Environmental and Economic Assessment of Electrothermal Swing Adsorption of Air Emissions from Sheet-Foam Production Compared to Conventional Abatement Techniques.

A life-cycle assessment (LCA) and cost analysis are presented comparing the environmental and economic impacts of using regenerative thermal oxidizer (RTO), granular activated carbon (GAC), and activated carbon fiber cloth (ACFC) systems to treat gaseous emissions from sheet-foam production. The ACFC system has the lowest operational energy consumption (i.e., 19.2, 8.7, and 3.4 TJ/year at a full-scale facility for RTO, GAC, and ACFC systems, respectively). The GAC system has the smallest environmental impacts across most impact categories for the use of electricity from select states in the United States that produce sheet foam. Monte Carlo simulations indicate the GAC and ACFC systems perform similarly (within one standard deviation) for seven of nine environmental impact categories considered and have lower impacts than the RTO for every category for the use of natural gas to produce electricity. The GAC and ACFC systems recover adequate isobutane to pay for themselves through chemical-consumption offsets, whereas the net present value of the RTO is $4.1 M (20 years, $0.001/m(3) treated). The adsorption systems are more environmentally and economically competitive than the RTO due to recovered isobutane for the production process and are recommended for resource recovery from (and treatment of) sheet-foam-production exhaust gas. Research targets for these adsorption systems should focus on increasing adsorptive capacity and saturation of GAC systems and decreasing electricity and N2 consumption of ACFC systems.

[1]  Bo Pedersen Weidema,et al.  Data quality management for life cycle inventories—an example of using data quality indicators☆ , 1996 .

[2]  Qiong Zhang,et al.  Adsorption and Regeneration on Activated Carbon Fiber Cloth for Volatile Organic Compounds at Indoor Concentration Levels , 2009, Journal of the Air & Waste Management Association.

[3]  Thilde Fruergaard,et al.  Life-cycle assessment of selected management options for air pollution control residues from waste incineration. , 2010, The Science of the total environment.

[4]  Douglas M. Ruthven,et al.  Principles of Adsorption and Adsorption Processes , 1984 .

[5]  G. Norris Impact Characterization in the Tool for the Reduction and Assessment of Chemical and Other Environmental Impacts , 2002 .

[6]  G. Grévillot,et al.  Temperature-swing gas separation with electrothermal desorption step , 1991 .

[7]  Hans-Jürgen Dr. Klüppel,et al.  The Revision of ISO Standards 14040-3 - ISO 14040: Environmental management – Life cycle assessment – Principles and framework - ISO 14044: Environmental management – Life cycle assessment – Requirements and guidelines , 2005 .

[8]  G. Denafas,et al.  LCA-BASED COMPARISON OF VOC REMOVAL FROM EXHAUST GASES BY PLASMA AND "CONVENTIONAL" END-OF-PIPE METHODS , 2011 .

[9]  Robert A Zerbonia,et al.  Carbon Bed Fires and the Use of Carbon Canisters for Air Emissions Control on Fixed-Roof Tanks , 2001, Journal of the Air & Waste Management Association.

[10]  R. T. Yang,et al.  Gas Separation by Adsorption Processes , 1987 .

[11]  Callie W. Babbitt,et al.  Design-based life cycle assessment of hazardous air pollutant control options at pulp and paper mills: a comparison of thermal oxidation to photocatalytic oxidation and biofiltration , 2009 .

[12]  William E. Franklin,et al.  Environmental tradeoffs: Life cycle approach to evaluate the burdens and benefits of emission control systems in the wood panel industry , 2002 .

[13]  Faisal Khan,et al.  Removal of Volatile Organic Compounds from polluted air , 2000 .

[14]  David L Johnsen,et al.  Capture and recovery of isobutane by electrothermal swing adsorption with post-desorption liquefaction. , 2010, Environmental science & technology.

[15]  Mark J. Rood,et al.  Adsorption and Electrothermal Desorption of Hazardous Organic Vapors , 2001 .

[16]  M. Rood,et al.  Capture of Organic Vapors Using Adsorption and Electrothermal Regeneration , 2004 .

[17]  P. Cloirec Adsorption onto Activated Carbon Fiber Cloth and Electrothermal Desorption of Volatile Organic Compound (VOCs): A Specific Review , 2012 .

[18]  G. Norris,et al.  TRACI the tool for the reduction and assessment of chemical and other environmental impacts , 2002 .

[19]  Dc Washington,et al.  USEPA. Reregistration Eligibility Decision (RED): 738‐R‐99‐004. United States Environmental Protection Agency, Prevention, Pesticides and Toxic Substances (7508C): 337 pp. , 1999 .

[20]  Julia Frankfurter,et al.  Air Pollution Control A Design Approach , 2016 .