A biphenylene-bridged dinuclear constrained geometry titanium complex for ethylene and ethylene/1-octene polymerizations

[1]  Thi Dieu Huyen Nguyen,et al.  Bridge length effect of new dinuclear constrained geometry catalysts on controlling the polymerization behaviors of ethylene/styrene copolymerization , 2011 .

[2]  H. Yun,et al.  Preparation of half-metallocenes of thiophene-fused and tetrahydroquinoline-linked cyclopentadienyl ligands for ethylene/α-olefin copolymerization. , 2010, Dalton transactions.

[3]  I. Fragalà,et al.  Proximity and cooperativity effects in binuclear d(0) olefin polymerization catalysis. theoretical analysis of structure and reaction mechanism. , 2009, Journal of the American Chemical Society.

[4]  T. Marks,et al.  Bimetallic effects in homopolymerization of styrene and copolymerization of ethylene and styrenic comonomers: scope, kinetics, and mechanism. , 2008, Journal of the American Chemical Society.

[5]  H. Yun,et al.  Ortho Lithiation of Tetrahydroquinoline Derivatives and Its Use for the Facile Construction of Polymerization Catalysts , 2007 .

[6]  B. Lee,et al.  Bimetallic phenylene-bridged Cp/amide titanium complexes and their olefin polymerization. , 2007, Dalton transactions.

[7]  W. Lyoo,et al.  Copolymerization of ethylene and norbornene via polymethylene bridged dinuclear constrained geometry catalysts , 2007 .

[8]  T. Marks,et al.  Alkenylsilane structure effects on mononuclear and binuclear organotitanium-mediated ethylene polymerization: scope and mechanism of simultaneous polyolefin branch and functional group introduction. , 2007, Journal of the American Chemical Society.

[9]  Sungjin Park,et al.  Dinuclear Metallocenes with a Modulated Biphenylene Bridge for Olefin Polymerization , 2007 .

[10]  H. Braunschweig,et al.  Constrained geometry complexes—Synthesis and applications , 2006 .

[11]  S. Kang,et al.  Phenylene-Bridged Cp/Carboxamide Ligands for Titanium Complexes of Various Binding Modes and Their Ethylene/1-Octene Copolymerization , 2006 .

[12]  D. Joe,et al.  o-Phenylene-bridged Cp/sulfonamido titanium complexes for ethylene/1-octene copolymerization. , 2006, Dalton transactions.

[13]  S. Kang,et al.  o-Phenylene-Bridged Cp/Amido Titanium Complexes for Ethylene/1-Hexene Copolymerizations , 2006 .

[14]  T. Marks,et al.  Significant Proximity and Cocatalyst Effects in Binuclear Catalysis for Olefin Polymerization , 2005 .

[15]  T. Marks,et al.  Coordination copolymerization of severely encumbered isoalkenes with ethylene: enhanced enchainment mediated by binuclear catalysts and cocatalysts. , 2005, Journal of the American Chemical Society.

[16]  G. Coates,et al.  Synthesis of Allyl-Terminated Syndiotactic Polypropylene: Macromonomers for the Synthesis of Branched Polyolefins , 2005 .

[17]  M. H. Lee,et al.  Biphenylene-bridged dinuclear group 4 metal complexes : Enhanced polymerization properties in olefin polymerization , 2005 .

[18]  Stephen A. Miller,et al.  A sterically expanded "constrained geometry catalyst" for highly active olefin polymerization and copolymerization: an unyielding comonomer effect. , 2004, Journal of the American Chemical Society.

[19]  T. Marks,et al.  Covalently Linked Heterobimetallic Catalysts for Olefin Polymerization , 2004 .

[20]  T. Marks,et al.  Polynuclear olefin polymerization catalysis: proximity and cocatalyst effects lead to significantly increased polyethylene molecular weight and comonomer enchainment levels. , 2004, Angewandte Chemie.

[21]  T. Marks,et al.  Bimetallic catalysis for styrene homopolymerization and ethylene-styrene copolymerization. Exceptional comonomer selectivity and insertion regiochemistry. , 2004, Journal of the American Chemical Society.

[22]  W. Lyoo,et al.  Studies of ethylene-styrene copolymerization with dinuclear constrained geometry complexes with methyl substitution at the five-membered ring in indenyl of [Ti(η5 :η1-C9H5SiMe2NCMe3)]2 [CH2]n , 2004 .

[23]  W. Lyoo,et al.  Investigation of ethylene and styrene copolymerization initiated with dinuclear constrained geometry catalysts holding polymethylene as a bridging ligand and indenyl as a cyclopentadienyl derivative , 2003 .

[24]  T. Marks,et al.  Catalyst/cocatalyst nuclearity effects in single-site olefin polymerization. Significantly enhanced 1-octene and isobutene comonomer enchainment in ethylene polymerizations mediated by binuclear catalysts and cocatalysts. , 2003, Journal of the American Chemical Society.

[25]  J. Mano,et al.  (R=alkyl or aryl) complexes as catalysts for ethylene polymerization , 2003 .

[26]  S. Noh,et al.  Syntheses of dinuclear titanium constrained geometry complexes with polymethylene bridges and their copolymerization properties , 2003 .

[27]  V. C. Gibson,et al.  Advances in non-metallocene olefin polymerization catalysis. , 2003, Chemical reviews.

[28]  T. Marks,et al.  Catalyst/cocatalyst nuclearity effects in single-site polymerization. Enhanced polyethylene branching and alpha-olefin comonomer enchainment in polymerizations mediated by binuclear catalysts and cocatalysts via a new enchainment pathway. , 2002, Journal of the American Chemical Society.

[29]  P. Rinaldi,et al.  Poly(ethylene-co-1-octene) Characterization by High-Temperature Multidimensional NMR at 750 MHz , 2001 .

[30]  K. Abboud,et al.  Heteroatom-Substituted Constrained-Geometry Complexes. Dramatic Substituent Effect on Catalyst Efficiency and Polymer Molecular Weight , 2001 .

[31]  I. Císařová,et al.  Synthesis and Crystal Structures of Dimethylsilylene-Bridged (Amidocyclopentadienyl)dichlorotitanium(IV) Complexes with Various Substituents on the Cyclopentadienyl Ligand , 2001 .

[32]  W. J. Kruper,et al.  Materials properties derived from INSITE metallocene catalysts , 2000 .

[33]  R. Mülhaupt,et al.  Short and long chain branching of polyethene prepared by means of ethene copolymerization with 1‐eicosene using MAO activated Me2Si(Me4Cp)(NtBu)TiCl2 , 2000 .

[34]  Shiping Zhu,et al.  Continuous solution copolymerization of ethylene and octene‐1 with constrained geometry metallocene catalyst , 1999 .

[35]  Shiping Zhu,et al.  Kinetics of Long Chain Branching in Continuous Solution Polymerization of Ethylene Using Constrained Geometry Metallocene , 1998 .

[36]  R. Waymouth,et al.  Group 4 ansa-Cyclopentadienyl-Amido Catalysts for Olefin Polymerization. , 1998, Chemical reviews.

[37]  Xu,et al.  Ethylene Copolymerization with 1-Octene Using a 2-Methylbenz , 1998, Macromolecules.

[38]  R. Waymouth,et al.  Ethylene-propylene copolymerization with 2-arylindene zirconocenes , 1998 .

[39]  A. Hiltner,et al.  Classification of homogeneous ethylene‐octene copolymers based on comonomer content , 1996 .

[40]  W. Schaefer,et al.  Model Ziegler-Natta .alpha.-Olefin Polymerization Catalysts Derived from[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}(PMe3)Sc(.mu.2-H)]2 and[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}Sc(.mu.2-CH2CH2CH3)]2. Synthesis, Structures, and Kinetic and Equilibrium Investigations of the Catalytically Active Species in Solut , 1994 .

[41]  J. Chien,et al.  Ethylene–hexene copolymerization by heterogeneous and homogeneous Ziegler–Natta catalysts and the “comonomer” effect , 1993 .

[42]  J. C. Randall A REVIEW OF HIGH RESOLUTION LIQUID 13CARBON NUCLEAR MAGNETIC RESONANCE CHARACTERIZATIONS OF ETHYLENE-BASED POLYMERS , 1989 .