Magnetization directions of individual nanoparticles

The magnetization directions of individual monodomain nanoparticles as small as 5 nanometers in diameter are determined using the Foucault method of Lorentz microscopy. A model is developed to explain the images and diffraction patterns of samarium cobalt nanoparticles as a function of the aperture shift direction. Thermally induced changes in the magnetization direction of superparamagnetic magnetite nanoparticles were observed but with a much slower rate than expected, due to surface anisotropy. When the time scale for magnetization reversal is much shorter than the data acquisition time, as in carbon-coated iron cobalt alloy nanoparticles, the images show an average of such thermally induced changes.

[1]  Andrew D. Kent,et al.  Growth of High Aspect Ratio Nanometer-Scale Magnets with Chemical Vapor Deposition and Scanning Tunneling Microscopy , 1993, Science.

[2]  R. Mccurrie,et al.  Ferromagnetic materials : structure and properties , 1994 .

[3]  Stephen Y. Chou,et al.  Nanolithographically defined magnetic structures and quantum magnetic disk (invited) , 1996 .

[4]  A. Hütten,et al.  LORENTZ MICROSCOPY OF GIANT MAGNETORESISTIVE AU-CO ALLOYS , 1995 .

[5]  M. McHenry,et al.  Magnetic Properties and Ordering in C-Coated FexCo1-x Alloy Nanocrystals , 1998 .

[6]  Scott,et al.  Morphology, structure, and growth of nanoparticles produced in a carbon arc. , 1995, Physical review. B, Condensed matter.

[7]  H. Fuller,et al.  Domains in Thin Magnetic Films Observed by Electron Microscopy , 1960 .

[8]  R. Mccurrie,et al.  The observation of magnetic domain structures of the intermetallic compounds SmCo5, LaCo5 and CeCo5 , 1970 .

[9]  Zhong Lin Wang Structural Analysis of Self-Assembling Nanocrystal Superlattices , 1998 .

[10]  S. Schultz,et al.  Observation of thermal switching of a single ferromagnetic particle , 1993 .

[11]  H. Kronmüller,et al.  The coercive field of sintered and melt-spun NdFeB magnets , 1987 .

[12]  M. Graef,et al.  Energy filtered Lorentz microscopy , 1997 .

[13]  W. Brown Rigorous Approach to the Theory of Ferromagnetic Microstructure , 1958 .

[14]  D. A. Dunnett Classical Electrodynamics , 2020, Nature.

[15]  S. Majetich,et al.  Magnetization Reversal In SmCo/sub 5/ Nanoparticles , 1997, 1997 IEEE International Magnetics Conference (INTERMAG'97).

[16]  Berkowitz,et al.  Surface Spin Disorder in NiFe2O4 Nanoparticles. , 1996, Physical review letters.

[17]  D. Bohm,et al.  Significance of Electromagnetic Potentials in the Quantum Theory , 1959 .

[18]  F. Pfeifer,et al.  Soft magnetic Ni-Fe and Co-Fe alloys - some physical and metallurgical aspects , 1980 .

[19]  S. Charap,et al.  Thermal stability of recorded information at high densities , 1996 .

[20]  E. Wohlfarth,et al.  A mechanism of magnetic hysteresis in heterogeneous alloys , 1948, Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences.

[21]  E. Kneller,et al.  Particle Size Dependence of Coercivity and Remanence of Single‐Domain Particles , 1963 .

[22]  D. Wohlleben Diffraction Effects in Lorentz Microscopy , 1967 .

[23]  Dominique Mailly,et al.  Experimental evidence of the Neel-Brown model of magnetization reversal , 1997 .

[24]  S. Schultz,et al.  Measuring the coercivity of individual sub-micron ferromagnetic particles by Lorentz microscopy , 1991 .

[25]  Emil Wolf,et al.  Principles of Optics: Contents , 1999 .