Nickel Based RTD Fabricated via Additive Screen Printing Process for Flexible Electronics

A novel nickel (Ni)-based resistance temperature detector (RTD) was successfully developed for temperature monitoring applications. The RTD was fabricated by depositing Ni ink on a flexible polyimide substrate using the screen printing process. Thermogravimetric analysis was performed to study the thermal behavior of the Ni ink, and it was observed that the Ni ink can withstand up to 200 °C before the decomposition of the binder in the ink system. Scanning electron microscopy and white light interferometry were used to analyze the surface morphology of the printed Ni. X-ray diffractometry was used to obtain structural information, phase, and crystallite size of the deposited Ni nanoparticles. Energy dispersive X-ray spectroscopy was used to obtain semi-quantitative information of the elements present in the fabricated RTD. The capability of the RTD to detect temperatures varying from −60 °C to 180 °C, in steps of 20 °C, was investigated at a constant relative humidity of 20%RH. The results of the RTD demonstrated a linear response with resistive changes as high as 113% at 180 °C when compared with its base resistance at −60 °C. An average TCR of 0.44%/°C was calculated for the printed RTD with a response time of <10 s. The obtained results demonstrated the feasibility of employing Ni on flexible substrates for the development of flexible temperature sensors.

[1]  Rahul Panat,et al.  Structure, electrical characteristics, and high-temperature stability of aerosol jet printed silver nanoparticle films , 2016 .

[2]  Matti Mäntysalo,et al.  High Resolution E-Jet Printed Temperature Sensor on Artificial Skin , 2017 .

[3]  J. Go,et al.  Direct fabrication of thin film gold resistance temperature detection sensors on a curved surface using a flexible dry film photoresist and their calibration up to 450 °C , 2013 .

[4]  B. B. Narakathu,et al.  Screen printing of flexible piezoelectric based device on polyethylene terephthalate (PET) and paper for touch and force sensing applications , 2017 .

[5]  Gwo-Bin Lee,et al.  Micromachine-based humidity sensors with integrated temperature sensors for signal drift compensation , 2003 .

[6]  Xian Jian,et al.  Controllable preparation of Ni nanoparticles for catalysis of coiled carbon fibers growth , 2014, Nanoscale Research Letters.

[7]  Young Soo Yoon,et al.  A study on the fabrication of an RTD (resistance temperature detector) by using Pt thin film , 2001 .

[8]  W. Swanger,et al.  The Properties of Pure Nickel , 2017 .

[9]  A. Rudawska,et al.  Analysis for determining surface free energy uncertainty by the Owen–Wendt method , 2009 .

[10]  E. Arzt,et al.  Abnormal growth of giant grains in silver thin films , 2001 .

[11]  B. B. Narakathu,et al.  Gravure printed flexible surface enhanced Raman spectroscopy (SERS) substrate for detection of 2,4-dinitrotoluene (DNT) vapor , 2015 .

[12]  M. Bendahan,et al.  Temperature sensor realized by inkjet printing process on flexible substrate , 2016 .

[13]  B. B. Narakathu,et al.  Detection of heavy metal compounds using a novel inkjet printed surface enhanced Raman spectroscopy (SERS) substrate , 2012 .

[14]  E.J.P. Santos,et al.  RTD-based smart temperature sensor: Process development and circuit design , 2008, 2008 26th International Conference on Microelectronics.

[15]  Jinho Bae,et al.  All-Printed Differential Temperature Sensor for the Compensation of Bending Effects. , 2016, Langmuir : the ACS journal of surfaces and colloids.

[16]  Sai Guruva Reddy Avuthu,et al.  Implementation of traditional printing techniques for the development of flexible printed sensors , 2015 .

[17]  M. Zielina,et al.  An analysis of the elemental composition of micro-samples using EDS technique , 2014 .

[18]  C. E. Stauffer The Measurement of Surface Tension by the Pendant Drop Technique , 1965 .

[19]  Banfield,et al.  Imperfect oriented attachment: dislocation generation in defect-free nanocrystals , 1998, Science.

[20]  B. B. Narakathu,et al.  A Screen Printed Phenanthroline-Based Flexible Electrochemical Sensor for Selective Detection of Toxic Heavy Metal Ions , 2016, IEEE Sensors Journal.

[21]  Y. Ye,et al.  Synthesis of nickel nanoparticles and carbon encapsulated nickel nanoparticles supported on carbon nanotubes , 2006 .

[22]  Jimin Xie,et al.  Modifiers-assisted formation of nickel nanoparticles and their catalytic application to p-nitrophenol reduction , 2013 .

[23]  D. Briand,et al.  Inkjet printing on paper for the realization of humidity and temperature sensors , 2011, 2011 16th International Solid-State Sensors, Actuators and Microsystems Conference.

[24]  John C. Batchelor,et al.  Inkjet printed paper based frequency selective surfaces and skin mounted RFID tags: the interrelation between silver nanoparticle ink, paper substrate and low temperature sintering technique , 2015 .

[25]  S. Yao,et al.  Wearable multifunctional sensors using printed stretchable conductors made of silver nanowires. , 2014, Nanoscale.

[26]  B. B. Narakathu,et al.  Screen Printing of Multilayered Hybrid Printed Circuit Boards on Different Substrates , 2015, IEEE Transactions on Components, Packaging and Manufacturing Technology.

[27]  F. Krebs,et al.  Roll-to-roll printed silver nanowires for increased stability of flexible ITO-free organic solar cell modules. , 2016, Nanoscale.

[28]  Francisco Molina-Lopez,et al.  Printed sensors on smart RFID labels for logistics , 2012, 10th IEEE International NEWCAS Conference.

[29]  B. B. Narakathu,et al.  Printed capacitive based humidity sensors on flexible substrates , 2011 .

[30]  B. B. Narakathu,et al.  Novel fully screen printed flexible electrochemical sensor for the investigation of electron transfer between thiol functionalized viologen and gold clusters , 2013 .

[31]  J. S. Pedersen,et al.  Determination of size distributions in nanosized powders by TEM, XRD, and SAXS , 2006 .

[32]  S. Jung,et al.  Design and fabrication of screen-printed silver circuits for stretchable electronics , 2014 .

[33]  Antonio Feteira,et al.  Negative Temperature Coefficient Resistance (NTCR) Ceramic Thermistors: An Industrial Perspective , 2009 .

[34]  N. Suriyanarayanan,et al.  Nanoscale synthesis and optical features of nickel nanoparticles , 2014 .

[35]  Hans-Erik Nilsson,et al.  Printed Humidity Sensor With Memory Functionality for Passive RFID Tags , 2013, IEEE Sensors Journal.

[36]  Tobias Merkel,et al.  A new technology for fluidic microsystems based on PCB technology , 1999 .

[37]  B. B. Narakathu,et al.  A screen printed and flexible piezoelectric-based AC magnetic field sensor , 2017 .

[38]  Zhiqiang Fang,et al.  A gravure printed antenna on shape-stable transparent nanopaper. , 2014, Nanoscale.

[39]  B. B. Narakathu,et al.  Development of a Microfluidic Sensing Platform by Integrating PCB Technology and Inkjet Printing Process , 2015, IEEE Sensors Journal.

[40]  B. B. Narakathu,et al.  A carbon nanotube based NTC thermistor using additive print manufacturing processes , 2018, Sensors and Actuators A: Physical.

[41]  Feng Huang,et al.  Two-Stage Crystal-Growth Kinetics Observed during Hydrothermal Coarsening of Nanocrystalline ZnS , 2003 .

[42]  Yang Song,et al.  Application of RTD Sensor in the Real Time Measurement and Wireless Transmission , 2014, 2014 Fourth International Conference on Instrumentation and Measurement, Computer, Communication and Control.

[43]  F. Krebs,et al.  Roll‐to‐Roll Printed Silver Nanowire Semitransparent Electrodes for Fully Ambient Solution‐Processed Tandem Polymer Solar Cells , 2015 .