A defect-pool model for near-interface states in amorphous silicon thin-film transistors

Abstract We present evidence that the majority of deep states located near to the gate-insulator interface in amorphous silicon (a-Si) thin-film transistors are part of a defect pool of silicon dangling-bond states, whose density and energy position within the energy gap of the a-Si are determined by the Fermi energy during thermal equilibration. Transistors made with silicon nitride and silicon oxide gate insulators tend to have different densities-of-states distributions. We show it is possible to modify the entire energy distribution of states, by annealing the transistors with an applied gate bias. The density of states and their energy distribution re-equilibrates to the new Fermi energy position, causing the density of states to be increased or decreased in different parts of the bandgap. In particular, an oxide transistor can be made to have a density-of-states distribution similar to a nitride transistor by suitable positive-bias annealing, and a nitride transistor can be made to have a density-of...

[1]  P. Thomas,et al.  The influence of spatially non-uniform density-of-state distributions on the characteristics of a-Si:H thin-film transistors , 1990 .

[2]  Jackson Role of band-tail carriers in metastable defect formation and annealing in hydrogenated amorphous silicon. , 1990, Physical review. B, Condensed matter.

[3]  K. Pierz,et al.  Correlation between defect density and Fermi-level position in a-Si:H , 1989 .

[4]  J. R. Hughes,et al.  Evidence for the defect pool concept for Si dangling bond states in a-Si:H from experiments with thin film transistors , 1989 .

[5]  Winer Chemical-equilibrium description of the gap-state distribution in a-Si:H. , 1989, Physical review letters.

[6]  Winer,et al.  Defect equilibria in undoped a-Si:H. , 1989, Physical review. B, Condensed matter.

[7]  S. Wagner,et al.  Implications of the ‘Defect Pool’ concept for ‘metastable’ and ‘stable’ defects in amorphous silicon , 1989 .

[8]  Hellmut Fritzsche,et al.  Amorphous silicon and related materials , 1989 .

[9]  Winer,et al.  Distribution of occupied near-surface band-gap states in a-Si:H. , 1988, Physical review. B, Condensed matter.

[10]  R. Street The origin of metastable states in a-Si:H , 1988 .

[11]  G. Müller On the generation and annealing of dangling bond defects in hydrogenated amorphous silicon , 1988 .

[12]  K. Pierz,et al.  Gap-state distribution in n-type and p-type a-Si:H from optical absorption , 1987 .

[13]  R. Street,et al.  Thermal equilibrium processes in doped amorphous silicon , 1987 .

[14]  M. Vaněček,et al.  a-Si:H gap states investigated by CPM and SCLC , 1987 .

[15]  I. D. French,et al.  Bias dependence of instability mechanisms in amorphous silicon thin‐film transistors , 1987 .

[16]  Jackson,et al.  Creation of near-interface defects in hydrogenated amorphous silicon-silicon nitride heterojunctions: The role of hydrogen. , 1987, Physical review. B, Condensed matter.

[17]  C. van Berkel,et al.  Resolution of amorphous silicon thin-film transistor instability mechanisms using ambipolar transistors , 1987 .

[18]  M. Stutzmann Weak bond-dangling bond conversion in amorphous silicon , 1987 .

[19]  R. Schropp,et al.  Undoped Amorphous Silicon TFTs with n-Channel OR p-Channel Device Operation for the Determination of the Gap States Distribution. , 1987 .

[20]  Inspec Properties of amorphous silicon , 1985 .

[21]  M. J. Powell Analysis of field-effect-conductance measurements on amorphous semiconductors , 1981 .

[22]  W. Spear,et al.  Investigation of the density of localized states in a-Si using the field effect technique , 1976 .

[23]  W. Spear,et al.  Investigation of the localised state distribution in amorphous Si films , 1972 .