Self‐Diffusion in Liquid Gallium
暂无分享，去创建一个
Self‐diffusion in liquid gallium metal at atmospheric pressure is described by the equation: D = 1.07 × 10—4 exp[—1122/RT] cm2 sec—1. At 30°C the effect of pressure on the rate of self‐diffusion is given by: log10D = —4.7793—9.529×10—6P (kg cm—2). The activation volume at this temperature is 0.55 cm3 g atom—1. Although the Stokes‐Einstein radius agrees quite well with the ionic radius of Ga+3, the temperature coefficients of viscosity and diffusivity differ somewhat.
[1] N. Nachtrieb,et al. Self‐Diffusion in Liquid Mercury , 1956 .
[2] N. Nachtrieb,et al. Effect of Pressure on Self‐Diffusion in White Phosphorus , 1955 .
[3] N. Nachtrieb,et al. Self-Diffusion in Solid Sodium. II. The Effect of Pressure , 1952 .
[4] K. Spells,et al. The determination of the viscosity of liquid gallium over an extended nrange of temperature , 1936 .