Accurate detection and discrimination of pollutant gases using a temperature modulated MOX sensor combined with feature extraction and support vector classification

Abstract Gas detection and discrimination have been, until recently, sensors-specific, with different sensors and techniques used for each of the gases. In this work, we describe a novel approach relying on a single physical sensor in conjunction with data-driven algorithms for detecting the presence of one of the three dangerous gases: CO, NO 2 , and O 3 individually or in mixtures. The approach uses a single Metal Oxide (MOX) sensor coupled with two heaters in its hardware part. Then, its software part uses a supervised machine learning model. The sensor is exposed to the different gases and their mixtures and would react accordingly with a change in its electric signals. These raw signals, along with the readings from the heaters, constitute the primary dataset for the discrimination. To further enhance the classification results, the raw dataset is augmented by calculating several time-domain features of each of the measurements. Then, the features are ranked, and the ones with the best results to solve the classification problem are selected. Once the pretreatment of the data is finished, the selected features are used to train and validate a multi-support vector machine model. Finally, the results showcased in this paper highlight the effectiveness of the proposed approach.

[1]  Josep Samitier,et al.  An intelligent detector based on temperature modulation of a gas sensor with a digital signal processor , 2001 .

[2]  Xin Zhang,et al.  Modeling data-driven sensor with a novel deep echo state network , 2020 .

[3]  Gang Xu,et al.  Metal–organic frameworks and their derivatives for electrically-transduced gas sensors , 2021, Coordination Chemistry Reviews.

[4]  Daphne Koller,et al.  Toward Optimal Feature Selection , 1996, ICML.

[5]  A. Wayne Whitney,et al.  A Direct Method of Nonparametric Measurement Selection , 1971, IEEE Transactions on Computers.

[6]  Yang Liu,et al.  Combining integrated sampling with SVM ensembles for learning from imbalanced datasets , 2011, Inf. Process. Manag..

[7]  Lidia Morawska,et al.  Real-time sensors for indoor air monitoring and challenges ahead in deploying them to urban buildings. , 2016, The Science of the total environment.

[8]  R. Piedrahita,et al.  Approach for quantification of metal oxide type semiconductor gas sensors used for ambient air quality monitoring , 2015 .

[9]  Josef Kittler,et al.  Fast branch & bound algorithms for optimal feature selection , 2004, IEEE Transactions on Pattern Analysis and Machine Intelligence.

[10]  Ton J.J. van den Boom,et al.  A temperature-controlled smart surface-acoustic-wave gas sensor , 1998 .

[11]  Wahyu Caesarendra,et al.  A Review of Feature Extraction Methods in Vibration-Based Condition Monitoring and Its Application for Degradation Trend Estimation of Low-Speed Slew Bearing , 2017 .

[12]  C. Xie,et al.  An entire feature extraction method of metal oxide gas sensors , 2008 .

[13]  Vasile Palade,et al.  Class Imbalance Learning Methods for Support Vector Machines , 2013 .

[14]  Igor Kononenko,et al.  Estimating Attributes: Analysis and Extensions of RELIEF , 1994, ECML.

[15]  H. Chojer,et al.  Development of low-cost indoor air quality monitoring devices: Recent advancements. , 2020, The Science of the total environment.

[16]  Yong Yin,et al.  A feature extraction method based on wavelet packet analysis for discrimination of Chinese vinegars using a gas sensors array , 2008 .

[17]  R. Gutierrez-Osuna,et al.  Active temperature modulation of metal-oxide sensors for quantitative analysis of gas mixtures , 2013 .

[18]  S. De Vito,et al.  Dynamic neural network architectures for on field stochastic calibration of indicative low cost air quality sensing systems , 2016 .

[19]  Jorge Cadima,et al.  Principal component analysis: a review and recent developments , 2016, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[20]  Comparison of information content of temporal response of chemoresistive gas sensor under three different temperature modulation regimes for gas detection of different feature reduction methods , 2017 .

[21]  Thomas G. Dietterich,et al.  Learning with Many Irrelevant Features , 1991, AAAI.

[22]  C. Xie,et al.  Temperature & light modulation to enhance the selectivity of Pt-modified zinc oxide gas sensor , 2017 .

[23]  F. Annanouch,et al.  Hydrodynamic evaluation of gas testing chamber: Simulation, experiment , 2019, Sensors and Actuators B: Chemical.

[24]  Eugenio Martinelli,et al.  Self-adapted temperature modulation in metal-oxide semiconductor gas sensors , 2012 .

[25]  B. Reedy,et al.  Temperature modulation in semiconductor gas sensing , 1999 .

[26]  B. Sorli,et al.  A review on flexible gas sensors: From materials to devices , 2018, Sensors and Actuators A: Physical.

[27]  Randal S. Olson,et al.  Benchmarking Relief-Based Feature Selection Methods , 2017, J. Biomed. Informatics.

[28]  Xu Yang,et al.  Identification of gas mixtures via sensor array combining with neural networks , 2021 .

[29]  E. Martinelli,et al.  Feature extraction of metal oxide gas sensors using dynamic moments , 2007 .

[30]  Stephen Kwek,et al.  Applying Support Vector Machines to Imbalanced Datasets , 2004, ECML.

[31]  R. Tauler,et al.  Multivariate curve resolution applied to temperature-modulated metal oxide gas sensors , 2010 .

[32]  N. Barsan,et al.  Fundamental and practical aspects in the design of nanoscaled SnO2 gas sensors: a status report , 1999 .

[33]  S. Pratsinis,et al.  Selective formaldehyde detection at ppb in indoor air with a portable sensor. , 2020, Journal of hazardous materials.

[34]  Xiang Wang,et al.  Bearing Fault Diagnosis Based on Statistical Locally Linear Embedding , 2015, Sensors.

[35]  V. Georgescu,et al.  Miniaturised MOX based sensors for pollutant and explosive gases detection , 2017 .

[36]  Alena Bartonova,et al.  In search of an optimal in-field calibration method of low-cost gas sensors for ambient air pollutants: Comparison of linear, multilinear and artificial neural network approaches , 2019, Atmospheric Environment.

[37]  M. Bendahan,et al.  Data Analysis-Based Gas Identification with a Single Metal Oxide Sensor Operating in Dynamic Temperature Regime , 2019 .

[38]  Jong‐Heun Lee,et al.  Dual-mode gas sensor for ultrasensitive and highly selective detection of xylene and toluene using Nb-doped NiO hollow spheres , 2019 .

[39]  L. Morawska,et al.  Smart homes and the control of indoor air quality , 2018, Renewable and Sustainable Energy Reviews.

[40]  Mobasshir Mahbub,et al.  IoT-Cognizant cloud-assisted energy efficient embedded system for indoor intelligent lighting, air quality monitoring, and ventilation , 2020, Internet Things.

[41]  P. K. Guha,et al.  Single resistive sensor for selective detection of multiple VOCs employing SnO2 hollowspheres and machine learning algorithm: A proof of concept , 2020 .

[42]  A. Kalaivani,et al.  A Survey on Methodologies for Handling Imbalance Problem in Multiclass Classification , 2020 .

[43]  Fanli Meng,et al.  Gas sensing behavior of a single tin dioxide sensor under dynamic temperature modulation , 2004 .

[44]  Karl Pearson F.R.S. LIII. On lines and planes of closest fit to systems of points in space , 1901 .

[45]  Thomas G. Dietterich,et al.  Solving Multiclass Learning Problems via Error-Correcting Output Codes , 1994, J. Artif. Intell. Res..

[46]  Larry A. Rendell,et al.  A Practical Approach to Feature Selection , 1992, ML.

[47]  Michele Penza,et al.  Low-cost sensors for outdoor air quality monitoring , 2020 .

[48]  Juan Manuel Jiménez-Soto,et al.  Estimation of the limit of detection in semiconductor gas sensors through linearized calibration models. , 2018, Analytica chimica acta.

[49]  Vladimir Vapnik,et al.  Support-vector networks , 2004, Machine Learning.

[50]  J. K. Radhakrishnan,et al.  Effect of temperature modulation, on the gas sensing characteristics of ZnO nanostructures, for gases O2, CO and CO2 , 2021 .

[51]  Aapo Hyvärinen,et al.  Independent component analysis: recent advances , 2013, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[52]  B. J. Kim,et al.  Fabrication of a room-temperature NO2 gas sensor using morphology controlled CVD-grown tellurium nanostructures , 2020, Sensors and Actuators B: Chemical.

[53]  Identifying Binary Mixtures of Volatile Organic Compounds With Isomeric Components Using a Single Thermal Shock-Induced Generic SnO2 Gas Sensor , 2020, IEEE Sensors Journal.

[54]  Xue-wen Chen An improved branch and bound algorithm for feature selection , 2003, Pattern Recognit. Lett..

[55]  S. D. Vito,et al.  CO, NO2 and NOx urban pollution monitoring with on-field calibrated electronic nose by automatic bayesian regularization , 2009 .

[56]  Thomas G. Dietterich,et al.  Efficient Algorithms for Identifying Relevant Features , 1992 .

[57]  David E. Motaung,et al.  A review on recent progress of p-type nickel oxide based gas sensors: Future perspectives , 2019, Journal of Alloys and Compounds.

[58]  Corrado Di Natale,et al.  Optimizing MOX sensor array performances with a reconfigurable self-adaptive temperature modulation interface , 2021 .

[59]  Yunqian Ma,et al.  Imbalanced Learning: Foundations, Algorithms, and Applications , 2013 .

[60]  Haibo He,et al.  ADASYN: Adaptive synthetic sampling approach for imbalanced learning , 2008, 2008 IEEE International Joint Conference on Neural Networks (IEEE World Congress on Computational Intelligence).

[61]  Eduard Llobet,et al.  An alternative global feature extraction of temperature modulated micro-hotplate gas sensors array using an energy vector approach , 2007 .

[62]  Thomas Marill,et al.  On the effectiveness of receptors in recognition systems , 1963, IEEE Trans. Inf. Theory.

[63]  Ananya Dey,et al.  Semiconductor metal oxide gas sensors: A review , 2018 .

[64]  V. Swaminathan,et al.  A novel hypergraph-based feature extraction technique for boiler flue gas components classification using PNN – A computational model for boiler flue gas analysis , 2017 .

[65]  Chih-Jen Lin,et al.  A comparison of methods for multiclass support vector machines , 2002, IEEE Trans. Neural Networks.

[66]  K. Persaud,et al.  A smart gas sensor for monitoring environmental changes in closed systems: results from the MIR space station , 1999 .

[67]  Luyu Wang Metal-organic frameworks for QCM-based gas sensors: A review , 2020, Sensors and Actuators A: Physical.

[68]  Khalifa Aguir,et al.  High performance of a gas identification system using sensor array and temperature modulation , 2007 .

[69]  Jung-Sik Kim,et al.  Recent advances on H2 sensor technologies based on MOX and FET devices: A review , 2018, Sensors and Actuators B: Chemical.

[70]  Gholam Hossein Roshani,et al.  Applicability of time-domain feature extraction methods and artificial intelligence in two-phase flow meters based on gamma-ray absorption technique , 2021 .

[71]  Eduard Llobet,et al.  Wavelet transform-based fast feature extraction from temperature modulated semiconductor gas sensors , 2002 .

[72]  Wenjing Yuan,et al.  Selective detection of methane by Pd-In2O3 sensors with a catalyst filter film , 2021 .

[73]  Keinosuke Fukunaga,et al.  A Branch and Bound Algorithm for Feature Subset Selection , 1977, IEEE Transactions on Computers.

[74]  Wenjing Yuan,et al.  Selective detection of methane by HZSM-5 zeolite/Pd-SnO2 gas sensors , 2020 .

[75]  N. Donato,et al.  Temperature modulated Cu-MOF based gas sensor with dual selectivity to acetone and NO2 at low operating temperatures , 2020 .

[76]  Dong Xiang,et al.  Metal Oxide Gas Sensors: Sensitivity and Influencing Factors , 2010, Sensors.