Solid-state dewetting for ordered arrays of crystallographically oriented metal particles

We demonstrate that topographically modified substrates can be used as templates to control solid-state dewetting of thin films by creating a periodic variation in the initial curvature of the film. The dewetting of gold films on oxidized silicon surfaces patterned with arrays of inverted pyramid shaped pits is investigated. For specific ranges of relative film thickness and topographic dimension, dewetting results in arrays of submicrometer-scale particles with uniform periodic spacing and nearly uniform size and crystallographic orientation.

[1]  Henry I. Smith,et al.  Templated Formation of Ordered Metallic Nano-Particle Arrays , 2004 .

[2]  Yangdo Kim,et al.  Low-Temperature Growth of Carbon Nanotube by Plasma-Enhanced Chemical Vapor Deposition using Nickel Catalyst , 2003 .

[3]  Henry I. Smith,et al.  Magnetic properties of large-area particle arrays fabricated using block copolymer lithography , 2002 .

[4]  Yu Dapeng,et al.  Investigation of the growth process of Si nanowires using the vapour-liquid-solid mechanism , 2002 .

[5]  H. Baik,et al.  Nucleation and growth control of carbon nanotubes in CVD process , 2002 .

[6]  John Robertson,et al.  Growth process conditions of vertically aligned carbon nanotubes using plasma enhanced chemical vapor deposition , 2001 .

[7]  A. Requicha,et al.  Plasmonics—A Route to Nanoscale Optical Devices , 2001 .

[8]  Growth of amorphous silicon nanowires , 2001 .

[9]  Y. Xing,et al.  Controlled growth of oriented amorphous silicon nanowires via a solid–liquid–solid (SLS) mechanism , 2001 .

[10]  C. Thompson Structure Evolution During Processing of Polycrystalline Films , 2000 .

[11]  K. Youcef-Toumi,et al.  Fabrication of Large Area Nanostructured Magnets by Interferometric Lithography , 1998, 7th Joint MMM-Intermag Conference. Abstracts (Cat. No.98CH36275).

[12]  Carl V. Thompson,et al.  Capillary instabilities in thin, continuous films , 1992 .

[13]  Carl V. Thompson,et al.  Capillary instabilities in thin films , 1990 .

[14]  Harry A. Atwater,et al.  Silicon-on-insulator by graphoepitaxy and zone-melting recrystallization of patterned films , 1983 .

[15]  Michael W. Geis,et al.  Crystallographic orientation of silicon on an amorphous substrate using an artificial surface‐relief grating and laser crystallization , 1979 .

[16]  R. S. Wagner,et al.  VAPOR‐LIQUID‐SOLID MECHANISM OF SINGLE CRYSTAL GROWTH , 1964 .

[17]  W. W. Mullins,et al.  Flattening of a Nearly Plane Solid Surface due to Capillarity , 1959 .