Temperature sensing and optical heating in Er3+ single-doped and Er3+/Yb3+ codoped NaY(WO4)2 particles

Temperature sensing properties and laser induced thermal effects in rare earth doped materials could inspire some critical applications in accurate temperature detection and thermal therapy. In this paper, a microwave-assisted hydrothermal method was used to synthesize rare earth doped NaY(WO4)2 microstructures. Microstructured NaY(WO4)2 samples with various morphologies were derived by controlling the amount of trisodium citrate in reaction solution. Microscopic image and crystal structure of the obtained samples were characterized by XRD, SEM and HRTEM. It was found that all the received samples exhibited pure phase, and the Cit3−/Y3+ ratio considerably influenced the morphology but the rare earth concentration did not. The temperature sensing performance for the samples with various morphologies and different rare earth concentrations was evaluated. It was confirmed that both the morphology and doping concentration slightly affected the temperature property. Furthermore, based on the temperature sensing technique of Er3+ doped materials, the 980 nm laser irradiation induced thermal effect in NaY(WO4)2 microstructures was studied. It was also found that the sample temperature was very sensitive to the sample morphology and the doping concentration of Er3+ and Yb3+.

[1]  R. Franke,et al.  Inside Cover: A General and Efficient Iridium‐Catalyzed Hydroformylation of Olefins (Angew. Chem. Int. Ed. 1/2011) , 2011 .

[2]  Baojiu Chen,et al.  Excited state absorption cross sections of 4I13/2 of Er3+ in ZBLAN , 2009 .

[3]  Francisco Sanz-Rodríguez,et al.  Temperature sensing using fluorescent nanothermometers. , 2010, ACS nano.

[4]  Luís D Carlos,et al.  Thermometry at the nanoscale. , 2015, Nanoscale.

[5]  Inocencio R. Martín,et al.  Optical characterization of Er3+-doped zinc fluorophosphate glasses for optical temperature sensors , 2013 .

[6]  Wei Xu,et al.  An optical temperature sensor based on the upconversion luminescence from Tm3+/Yb3+ codoped oxyfluoride glass ceramic , 2012 .

[7]  W. Cao,et al.  Highly sensitive optical thermometry through thermally enhanced near infrared emissions from Nd3+/Yb3+ codoped oxyfluoride glass ceramic , 2013 .

[8]  Luigi Carbone,et al.  Microwave-assisted synthesis of colloidal inorganic nanocrystals. , 2011, Angewandte Chemie.

[9]  Guangsheng Guo,et al.  Synthesis, characterization and alcohol-sensing properties of rare earth doped In2O3 hollow spheres , 2013 .

[10]  Inocencio R. Martín,et al.  Effects of Er3+ concentration on thermal sensitivity in optical temperature fluorotellurite glass sensors , 2013 .

[11]  Xudong Zhao,et al.  Self‐Assembled NaY(WO4)2 Hierarchical Dumbbells: Microwave‐Assisted Hydrothermal Synthesis and Their Tunable Upconversion Luminescent Properties , 2012 .

[12]  M. Niederberger,et al.  Microwave chemistry for inorganic nanomaterials synthesis. , 2010, Nanoscale.

[13]  V. K. Rai,et al.  Er3+-Yb3+ and Eu3+-Er3+-Yb3+ codoped Y2O3 phosphors as optical heater , 2014 .

[14]  Baojiu Chen,et al.  Pumping-route-dependent concentration quenching and temperature effect of green up- and down-conversion luminescence in Er3+/Yb3+ co-doped Gd2(WO4)3 phosphors , 2013 .

[15]  Xiaohua Huang,et al.  Cancer cell imaging and photothermal therapy in the near-infrared region by using gold nanorods. , 2006, Journal of the American Chemical Society.

[16]  Baojiu Chen,et al.  Laser induced thermal effect on upconversion luminescence and temperature-dependent upconversion mechanism in Ho3+/Yb3+-codoped Gd2(WO4)3 phosphor , 2013 .

[17]  L. Liz‐Marzán,et al.  All‐In‐One Optical Heater‐Thermometer Nanoplatform Operative From 300 to 2000 K Based on Er3+ Emission and Blackbody Radiation , 2013, Advanced materials.

[18]  Ji-Ho Park,et al.  Cooperative nanomaterial system to sensitize, target, and treat tumors , 2009, Proceedings of the National Academy of Sciences.

[19]  Zhiguo Zhang,et al.  Excellent optical thermometry based on short-wavelength upconversion emissions in Er3+/Yb3+ codoped CaWO4. , 2012, Optics letters.

[20]  Yangyang He,et al.  Temperature Sensing and In Vivo Imaging by Molybdenum Sensitized Visible Upconversion Luminescence of Rare‐Earth Oxides , 2012, Advanced materials.

[21]  U. Rodríguez-Mendoza,et al.  Role of the host matrix on the thermal sensitivity of Er3+ luminescence in optical temperature sensors , 2012 .

[22]  Baojiu Chen,et al.  Self-assembled 3D flower-shaped NaY(WO4)2:Eu3+ microarchitectures: Microwave-assisted hydrothermal synthesis, growth mechanism and luminescent properties , 2012 .

[23]  S. Singh,et al.  Diode laser pumped Gd2O3:Er3+/Yb3+ phosphor as optical nano-heater , 2010 .

[24]  N. Kotov,et al.  Thermometer design at the nanoscale , 2007 .