Host-guest complexation driven dynamic supramolecular self-assembly.

Host-guest complexation between pillararene trimer 1 and biviologen 2 was used to fabricate the dynamic supramolecular self-assembly, which exhibits a reversible multidimensional transformation from 0D to 3D upon concentration changes. As a comparison, assemblies built by the complexation between 1,4-dimethoxypillar[5]arene and 2 only show spherical morphology under similar conditions.

[1]  M. Ward,et al.  Functional behaviour from controlled self-assembly: challenges and prospects. , 2013, Chemical Society reviews.

[2]  Yanli Zhao,et al.  Thermo-responsive fluorescent vesicles assembled by fluorescein-functionalized pillar[5]arene , 2013 .

[3]  J. F. Stoddart,et al.  Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework. , 2012, Journal of the American Chemical Society.

[4]  Jianzhuang Chen,et al.  An amphiphilic pillar[5]arene: synthesis, controllable self-assembly in water, and application in calcein release and TNT adsorption. , 2012, Journal of the American Chemical Society.

[5]  Jinming Hu,et al.  Enzyme-responsive polymeric assemblies, nanoparticles and hydrogels. , 2012, Chemical Society reviews.

[6]  J. F. Stoddart,et al.  Cooperative self-assembly: producing synthetic polymers with precise and concise primary structures. , 2012, Chemical Society reviews.

[7]  Yiyong Mai,et al.  Self-assembly of block copolymers. , 2012, Chemical Society reviews.

[8]  Feihe Huang,et al.  A water-soluble pillar[6]arene: synthesis, host-guest chemistry, and its application in dispersion of multiwalled carbon nanotubes in water. , 2012, Journal of the American Chemical Society.

[9]  Jun-Li Hou,et al.  Single-molecular artificial transmembrane water channels. , 2012, Journal of the American Chemical Society.

[10]  Feihe Huang,et al.  Pillar[6]arene-based photoresponsive host-guest complexation. , 2012, Journal of the American Chemical Society.

[11]  Yong Yang,et al.  Pillararenes, a new class of macrocycles for supramolecular chemistry. , 2012, Accounts of chemical research.

[12]  Feihe Huang,et al.  per-Hydroxylated pillar[6]arene: synthesis, X-ray crystal structure, and host-guest complexation. , 2012, Organic letters.

[13]  J. F. Stoddart,et al.  A self-complexing and self-assembling pillar[5]arene. , 2012, Chemical communications.

[14]  K. Sharma,et al.  Pillar[5]arenes: fascinating cyclophanes with a bright future. , 2012, Chemical Society reviews.

[15]  T. Ogoshi,et al.  Synthesis of novel pillar-shaped cavitands “Pillar[5]arenes” and their application for supramolecular materials , 2012, Journal of Inclusion Phenomena and Macrocyclic Chemistry.

[16]  Wen Si,et al.  Selective artificial transmembrane channels for protons by formation of water wires. , 2011, Angewandte Chemie.

[17]  J. F. Stoddart,et al.  Dynamic clicked surfaces based on functionalised pillar[5]arene. , 2011, Chemical communications.

[18]  Zhenxia Chen,et al.  Self-assembly and proton conductance of organic nanotubes from pillar[5]arenes , 2011 .

[19]  Y. Yu,et al.  Pillar[5]arene decaamine: synthesis, encapsulation of very long linear diacids and formation of ion pair-stopped [2]rotaxanes. , 2011, Chemical communications.

[20]  J. F. Stoddart,et al.  Monofunctionalized pillar[5]arene as a host for alkanediamines. , 2011, Journal of the American Chemical Society.

[21]  Zhi Ma,et al.  Formation of linear supramolecular polymers that is driven by C-H⋅⋅⋅π interactions in solution and in the solid state. , 2011, Angewandte Chemie.

[22]  Y. Yu,et al.  Self-assembly of [2]pseudorotaxanes based on pillar[5]arene and bis(imidazolium) cations. , 2010, Chemical communications.

[23]  D. Schollmeyer,et al.  Synthesis and Conformational Properties of Nonsymmetric Pillar[5]arenes and Their Acetonitrile Inclusion Compounds , 2010 .

[24]  T. Ogoshi,et al.  High Yield Synthesis of Polyrotaxane Constructed from Pillar[5]arene and Viologen Polymer and Stabilization of Its Radical Cation , 2010 .

[25]  T. Ogoshi,et al.  Synthesis, conformational and host-guest properties of water-soluble pillar[5]arene. , 2010, Chemical communications.

[26]  Chunju Li,et al.  Complex interactions of pillar[5]arene with paraquats and bis(pyridinium) derivatives. , 2010, Organic & biomolecular chemistry.

[27]  Xi Zhang,et al.  Tuning the Amphiphilicity of Building Blocks: Controlled Self‐Assembly and Disassembly for Functional Supramolecular Materials , 2009 .

[28]  A. Douhal.  Ultrafast guest dynamics in cyclodextrin nanocavities. , 2004, Chemical reviews.

[29]  H. Schneider,et al.  NMR Studies of Cyclodextrins and Cyclodextrin Complexes. , 1998, Chemical reviews.

[30]  P. Maccarthy.  Simplified experimental route for obtaining Job's curves , 1978 .