.  Wettability of NAPL-Contaminated Sands , 1996 .

[47]  David Wilkinson,et al.  Invasion percolation: a new form of percolation theory , 1983 .

[48]  R. P. Mayer,et al.  Mercury porosimetry—breakthrough pressure for penetration between packed spheres , 1965 .

[49]  J. Buckley,et al.  Wetting Alteration by Brine and Crude Oil: From Contact Angles to Cores , 1996 .

[50]  Norman R. Morrow,et al.  The Effects of Surface Roughness On Contact: Angle With Special Reference to Petroleum Recovery , 1975 .

[51]  M. Blunt Pore Level Modeling of the Effects of Wettability , 1997 .

[52]  G. Hirasaki Wettability: Fundamentals and Surface Forces , 1991 .

[53]  R. Lenormand,et al.  Mechanisms of the displacement of one fluid by another in a network of capillary ducts , 1983, Journal of Fluid Mechanics.

[54]  L. Scriven,et al.  Effect of Wettability on Two-Phase Relative Permeabilities and Capillary Pressures , 1983 .

[55]  Joseph Hoshen,et al.  Percolation and cluster distribution. III. Algorithms for the site-bond problem , 1979 .

[56]  K. Sorbie,et al.  Pore-Scale Modeling of Wettability Effects and Their Influence on Oil Recovery , 1999 .

[57]  Martin J. Blunt,et al.  Effects of wettability on three-phase flow in porous media , 2000 .

[58]  J. Hoshen Percolation analog for a two-component liquid-vapor system , 1980 .

[59]  Randy D. Hazlett,et al.  Simulation of capillary-dominated displacements in microtomographic images of reservoir rocks , 1995 .

[60]  J. Buckley,et al.  Some mechanisms of crude oil/brine/solid interactions , 1998 .

[61]  Stig Bakke,et al.  Extending Predictive Capabilities to Network Models , 1998 .

[62]  R. Lenormand Pattern growth and fluid displacements through porous media , 1986 .