The volatile components of wild ginger (Siphonochilus aethiopicus (Schweinf) B.l Burtt)

Volatile components were isolated from the matrix of fresh and roasted samples of wild ginger (Siphonochilus aethiopicus (Schweinf) B.L Burtt) by solvent extraction and vacuum distilled. Quantitative determination of the volatiles in the distillate was done by GC-FID and organoleptic examination by GC-olfactometry. The sesquiterpenes were the major components of fresh wild ginger having a weight percent of 70 as against the monoterpene percentage of 3.5 and diterpene percentage of 25. The distillates obtained contained no ditepenes, while the monoterpene percentage increased to 72 in the fresh sample and 49 in the roasted sample. The sesquiterpene weight percent of the distillates decreased to 16 in the fresh sample and 27 in the roasted sample. Methyl-2-/-3-methyl butanoates, propyl-2-methylbutanoate, β-phellandrene, 2-isopropyl-3-methoxypyrazine, 2-isobutyl-3-methoxypyrazine, methional, furanodiene and curzerenone were odorants important for the flavour of the fresh sample having the higher FD-factors. Curzerenone and furanodiene were characterised by NMR and GCMS after isolation from the crude solvent extract. 2-Acetylthiophene together with these eight odorants was strongly involved in the characteristic pleasant flavour of the roasted spice. The lowest odour threshold value of curzerenone detected was 0.8 to 1.69 µg/Lair.   Key words: Siphonochilus aethiopicus, flavour, terpenes, curzerenone.

[1]  Carol Clements,et al.  Bioactive diterpenes and sesquiterpenes from the rhizomes of wild ginger (Siphonochilus aethiopicus (Schweinf) B.L Burtt). , 2011, African journal of traditional, complementary, and alternative medicines : AJTCAM.

[2]  T. Řezanka,et al.  Fast and easy GC/MS identification of myrrh resins , 2008, Pharmaceutical Chemistry Journal.

[3]  W. Haber,et al.  Chemical composition and antimicrobial activity of the bark essential oil of Cedrela odorata from Monteverde, Costa Rica , 2009 .

[4]  W. Setzer Ab initio analysis of the Cope rearrangement of germacrane sesquiterpenoids , 2008, Journal of molecular modeling.

[5]  Z. Cai,et al.  Analysis of volatile components of Curcuma sichuanensis X. X. Chen by gas chromatography-mass spectrometry. , 2007, Journal of pharmaceutical and biomedical analysis.

[6]  P. Y. Bruice Organic chemistry / Paula Yurkanis Bruice , 2007 .

[7]  R. Bikanga,et al.  Aromatic Plants of Tropical Central Africa. Part XLVI. Essential Oil Constituents of Cassia alata (L.) from Gabon , 2005 .

[8]  J. Igoli,et al.  TRADITIONAL MEDICINE PRACTICE AMONGST THE IGEDE PEOPLE OF NIGERIA. PART II , 2005 .

[9]  Zi-Tao Jiang,et al.  Chemical composition of the essential oil of Cuminum cyminum L. from China , 2004 .

[10]  J. Bessière,et al.  Aromatic plants of tropical central Africa. Part XLIX: chemical composition of essential oils of the leaf and rhizome of Aframomum giganteum K. Schum from Gabon , 2004 .

[11]  Romică Creţu,et al.  Food Chemistry , 2021 .

[12]  P. Wessels,et al.  Furanoterpenoids from Siphonochilus aethiopicus , 2002 .

[13]  K. Başer,et al.  The Essential Oils of Aframomum corrorima (Braun) Jansen and A. angustifolium K. Schum. from Africa , 2001 .

[14]  M. Lis‐Balchin,et al.  Composition of the essential oils of Pelargonium odoratissimum, P. exstipulatum, and P. × fragrans (Geraniaceae) and their bioactivity , 2000 .

[15]  H. Pfeifhofer Composition of the essential oil of Pinus canariensis Sweet ex Sprengel , 2000 .

[16]  G. Alonzo,et al.  Citrus somatic hybrid leaf essential oil. , 2000 .

[17]  H. S. Song,et al.  Quantitative determination and characteristic flavour of Citrus junos (yuzu) peel oil , 2000 .

[18]  T. Itoh,et al.  Volatile components of peel cold-pressed oils of two cultivars of sweet orange (Citrus sinensis (L.) Osbeck) from Ethiopia , 2000 .

[19]  L. Rojas,et al.  The essential oil of Espeletia weddellii Sch. Bip. ex Wedd , 2000 .

[20]  N. B. Shankaracharya,et al.  A comparison of the essential oils of Aframomum daniellii (Hook. f.) K. Schum. and Amomum subulatum Roxb , 1998 .

[21]  R. Croteau,et al.  Germacrene C synthase from Lycopersicon esculentum cv. VFNT cherry tomato: cDNA isolation, characterization, and bacterial expression of the multiple product sesquiterpene cyclase. , 1998, Proceedings of the National Academy of Sciences of the United States of America.

[22]  Terry E. Acree,et al.  Peer Reviewed: GC/Olfactometry GC With a Sense of Smell , 1997 .

[23]  H. Guth Determination of the Configuration of Wine Lactone , 1996 .

[24]  C. Milo,et al.  Changes in the odorants of boiled trout (Salmo fario) as affected by the storage of the raw material , 1993 .

[25]  Werner Grosch,et al.  Detection of potent odorants in foods by aroma extract dilution analysis , 1993 .

[26]  Harold Egan,et al.  Pearson's Composition and Analysis of Foods , 1991 .

[27]  W. Grosch,et al.  3‐Methylnonane‐2,4‐dione – An Intense Odour Compound Formed during Flavour Reversion of Soya‐Bean Oil , 1989 .

[28]  Frank Ullrich,et al.  Identification of the most intense volatile flavour compounds formed during autoxidation of linoleic acid , 1987 .

[29]  R. T. Weavers,et al.  Foliage sesquiterpenes and diterpenes of Podocarpus spicatus , 1987 .

[30]  C. Brieskorn,et al.  [Constituents of the essential oil of myrrh]. , 1982, Planta medica.

[31]  K. Y. Kiew Taxonomic studies in the genus Kaempferia (Zingiberaceae) , 1980 .

[32]  T. Takemoto,et al.  Sesquiterpenoids. Part XLVII. Structure, configuration, conformation, and thermal rearrangement of furanodienone, isofuranodienone, curzerenone, epicurzerenone, and pyrocurzerenone, sesquiterpenoids of Curcuma zedoaria , 1975 .

[33]  G. Rücker,et al.  Die struktur des isofuranodiens aus stenocylax michelii (myrtaceae) , 1971 .

[34]  T. Takemoto,et al.  Structure of Furanodiene and Isofuranogermacrene (Curzerene) , 1970 .

[35]  D. Connell Natural pungent compounds. III. The paradols and associated compounds. , 1970 .

[36]  J. Dalziel,et al.  The useful plants of West Tropical Africa. , 1938 .