Transition-Metal-Free Direct Arylation: Synthesis of Halogenated 2-Amino-2′-hydroxy-1,1′-biaryls and Mechanism by DFT Calculations.
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The reaction proceeds with complete regioselectivity to afford the target compounds, which are difficult to prepare using other methods.
[1] D. Ess,et al. Transition-metal-free direct arylation: synthesis of halogenated 2-amino-2'-hydroxy-1,1'-biaryls and mechanism by DFT calculations. , 2013, Journal of the American Chemical Society.