The Electrical Resistivities of NaNO2 and KNO3 Crystals

The d c electrical resistivities of NaNO 2 and KNO 3 crystals were measured by the potentiometer method in the temperature range covering their transition points. The obtained results were found to obey the conventional exponential law and the activation energies in both phases were calculated. It was observed that at the transition point the electrical resistivity shows a steep jump, which is about two∼six times in NaNO 2 and about one hundred times in KNO 3 . A little discussion was made about this phenomenon in connection with the appearance of some disordering in the crystal structure.

[1]  S. Nomura Some Experimental and Theoretical Studies of Ferroelectricity in NaNO 2 , 1961 .

[2]  S. Sawada,et al.  Thermal Conductivity of Sodium Nitrite , 1961 .

[3]  S. Nomura,et al.  Dielectric Behavior of KNO 3 in Its Ferroelectric Phase III , 1961 .

[4]  S. Shozo,et al.  Dielectric Properties of Ferroelectric NaNO2 , 1961 .

[5]  Sato Yoshiki,et al.  Study of the Phase Transition in NaNO2 by Polarized Infrared Radiation , 1961 .

[6]  S. Nomura Thermal Properties of NaNO2 , 1961 .

[7]  S. Hoshino,et al.  Anomalous Temperature Dependence of Lattice Constants of Ferroelectric Sodium Nitrite , 1961 .

[8]  S. Nomura,et al.  Domain Structure of NaNO2 , 1961 .

[9]  I. Shibuya X-Ray Studies of the Ferroelectric Phase Transition in NaNo 2 , 1961 .

[10]  Sigetosi Tanisaki,et al.  Microdomain Structure in Paraelectric Phase of NaNO2 , 1961 .

[11]  B. Frazer,et al.  A neutron diffraction refinement of the low temperature phase of NaNO2 , 1961 .

[12]  S. Sawada,et al.  Thermal Conductivity of KNO3 , 1960 .

[13]  S. Nomura,et al.  Ferroelectricity in the Phase III of KNO3 , 1958 .

[14]  S. Nomura,et al.  Ferroelectricity in NaNO 2 , 1958 .

[15]  G. Carpenter Further least-squares refinement of the crystal structure of sodium nitrite , 1955 .

[16]  A. Ubbelohde,et al.  The persistence of crystal axes in a thermal transformation , 1953, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[17]  M. Truter Refinement of a non-centrosymmetrical structure: sodium nitrite , 1954 .

[18]  P. W. Bridgman Polymorphic Changes under Pressure of the Univalent Nitrates , 1916 .