Depolarized Rayleigh scattering and orientational relaxation of molecules in solution. IV. Mixtures of hexafluorobenzene with benzene and with mesitylene

Measurements of the orientational relaxation times of the components of mixtures of hexafluorobenzene with benzene and mesitylene have been made by depolarized Rayleigh scattering. In both mixtures, there were strong ’’static’’ and ’’dynamic’’ cross correlation terms which affected the individual reorientation times. There was no significant contribution to the Rayleigh spectra from a long‐lived complex in these mixtures.

[1]  J. I. Brauman,et al.  Depolarized Rayleigh scattering and 13C NMR studies of anisotropic molecular reorientation of aromatic compounds in solution , 1974 .

[2]  T. Bull.  2D and 19F spin‐lattice relaxation in deuterated 1,3,5‐trifluorobenzene , 1973 .

[3]  J. I. Brauman,et al.  Depolarized Rayleigh scattering and orientational relaxation of molecules in solution. III Carboxylic acids , 1973 .

[4]  J. I. Brauman,et al.  Depolarized Rayleigh scattering and orientational relaxation of molecules in solution. II Chloroform and nitrobenzene , 1973 .

[5]  J. I. Brauman,et al.  Depolarized Rayleigh scattering and orientational relaxation of molecules in solution. I. Benzene, toluene, and para‐xylene , 1973 .

[6]  T. Keyes.  Microscopic theory of collective anisotropic molecular reorientation , 1972 .

[7]  T. Keyes,et al.  Depolarized Light Scattering: Theory of the Sharp and Broad Rayleigh Lines , 1972 .

[8]  Stanislaw Kielich,et al.  APPORT DE LA DIFFUSION RAYLEIGH DÉPOLARISÉE ET DE L'EFFET KERR OPTIQUE A L'ÉTUDE DES CORRÉLATIONS RADIALES ET D'ORIENTATION DANS QUELQUES LIQUIDES , 1972 .

[9]  P. Flory,et al.  Depolarized rayleigh scattering and the mean-squared optical anisotropies of n-alkanes in solution , 1972 .

[10]  H. C. Andersen,et al.  Erratum: Kinetic Equations for Orientational and Shear Relaxation and Depolarized Light Scattering in Liquids , 1971 .

[11]  D. Jackson,et al.  The intensity and spectra of depolarized light scattered from benzene-nitrobenzene mixtures , 1971 .

[12]  D. Grant,et al.  Nuclear Overhauser Effects and 13C Relaxation Times in 13C–{H} Double Resonance Spectra , 1970 .

[13]  W. Brey,et al.  Nuclear spin-lattice relaxation and chemical shift studies of fluorocarbon-hydrocarbon mixtures , 1970 .

[14]  Richard I. Shrager,et al.  Modelaide: a computer graphics program for the evaluation of mathematical models , 1969, COMG.

[15]  A. Ben-Reuven,et al.  Light Scattering by Orientational Fluctuations in Liquids , 1969 .

[16]  D. Murthy,et al.  The stereospecific solvation of non-polar organic solutes in liquid benzene , 1969 .

[17]  R. Pecora.  Spectrum of Light Scattered from Optically Anisotropic Macromolecules , 1968 .

[18]  W. Gaw,et al.  Thermodynamic properties of binary systems containing hexafluorobenzene. Part 4.—Excess Gibbs free energies of the three systems hexafluorobenzene + benzene, touene, and p-xylene , 1968 .

[19]  W. Steele,et al.  Scattering from Fluids of Nonspherical Molecules. II. Light , 1965 .