An overview: Energy saving and pollution reduction by using green fuel blends in diesel engines

The diesel engine offers superior fuel and thermal efficiencies, greater power output, superior torque and better durability compared to the spark ignition engine. On the other hand, the diesel engine is a major source of both criteria and non-criteria air pollutants, which contribute to the deteriorating air quality further putting the health of mankind at risk. Thus, there is a need to find sustainable and environmental friendly fuel types for the diesel engine application. Therefore, in this review, we embark on a discourse on the application of oxygenated alternative fuels such as biodiesel, acetone–butanol–ethanol (ABE) solution and water-addition as green fuel reformulation strategies aimed at achieving engine pollutant reduction, while maintaining the integrity of the energy performance of the diesel engine. Furthermore, more research and study is recommended on these green fuels to gain more insight on their effect especially on the unregulated vehicle emissions such as polycyclic aromatic hydrocarbons (PAHs), persistent organic compounds (POPs) and carbonyls. Compared with conventional fossil diesel, by using the biodiesel and/or ABE solution in the diesel blends do reduce the emissions of particulate matter (PM), CO, PAHs and POPs, while in the most cases, the NOx emission will be increased. However, due to the combination mechanisms of higher oxygen content, more complete combustion and cooling effect, if the diesel blend contains proper amount of biodiesel, ABE solution and a small amount of water (0.5%), it is a green fuel, which displays a excellent performance in both brake thermal efficiency (BTE) and NOx–PM trade-off and in significant emission reductions for PAHs and POPs, while, the emissions of both carbon monoxide (CO) and hydrocarbons (HCs) may elevated and therefore a diesel oxidation catalyst (DOC) is needed. This review article proposes a green diesel fuel blend not only for scientific study but also for future practical application.

[1]  A. Khasnis,et al.  Global warming and infectious disease. , 2005, Archives of medical research.

[2]  C. Yuan,et al.  Reducing carbonyl emissions from a heavy-duty diesel engine at US transient cycle test by use of paraffinic/biodiesel blends , 2009 .

[3]  M. Lapuerta,et al.  Effect of soot accumulation in a diesel particle filter on the combustion process and gaseous emissions , 2012 .

[4]  A. Tsolakis,et al.  Engine performance and emissions of a diesel engine operating on diesel-RME (rapeseed methyl ester) blends with EGR (exhaust gas recirculation) , 2007 .

[5]  Bing Liu,et al.  Combustion and emissions of a DI diesel engine fuelled with diesel-oxygenate blends , 2008 .

[6]  Ye Sun,et al.  Hydrolysis of lignocellulosic materials for ethanol production: a review. , 2002, Bioresource technology.

[7]  Ayhan Demirbas,et al.  Progress and recent trends in biofuels , 2007 .

[8]  B. Cheirsilp,et al.  Development of Acetone Butanol Ethanol (ABE) Production from Palm Pressed Fiber by Mixed Culture of Clostridium sp. and Bacillus sp. , 2011 .

[9]  E. Torres,et al.  Carbonyl compounds emitted by a diesel engine fuelled with diesel and biodiesel–diesel blends: Sampling optimization and emissions profile , 2008 .

[10]  Ali M.A. Attia,et al.  Influence of the structure of water-in-fuel emulsion on diesel engine performance , 2014 .

[11]  Shunsuke Mori,et al.  CCS, Nuclear Power and Biomass An Assessment of Option Triangle under Global Warming Mitigation Policy by an Integrated Assessment Model MARIA-23 , 2013 .

[12]  Sayon Sidibe,et al.  Use of crude filtered vegetable oil as a fuel in diesel engines state of the art: Literature review , 2010 .

[13]  G. Subbaiah,et al.  The Effect of Biodiesel and Bioethanol Blended Diesel Fuel on the Performance and Emission Characteristics of a Direct Injection Diesel Engine , 2010 .

[14]  Cherng-Yuan Lin,et al.  An oxygenating additive for improving the performance and emission characteristics of marine diesel engines , 2003 .

[15]  Wen-Jhy Lee,et al.  Characteristics of polycyclic aromatic hydrocarbon (PAH) emissions from a UH-1H helicopter engine and its impact on the ambient environment , 2006 .

[16]  A. Rashid A. Aziz,et al.  Water-in-diesel emulsion and its micro-explosion phenomenon-review , 2011, 2011 IEEE 3rd International Conference on Communication Software and Networks.

[17]  Ingemar Denbratt,et al.  Low Soot, Low NOx in a Heavy Duty Diesel Engine Using High Levels of EGR , 2005 .

[18]  N. Qureshi,et al.  Production of acetone-butanol-ethanol from concentrated substrates using Clostridium acetobutylicum in an integrated fermentation-product removal process , 1995 .

[19]  S. Schneider,et al.  Climate Change 2007 Synthesis report , 2008 .

[20]  Hsi-Hsien Yang,et al.  Effects of ethanol-blended gasoline on emissions of regulated air pollutants and carbonyls from motorcycles , 2012 .

[21]  Erik Dahlquist,et al.  Biodiesel production from waste cooking oil catalyzed by TiO2-MgO mixed oxides. , 2010, Bioresource technology.

[22]  C. Papastefanou Chapter 1 Atmospheric aerosol particles , 2008 .

[23]  Karthik Nithyanandan,et al.  Impacts of acetone on the spray combustion of Acetone–Butanol–Ethanol (ABE)-Diesel blends under low ambient temperature , 2015 .

[24]  C. B. Chen,et al.  Effect of fuel aromatic content on PAH emission from a heavy-duty diesel engine. , 2000, Chemosphere.

[25]  Wei Liu,et al.  Fighting global warming by climate engineering: Is the Earth radiation management and the solar radiation management any option for fighting climate change? , 2014 .

[26]  T. Mahlia,et al.  Biodiesel Production from Macro Algae as a Green Fuel for Diesel Engine , 2010 .

[27]  John Kennedy Mwangi,et al.  Emission Reductions of Nitrogen Oxides, Particulate Matter and Polycyclic Aromatic Hydrocarbons by Using Microalgae Biodiesel, Butanol and Water in Diesel Engine , 2015 .

[28]  Choongsik Bae,et al.  Joonsik Hwang, Donghui Qi, Yongjin Jung, Choongsik Bae, Effect of Injection Parameters on the Combustion and Emission Characteristics in a Compression Ignition Engine Fuelled with Waste Cooking Oil Biodiesel , 2013 .

[29]  Avinash Kumar Agarwal,et al.  Wear assessment in a biodiesel fueled compression ignition engine , 2003 .

[30]  Mingfa Yao,et al.  Development of an n-heptane-n-butanol-PAH mechanism and its application for combustion and soot prediction , 2013 .

[31]  R. D. Misra,et al.  Straight vegetable oils usage in a compression ignition engine-A review , 2010 .

[32]  Hüseyin Serdar Yücesu,et al.  The potential of using vegetable oil fuels as fuel for diesel engines , 2001 .

[33]  Yuan-Chung Lin,et al.  Saving energy and reducing emissions of both polycyclic aromatic hydrocarbons and particulate matter by adding bio-solution to emulsified diesel. , 2006, Environmental science & technology.

[34]  Michael Taylor,et al.  An overview of second generation biofuel technologies. , 2010, Bioresource technology.

[35]  C. Webb,et al.  Fuel Sulfur Effects on a Medium-Duty Diesel Pick-Up with a NOx Adsorber, Diesel Particle Filter Emissions Control System: 2000-Hour Aging Results , 2006 .

[36]  Mohamed Y. E. Selim,et al.  Stability Behavior of Water-in-Diesel Fuel Emulsion , 2009 .

[37]  Guo-Ping Chang-Chien,et al.  Emissions of Polychlorinated Dibenzo-p-dioxin and Polychlorinated Dibenzofuran from Motorcycles , 2010 .

[38]  Brandon T. Tompkins,et al.  Low Temperature Heat Release of Palm and Soy Biodiesel in Late Injection Low Temperature Combustion , 2014 .

[39]  Kyle Benalil,et al.  Effect of biodiesel–butanol fuel blends on emissions and performance characteristics of a diesel engine , 2014 .

[40]  Mingfa Yao,et al.  Diesel Engine Combustion Control: Medium or Heavy EGR? , 2010 .

[41]  P. Bonsack,et al.  PCDD/F formation in an iron/potassium-catalyzed diesel particle filter. , 2013, Environmental science & technology.

[42]  Willem P. Nel,et al.  IMPLICATIONS OF FOSSIL FUEL CONSTRAINTS ON ECONOMIC GROWTH AND GLOBAL WARMING , 2009 .

[43]  Peilin Cen,et al.  Artificial symbiosis for acetone-butanol-ethanol (ABE) fermentation from alkali extracted deshelled corn cobs by co-culture of Clostridium beijerinckii and Clostridium cellulovorans , 2014, Microbial Cell Factories.

[44]  C. Lee,et al.  Reduction in emissions of nitrogen oxides, particulate matter, and polycyclic aromatic hydrocarbon by adding water-containing butanol into a diesel-fueled engine generator , 2012 .

[45]  M. Shehata Cylinder pressure, performance parameters, heat release, specific heats ratio and duration of combustion for spark ignition engine , 2010 .

[46]  M. Morita,et al.  PCDDs and PCDFs in vehicle exhaust particles in Japan. , 1999, Chemosphere.

[47]  T. Berntsen,et al.  Global temperature change from the transport sectors: Historical development and future scenarios , 2009 .

[48]  Yu-Cheng Chang,et al.  Green energy: Water-containing acetone–butanol–ethanol diesel blends fueled in diesel engines , 2013 .

[49]  Kuo-Hsiang Hsu,et al.  Emissions of Regulated Pollutants and PAHs from Waste-cooking-oil Biodiesel-fuelled Heavy-duty Diesel Engine with Catalyzer , 2012 .

[50]  Marc Chesney,et al.  The impact of possible climate catastrophes on global warming policy , 2003 .

[51]  Y. Mu,et al.  Carbonyls emission from ethanol-blended gasoline and biodiesel-ethanol-diesel used in engines , 2008 .

[52]  M. Abu-Zaid,et al.  Performance of single cylinder, direct injection Diesel engine using water fuel emulsions , 2004 .

[53]  V. Grigoriadis,et al.  Emissions of PCDDs and PCDFs in gasoline and diesel fueled cars , 1990 .

[54]  L. Turrio-Baldassarri,et al.  Occurrence of PCDD/Fs in urban air before and after the ban of leaded gasoline. , 2005, Chemosphere.

[55]  Wen-Yinn Lin,et al.  PM, carbon, and PAH emissions from a diesel generator fuelled with soy-biodiesel blends. , 2010, Journal of hazardous materials.

[56]  Poh Seng Lee,et al.  Experimental investigation of the performance and emission characteristics of direct injection diesel engine by water emulsion diesel under varying engine load condition , 2013 .

[57]  Marcelo A. Savi,et al.  Analysis of the global warming dynamics from temperature time series. , 2010 .

[58]  Ekrem Buyukkaya,et al.  Effects of biodiesel on a DI diesel engine performance, emission and combustion characteristics , 2010 .

[59]  Anthony Leiserowitz,et al.  Who remembers a hot summer or a cold winter? The asymmetric effect of beliefs about global warming on perceptions of local climate conditions in the U.S. , 2013 .

[60]  Lilian L. N. Guarieiro,et al.  Emission profile of 18 carbonyl compounds, CO, CO2, and NOx emitted by a diesel engine fuelled with diesel and ternary blends containing diesel, ethanol and biodiesel or vegetable oils , 2009 .

[61]  Talal Yusaf,et al.  Chlorella protothecoides Microalgae as an Alternative Fuel for Tractor Diesel Engines , 2013 .

[62]  Stuart J Day,et al.  Effects of vehicle type and fuel quality on real world toxic emissions from diesel vehicles , 2008 .

[63]  Diana López,et al.  Production and utilization performance of a glycerol derived additive for diesel engines , 2012 .

[64]  Chonglin Song,et al.  Influence of ethanol-diesel blended fuels on diesel exhaust emissions and mutagenic and genotoxic activities of particulate extracts. , 2007, Journal of hazardous materials.

[65]  Ming Huo,et al.  Low temperature spray combustion of acetone–butanol–ethanol (ABE) and diesel blends , 2014 .

[66]  O. Doğan The influence of n-butanol/diesel fuel blends utilization on a small diesel engine performance and emissions , 2011 .

[67]  Barbara Zielinska,et al.  Atmospheric transformation of diesel emissions. , 2005, Research report.

[68]  Dagobert Kessel,et al.  Global warming — facts, assessment, countermeasures , 2000 .

[69]  Roy Radner,et al.  A Strategic Analysis of Global Warming: Theory and Some Numbers , 2005 .

[70]  Jongtae Lee,et al.  Evaluation of regulated and unregulated emissions from a diesel powered vehicle fueled with diesel/biodiesel blends in Korea , 2014 .

[71]  Jinyue Yan,et al.  Energy from algae: Current status and future trends: Algal biofuels – A status report , 2011 .

[72]  Richard J. Brown,et al.  Combustion analysis of microalgae methyl ester in a common rail direct injection diesel engine , 2015 .

[73]  Ming Zheng,et al.  Fuel Efficiency Improvements of Low Temperature Combustion Diesel Engines , 2008 .

[74]  Juan J. Hernández,et al.  Speciation of the semivolatile hydrocarbon engine emissions from sunflower biodiesel , 2008 .

[75]  Robert L. McCormick,et al.  Regulated and Unregulated Exhaust Emissions Comparison for Three Tier II Non-Road Diesel Engines Operating on Ethanol- Diesel Blends , 2005 .

[76]  Yu Zhang,et al.  Impact of biodiesel on NOx emissions in a common rail direct injection diesel engine , 2007 .

[77]  M. Cheng,et al.  Reducing emissions of persistent organic pollutants from a diesel engine by fueling with water-containing butanol diesel blends. , 2014, Environmental science & technology.

[78]  C. Muraleedharan,et al.  Use of vegetable oils as I.C. engine fuels—A review , 2004 .

[79]  Octavio Armas,et al.  Effect of biodiesel fuels on diesel engine emissions , 2008 .

[80]  C. D. Rakopoulos,et al.  Combustion heat release analysis of ethanol or n-butanol diesel fuel blends in heavy-duty DI diesel engine , 2011 .

[81]  Mike Sutton,et al.  Investigations on the effect of chlorine in lubricating oil and the presence of a diesel oxidation catalyst on PCDD/F releases from an internal combustion engine. , 2007, Chemosphere.

[82]  Jinyue Yan,et al.  Catalytic Biodiesel Production , 2013 .

[83]  Ying Li,et al.  Isolation of a novel alkaline-stable lipase from a metagenomic library and its specific application for milkfat flavor production , 2014, Microbial Cell Factories.

[84]  Avinash Kumar Agarwal,et al.  Effect of Biodiesel Utilization of Wear of Vital Parts in Compression Ignition Engine , 2003 .

[85]  Ahmad Muhsin Ithnin,et al.  An overview of utilizing water-in-diesel emulsion fuel in diesel engine and its potential research study , 2014 .

[86]  Wen-Jhy Lee,et al.  Energy Savings and Emission Reduction of Nitrogen Oxides, Particulate Matter, and Polycyclic Aromatic Hydrocarbons by Adding Water-Containing Acetone and Neat Soybean Oil to a Diesel-Fueled Engine Generator , 2010 .

[87]  S. Suranovic,et al.  Fossil fuel addiction and the implications for climate change policy , 2013 .

[88]  C. D. Rakopoulos,et al.  Effects of butanol–diesel fuel blends on the performance and emissions of a high-speed DI diesel engine , 2010 .

[89]  Shing Tet Leong,et al.  Applicability of gasoline containing ethanol as Thailand's alternative fuel to curb toxic VOC pollutants from automobile emission , 2002 .

[90]  Ezio Mancaruso,et al.  Ethanol effect as premixed fuel in dual-fuel CI engines: Experimental and numerical investigations , 2014 .

[91]  Kadir Aydin,et al.  Effect of diesel–microalgae biodiesel–butanol blends on performance and emissions of diesel engine , 2014 .

[92]  H. Raheman,et al.  Performance of a diesel engine with blends of biodiesel (from a mixture of oils) and high-speed diesel , 2013 .

[93]  K. Subramanian A comparison of water–diesel emulsion and timed injection of water into the intake manifold of a diesel engine for simultaneous control of NO and smoke emissions , 2011 .

[94]  Yifang Zhu,et al.  Study of ultrafine particles near a major highway with heavy-duty diesel traffic , 2002 .

[95]  P. Claassen,et al.  Acetone, butanol and ethanol production from domestic organic waste by solventogenic clostridia. , 2000, Journal of molecular microbiology and biotechnology.

[96]  A. Ulrich,et al.  Secondary Emissions Risk Assessment of Diesel Particulate Traps for Heavy Duty Applications , 2005 .

[97]  Guo-Ping Chang-Chien,et al.  Reduction of Toxic Pollutants Emitted from Heavy-duty Diesel Vehicles by Deploying Diesel Particulate Filters , 2011 .

[98]  Carlo Beatrice,et al.  Mixture of glycerol ethers as diesel bio-derivable oxy-fuel: Impact on combustion and emissions of an automotive engine combustion system , 2014 .

[99]  Tie Li,et al.  Characteristics of Smokeless Low Temperature Diesel Combustion in Various Fuel-Air Mixing and Expansion of Operating Load Range , 2009 .

[100]  Yousef Haik,et al.  Combustion of algae oil methyl ester in an indirect injection diesel engine , 2011 .

[101]  William Cannella,et al.  Boosted HCCI Combustion Using Low-Octane Gasoline with Fully Premixed and Partially Stratified Charges , 2012 .

[102]  Ming Huo,et al.  A Preliminary Investigation of the Performance and Emissions of a Port-Fuel Injected SI Engine Fueled with Acetone-Butanol-Ethanol (ABE) and Gasoline , 2014 .

[103]  Choongsik Bae,et al.  Operating Range of Low Temperature Diesel Combustion with Supercharging , 2009 .

[104]  Niraj S. Topare,et al.  Biodiesel from Algae Oil as an Alternative Fuel for Diesel Engine , 2011 .

[105]  Ming Huo,et al.  Study on the spray and combustion characteristics of water–emulsified diesel , 2014 .

[106]  Jan Czerwinski,et al.  Secondary effects of catalytic diesel particulate filters: copper-induced formation of PCDD/Fs. , 2007, Environmental science & technology.

[107]  K. Akihama,et al.  Mechanism of the Smokeless Rich Diesel Combustion by Reducing Temperature , 2001 .

[108]  John Kennedy Mwangi,et al.  Microalgae Oil: Algae Cultivation and Harvest, Algae Residue Torrefaction and Diesel Engine Emissions Tests , 2015 .

[109]  Stefan Hausberger,et al.  Road vehicle emission factors development: A review , 2013 .

[110]  G. Nagarajan,et al.  Effect of injection pressure on heat release rate and emissions in CI engine using orange skin powder diesel solution , 2009 .

[111]  T. Lin,et al.  Effect of the gasoline additives on PAH emission. , 1998, Chemosphere.

[112]  Michael F. J. Brunt,et al.  Calculation of Heat Release in Direct Injection Diesel Engines , 1999 .

[113]  Shui-Jen Chen,et al.  Emission reduction of NOx, PM, PM-carbon, and PAHs from a generator fuelled by biodieselhols. , 2014, Journal of hazardous materials.

[114]  Avinash Kumar Agarwal,et al.  Experimental investigations of the effect of biodiesel utilization on lubricating oil tribology in diesel engines , 2005 .

[115]  M. Elsener,et al.  Urea-SCR: a promising technique to reduce NOx emissions from automotive diesel engines , 2000 .

[116]  G. Labeckas,et al.  THE EFFECT OF RAPESEED OIL METHYL ESTER ON DIRECT INJECTION DIESEL ENGINE PERFORMANCE AND EXHAUST EMISSIONS , 2006 .

[117]  Shui-Jen Chen,et al.  Gas/Particle Partitioning of Dioxins in Exhaust Gases from Automobiles , 2010 .

[118]  Barbara Zielinska,et al.  Polycyclic aromatic hydrocarbon exhaust emissions from different reformulated diesel fuels and engine operating conditions. , 2009 .

[119]  Chao He,et al.  Comparison of carbonyl compounds emissions from diesel engine fueled with biodiesel and diesel , 2009 .

[120]  Hiroshi Yamasaki,et al.  Recent advances in the combustion of water fuel emulsion , 2002 .

[121]  Athanasios Tsolakis,et al.  Diesel emissions improvements through the use of biodiesel or oxygenated blending components , 2012 .

[122]  John D. Spengler,et al.  Using advanced dispersion models and mobile monitoring to characterize spatial patterns of ultrafine particles in an urban area , 2011 .

[123]  Susan T. Bagley,et al.  A Study of the Effects of Exhaust Gas Recirculation on Heavy-Duty Diesel Engine Emissions , 1998 .

[124]  Zuohua Huang,et al.  Diesel engine gaseous and particle emissions fueled with diesel-oxygenate blends , 2012 .

[125]  Shijin Shuai,et al.  Characteristics of carbonyl compounds emission from a diesel-engine using biodiesel–ethanol–diesel as fuel , 2006 .

[126]  Moo Been Chang,et al.  Formation and removal of PCDD/Fs in a municipal waste incinerator during different operating periods. , 2007, Chemosphere.

[127]  Ali Alahmer,et al.  Influence of using emulsified diesel fuel on the performance and pollutants emitted from diesel engine , 2013 .

[128]  Rolf Egnell,et al.  The Influence of EGR on Heat Release Rate and NO Formation in a DI Diesel Engine , 2000 .

[129]  Timothy V. Johnson,et al.  Review of diesel emissions and control , 2009 .

[130]  Gang Lv,et al.  Carbonyl compound emissions from a heavy-duty diesel engine fueled with diesel fuel and ethanol-diesel blend. , 2010, Chemosphere.

[131]  M. Ema,et al.  Developmental toxicity of diesel exhaust: a review of studies in experimental animals. , 2013, Reproductive toxicology.

[132]  M. Zheng,et al.  Impact of Fuel Properties on Diesel Low Temperature Combustion , 2011 .

[133]  Giorgio Zamboni,et al.  Influence of high and low pressure EGR and VGT control on in-cylinder pressure diagrams and rate of heat release in an automotive turbocharged diesel engine , 2013 .

[134]  Perng-Jy Tsai,et al.  Approach for energy saving and pollution reducing by fueling diesel engines with emulsified biosolution/ biodiesel/diesel blends. , 2008, Environmental science & technology.

[135]  T. J. Wallington,et al.  Diesel vehicles and sustainable mobility in the U.S , 2013 .

[136]  P. Comte,et al.  Microstructure and Chemical Composition of Diesel and Biodiesel Particle Exhaust , 2014 .

[137]  A. Maiboom,et al.  Various effects of EGR on combustion and emissions on an automotive DI Diesel engine: numerical and experimental study , 2007 .

[138]  C. Mueller,et al.  Operational Characteristics of Oxygenate-Water Fuel Blends Studied in an Optical DI Diesel Engine with Simulated Exhaust Gas Recirculation , 2007 .

[139]  U Quass,et al.  PCDD/F emissions from heavy duty vehicle diesel engines. , 1999, Chemosphere.

[140]  Lin Lin,et al.  Opportunities and challenges for biodiesel fuel , 2011 .

[141]  Soo-Young No,et al.  Inedible vegetable oils and their derivatives for alternative diesel fuels in CI engines: A review , 2011 .

[142]  Tao Li,et al.  Environmental emissions and energy consumptions assessment of a diesel engine from the life cycle perspective , 2013 .

[143]  S. Kent Hoekman,et al.  Review of the effects of biodiesel on NOx emissions , 2012 .

[144]  Hua Chen,et al.  Performance and combustion characteristics of biodiesel-diesel-methanol blend fuelled engine , 2010 .

[145]  Zafer Utlu,et al.  The effect of biodiesel fuel obtained from waste frying oil on direct injection diesel engine performance and exhaust emissions , 2008 .

[146]  Sergio Machado Corrêa,et al.  Aromatic hydrocarbons emissions in diesel and biodiesel exhaust , 2006 .

[147]  L. Chiari,et al.  Fossil-fuel constraints on global warming. , 2010 .

[148]  Yasuhiro Fukushima,et al.  Assessment of energy performance and air pollutant emissions in a diesel engine generator fueled wit , 2011 .

[149]  M. Walsh,et al.  Mobile Source Related Air Pollution: Effects on Health and the Environment , 2011 .

[150]  A. Pisello,et al.  Albedo control as an effective strategy to tackle Global Warming: A case study , 2014 .

[151]  T. Streibel,et al.  Experimental and statistical determination of indicator parameters for the evaluation of fly ash and boiler ash PCDD/PCDF concentration from municipal solid waste incinerators. , 2007, Chemosphere.

[152]  Bogdan Nitu,et al.  Effect of EGR on Autoignition, Combustion, Regulated Emissions and Aldehydes in DI Diesel Engines , 2002 .

[153]  Zhijun Wu,et al.  Characteristics of Combustion and Emissions in a DI Engine Fueled with Biodiesel Blends from Soybean Oil , 2008 .

[154]  Roy M. Harrison,et al.  Sources and concentration of nanoparticles (<10 nm diameter) in the urban atmosphere , 2001 .

[155]  Chih-Chieh Chen,et al.  Effects of water-emulsified fuel on a diesel engine generator’s thermal efficiency and exhaust , 2014, Journal of the Air & Waste Management Association.

[156]  Thomas W Hesterberg,et al.  Evaluation of carcinogenic hazard of diesel engine exhaust needs to consider revolutionary changes in diesel technology. , 2012, Regulatory toxicology and pharmacology : RTP.

[157]  Tony E Grift,et al.  ffect of biodiesel on engine performances and emissions , 2010 .

[158]  Hua Zhao,et al.  The Dilution, Chemical, and Thermal Effects of Exhaust Gas Recirculation on Disesel Engine Emissions - Part 4: Effects of Carbon Dioxide and Water Vapour , 1997 .

[159]  Avinash Kumar Agarwal,et al.  Performance evaluation of a vegetable oil fuelled compression ignition engine , 2008 .

[160]  Sergio Machado Corrêa,et al.  Carbonyl emissions in diesel and biodiesel exhaust. , 2008 .

[161]  Zoran Filipi,et al.  The Impact of Exhaust Gas Recirculation on Performance and Emissions of a Heavy-Duty Diesel Engine , 2003 .

[162]  Jan Czerwinski,et al.  Secondary effects of catalytic diesel particulate filters: conversion of PAHs versus formation of nitro-PAHs. , 2008, Environmental science & technology.

[163]  Erkan Öztürk,et al.  Performance, emissions, combustion and injection characteristics of a diesel engine fuelled with canola oil–hazelnut soapstock biodiesel mixture , 2015 .

[164]  M. Musculus On the Correlation between NOx Emissions and the Diesel Premixed Burn , 2004 .

[165]  Jon Luecke,et al.  Diesel particle filter and fuel effects on heavy-duty diesel engine emissions. , 2010, Environmental science & technology.

[166]  Yu-Cheng Chang,et al.  Use of water containing acetone–butanol–ethanol for NOx-PM (nitrogen oxide-particulate matter) trade-off in the diesel engine fueled with biodiesel , 2014 .

[167]  J. Lelieveld,et al.  Transport impacts on atmosphere and climate: Land transport , 2010 .

[168]  A. Maiboom,et al.  Experimental study of various effects of exhaust gas recirculation (EGR) on combustion and emissions of an automotive direct injection diesel engine , 2008 .

[169]  Ralph A. Winter Innovation and the dynamics of global warming , 2014 .

[170]  Zunqing Zheng,et al.  Experimental study of n-butanol additive and multi-injection on HD diesel engine performance and emissions , 2010 .

[171]  Rafael L. Quirino,et al.  Heats of combustion of biofuels obtained by pyrolysis and by transesterification and of biofuel/diesel blends , 2006 .

[172]  Y. Ni,et al.  Recent progress on industrial fermentative production of acetone–butanol–ethanol by Clostridium acetobutylicum in China , 2009, Applied Microbiology and Biotechnology.

[173]  N. Henein,et al.  Effect of Different Biodiesel Blends on Autoignition, Combustion, Performance and Engine-Out Emissions in a Single Cylinder HSDI Diesel Engine , 2009 .

[174]  Kang-Shin Chen,et al.  Emission reductions of Air Pollutants from a Heavy-duty Diesel Engine Mixed with Various Amounts of H2/O2 , 2012 .

[175]  D. Prajapati,et al.  Study of Brake Thermal Efficiencies of Blend Fuels Using CVCRM Engine Test Rig , 2012 .

[176]  Naveen Kumar,et al.  Evaluation of Emission Characteristics of Blend of Algae Oil Methyl Ester with Diesel in a Medium Capacity Diesel Engine , 2014 .

[177]  Haji Hassan Masjuki,et al.  Impacts of biodiesel combustion on NOx emissions and their reduction approaches , 2013 .

[178]  Kang-Shin Chen,et al.  Saving energy and reducing pollution by use of emulsified palm-biodiesel blends with bio-solution additive , 2010 .

[179]  Hsi-Hsien Yang,et al.  Effects of waste cooking oil-based biodiesel on the toxic organic pollutant emissions from a diesel engine , 2014 .

[180]  Ayhan Demirbas,et al.  Biofuels sources, biofuel policy, biofuel economy and global biofuel projections , 2008 .

[181]  A. Demirbas,et al.  Importance of biodiesel as transportation fuel , 2007 .

[182]  Krister Holmberg,et al.  Water-in-diesel emulsions and related systems. , 2006, Advances in colloid and interface science.

[183]  Song Han,et al.  Techno-Economic Analysis of a Straw-Based Biorefinery System for Power, Heat, Pellet and Bioethanol Production , 2011 .

[184]  Claire Holman,et al.  Passenger car global warming potential: Current and projected levels in the UK☆ , 1994 .

[185]  Xavier Tauzia,et al.  Influence of EGR unequal distribution from cylinder to cylinder on NOx–PM trade-off of a HSDI automotive Diesel engine , 2009 .

[186]  Jordan J. Baruch,et al.  Combating global warming while enhancing the future , 2008 .

[187]  Avinash Kumar Agarwal,et al.  Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines , 2007 .

[188]  Ming Huo,et al.  Different percentage of acetone-butanol-ethanol (ABE) and diesel blends at low temperature condition in a constant volume chamber , 2014 .

[189]  Konstantinos Boulouchos,et al.  Influence of water-diesel fuel emulsions and EGR on combustion and exhaust emissions of heavy duty DI-diesel engines equipped with common-rail injection system , 2003 .

[190]  Aam Muharam,et al.  Performance and emission characteristic on a two cylinder DI diesel engine fuelled with ethanol-diesel blends , 2013 .

[191]  Lidia Morawska,et al.  A review of commuter exposure to ultrafine particles and its health effects , 2011 .

[192]  C. D. Rakopoulos,et al.  Investigation of the performance and emissions of bus engine operating on butanol/diesel fuel blends , 2010 .

[193]  Wen-Yinn Lin,et al.  Emissions from a generator fueled by blends of diesel, biodiesel, acetone, and isopropyl alcohol: analyses of emitted PM, particulate carbon, and PAHs. , 2014, The Science of the total environment.

[194]  Dimitrios C. Rakopoulos,et al.  Investigating the emissions during acceleration of a turbocharged diesel engine operating with bio-d , 2010 .

[195]  G. C. Mavropoulos,et al.  Effect of exhaust gas recirculation (EGR) temperature for various EGR rates on heavy duty DI diesel engine performance and emissions , 2008 .

[196]  Hsi-Hsien Yang,et al.  Effects of the biodiesel blend fuel on aldehyde emissions from diesel engine exhaust , 2008 .

[197]  Ayhan Demirbas,et al.  Political, economic and environmental impacts of biofuels: A review , 2009 .

[198]  Wen-Jhy Lee,et al.  Impact of using fishing boat fuel with high poly aromatic content on the emission of polycyclic aromatic hydrocarbons from the diesel engine , 2006 .

[199]  L. Chiari,et al.  Constraints of fossil fuels depletion on global warming projections , 2011 .

[200]  J. F. Izquierdo,et al.  Fuel additives from glycerol etherification with light olefins: State of the art , 2012 .

[201]  Wen-Jhy Lee,et al.  PAH emissions and energy efficiency of palm-biodiesel blends fueled on diesel generator , 2006 .

[202]  Hamid Taghavifar,et al.  Investigating the effect of combustion properties on the accumulated heat release of DI engines at rated EGR levels using the ANN approach , 2014 .

[203]  J. Keskinen,et al.  Effect of oxidation catalysts on diesel soot particles. , 2006, Environmental science & technology.

[204]  Sajjad Emami,et al.  Effects of injection timing, before and after top dead center on the propulsion and power in a diesel engine , 2014 .

[205]  A. Maiboom,et al.  NOx and PM emissions reduction on an automotive HSDI Diesel engine with water-in-diesel emulsion and EGR: An experimental study , 2011 .

[206]  Haiyong Peng,et al.  Effects of exhaust gas recirculation (EGR) on combustion and emissions during cold start of direct injection (DI) diesel engine , 2008 .

[207]  H. Rosenkranz Direct-acting mutagens in diesel exhausts: magnitude of the problem. , 1982, Mutation research.

[208]  O. M. I. Nwafor,et al.  Emission characteristics of diesel engine operating on rapeseed methyl ester , 2004 .

[209]  Wei-Lun Chang Acetone-Butanol-Ethanol Fermentation by Engineered Clostridium beijerinckii and Clostridium tyrobutyricum , 2010 .

[210]  Reducing emissions of carbonyl compounds and regulated harmful matters from a heavy-duty diesel engine fueled with paraffinic/biodiesel blends at one low load steady-state condition , 2009 .

[211]  S. Fernando,et al.  NOx Reduction from Biodiesel Fuels , 2006 .

[212]  Chunhua Zhang,et al.  Spray and Combustion Characteristics of Neat Acetone-Butanol-Ethanol, n-Butanol, and Diesel in a Constant Volume Chamber , 2014 .

[213]  M. P. Dorado,et al.  A comparison of performance of higher alcohols/diesel fuel blends in a diesel engine , 2012 .

[214]  Shou-Heng Liu,et al.  A new alternative paraffinic-palmbiodiesel fuel for reducing polychlorinated dibenzo-p-dioxin/dibenzofuran emissions from heavy-duty diesel engines. , 2011, Journal of hazardous materials.

[215]  J. C. Wall,et al.  Investigation of PCDD/F emissions from mobile source diesel engines: impact of copper zeolite SCR catalysts and exhaust aftertreatment configurations. , 2011, Environmental science & technology.

[216]  M. P. Dorado,et al.  Performance tests of a diesel engine fueled with pentanol/diesel fuel blends , 2013 .