Humidity sensors fabricated with photo-curable electrolyte inks using an ink-jet printing technique and their properties

Abstract Photo-curable humidity-sensitive electrolyte inks were prepared by dissolving the following in methanol/2-methoxyethanol: [2-[(methacryloyloxy)ethyl]dimethyl]propyl ammonium bromide (MEPAB), 1,5-[bis(2-methacryloxyethyl)dimethylammono]pentane dibromide (MDAPD), a multifunctional reactive oligomer (SP1013), trimethylolpropane triacrylate (TMPTA), and photo-initiators. The inks were composed of mixtures with the following contents: MEPAB/MDAPD/SP1013/TMPTA = 6/24/17.2/12.8, 10/20/17.2/12.8, 15/15/17.2/12.8, 20/10/17.2/12.8, and 24/6/17.2/12.8. The humidity-sensitive membranes were fabricated on an electrode using a wide format drop-on-demand ink-jet printer equipped with a UV lamp system, and the printed inks were UV-cured simultaneously. The humidity-sensing characteristics including water durability and high humidity–temperature cycle were measured and estimated. The humidity sensors obtained using the ink-jet print technique showed similar humidity-sensitive characteristics within ± 1%RH.

[1]  H. Rhee,et al.  Humidity sensitive properties of copolymers containing phosphonium salts , 1999 .

[2]  H. Sirringhaus,et al.  High-Resolution Ink-Jet Printing of All-Polymer Transistor Circuits , 2000, Science.

[3]  Hyung-seok Park,et al.  Humidity sensitivity of hybrid polyelectrolytes prepared by the sol-gel process , 2005 .

[4]  C. Edwards 38.3: Application of Polymer LED Materials Using Piezo Ink-Jet Printing(Session 38: Display Manufacturing: OLEDs)(Report on SID 2001) , 2001 .

[5]  M. Gong,et al.  Humidity sensors fabricated with polyelectrolyte membrane using an ink-jet printing technique and their electrical properties , 2005 .

[6]  Sawyer B. Fuller,et al.  Ink-jet printed nanoparticle microelectromechanical systems , 2002 .

[7]  Chung-Chih Wu,et al.  Ink-jet printing of doped polymers for organic light emitting devices , 1998 .

[8]  Shuji Miyoshi,et al.  A thin-film resistance humidity sensor , 1983 .

[9]  M. Gong,et al.  Humidity-sensitive properties of self-assembled polyelectrolyte system , 2005 .

[10]  Y. Sadaoka,et al.  A Humidity Sensor Composed of Interpenetrating Polymer Networks of Hydrophilic and Hydrophobic Methacrylate Polymers , 1993 .

[11]  Richard H. Friend,et al.  High-Resolution Ink-Jet Printing of All-Polymer Transistor Circuits , 2001 .

[12]  S. Joo,et al.  Polymeric humidity sensor using polyelectrolytes derived from alkoxysilane cross-linker , 2005 .

[13]  Y. Sadaoka,et al.  Humidity sensors composed of grafted copolymers , 1986 .

[14]  H. Fukumoto,et al.  Humidity-sensitive and water-resistive polymeric materials , 1988 .

[15]  Hyung-seok Park,et al.  Humidity sensitive properties of quaternary ammonium salts containing polyelectrolytes crosslinked with 2-oxazoline crosslinker , 2005 .

[16]  Yang Yang,et al.  Organic/polymeric electroluminescent devices processed by hybrid ink-jet printing , 2000 .

[17]  Brian Derby,et al.  A Low Curing Temperature Silver Ink for Use in Ink‐Jet Printing and Subsequent Production of Conductive Tracks , 2005 .

[18]  M. Matsuguchi,et al.  A Humidity Sensor Using Polytetrafluoroethylene‐Graft‐Quaternized‐Polyvinylpyridine , 1991 .

[19]  H. Rhee,et al.  Humidity sensor using epoxy resin containing quaternary ammonium salts , 2001 .

[20]  Richard H. Friend,et al.  Inkjet Printed Via‐Hole Interconnections and Resistors for All‐Polymer Transistor Circuits , 2001 .