High efficiency dye-sensitized nanocrystalline solar cells based on ionic liquid polymer gel electrolyte.

An ionic liquid polymer gel containing 1-methyl-3-propylimidazolium iodide (MPII) and poly(vinylidenefluoride-co-hexafluoropropylene) (PVDF-HFP) has been employed as quasi-solid-state electrolyte in dye-sensitized nanocrystalline TiO2 solar cells with an overall conversion efficiency of 5.3% at AM 1.5 illumination.

[1]  J. Fuller,et al.  Ionic liquid–polymer gel electrolytes from hydrophilic and hydrophobic ionic liquids , 1998 .

[2]  R. Sheldon Catalytic reactions in ionic liquids. , 2001, Chemical communications.

[3]  Michael J. Zaworotko,et al.  Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids , 1992 .

[4]  Claudia Barolo,et al.  Design, synthesis, and application of amphiphilic ruthenium polypyridyl photosensitizers in solar cells based on nanocrystalline TiO2 films , 2002 .

[5]  Howells,et al.  Diffusion of redox probes in hydrated sol-gel-derived glasses , 2000, Analytical chemistry.

[6]  A. Bard,et al.  Integrated chemical systems: photocatalysis at titanium dioxide incorporated into Nafion and clay , 1985 .

[7]  H. Dahms Electronic conduction in aqueous solution , 1968 .

[8]  I. Ruff,et al.  Transfer diffusion. I. Theoretical , 1971 .

[9]  Wei-Min Zhang,et al.  Diffusion and concentration of molecular probes in thermoresponsive poly(N-isopropylacrylamide) hydrogels: effect of the volume phase transition. , 2002, Analytical chemistry.

[10]  L. Kavan,et al.  Nafion modified TiO2 electrodes: photoresponse and sensitization by Ru(II)-bipyridyl complexes , 1989 .

[11]  Josef Salbeck,et al.  Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies , 1998, Nature.

[12]  G. Denuault,et al.  Direct determination of diffusion coefficients by chronoamperometry at microdisk electrodes , 1991 .

[13]  Elias Stathatos,et al.  A High-Performance Solid-State Dye-Sensitized Photoelectrochemical Cell Employing a Nanocomposite Gel Electrolyte Made by the Sol–Gel Route , 2002 .

[14]  Daniel T. Schwartz,et al.  Large Enhancement in Photocurrent Efficiency Caused by UV Illumination of the Dye-Sensitized Heterojunction TiO2/RuLL‘NCS/CuSCN: Initiation and Potential Mechanisms , 1998 .

[15]  H. Pettersson,et al.  The Performance and Stability of Ambient Temperature Molten Salts for Solar Cell Applications , 1996 .

[16]  Takayuki Kitamura,et al.  Quasi-solid-state dye-sensitized solar cells using room temperature molten salts and a low molecular weight gelator. , 2002, Chemical communications.

[17]  M. Grätzel,et al.  Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts. , 1996, Inorganic chemistry.

[18]  M. Dissanayake,et al.  Dye-sensitised photoelectrochemical solar cells with polyacrylonitrile based solid polymer electrolytes , 2002 .

[19]  Photoinduced oxidation of bromide to bromine on irradiated platinized titanium dioxide powders and platinized titanium dioxide particles supported on Nafion films , 1986 .

[20]  Tetsuya Tsuda,et al.  The Application of Room Temperature Molten Salt with Low Viscosity to the Electrolyte for Dye-Sensitized Solar Cell , 2001 .

[21]  P. Wasserscheid,et al.  Ionic Liquids-New "Solutions" for Transition Metal Catalysis. , 2000, Angewandte Chemie.

[22]  J. Fuller,et al.  Ionic liquid–polymer gel catalytic membrane , 1997 .

[23]  R. Murray,et al.  An ionic liquid form of DNA: redox-active molten salts of nucleic acids. , 2001, Journal of the American Chemical Society.

[24]  M. Grätzel Photoelectrochemical cells : Materials for clean energy , 2001 .

[25]  P. Falaras,et al.  A solvent-free composite polymer/inorganic oxide electrolyte for high efficiency solid-state dye-sensitized solar cells , 2002 .

[26]  J. Fuller,et al.  Ionic Liquid‐Polymer Gel Electrolytes , 1997 .