论文信息 - Tetrazole compounds. 11. electron impact mass spectrometry of 1‐aryl‐5‐(l‐acyl‐2‐dialkylaminovinyl)‐1H‐tetrazoles

Tetrazole compounds. 11. electron impact mass spectrometry of 1‐aryl‐5‐(l‐acyl‐2‐dialkylaminovinyl)‐1H‐tetrazoles

The mass spectrometric behaviour of 1-aryl-5-(1-acyl-2-dialkylaminovinyl)-1H-tetrazoles was studied, especially using 1-phenyl-5-(1-benzoyl-2-dimethylaminovinyl)-1H-tetrazole 1 and its D-and 15N-labeled derivatives. All tetrazoles investigated showed a clearly observable molecular ion and underwent as the main fragmentation the elimination of nitrogen followed by a number of various subsequent processes. Besides, primary fragments such as [M − N3•]+ and [M — ArN3]+• were also observed.

M. Möder | G. Fischer | Herrmann Michael

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