Sn CONCENTRATION GRADIENTS IN POWDER-IN-TUBE SUPERCONDUCTORS

The Sn concentration gradients across the A15 phase have been studied by Energy Dispersive X-ray Spectroscopy (EDS) measurements. High spatial resolution EDS measurements in the Transmission Electron Microscope reveal a comparatively strong Sn concentration gradient from the periphery towards the centre of individual (Nb-Ta)3Sn grains.

[1]  K. Timmerhaus Advances in Cryogenic Engineering , 2012 .

[2]  T. Boutboul,et al.  Heat Treatment Optimization Studies on PIT ${\rm Nb}_{3}{\rm Sn}$ Strand for the NED Project , 2009, IEEE Transactions on Applied Superconductivity.

[3]  C. Senatore,et al.  Microstructure, composition and critical current density of superconducting Nb3Sn wires , 2008 .

[4]  David C. Larbalestier,et al.  Microstructural factors important for the development of high critical current density Nb3Sn strand , 2008 .

[5]  H. Kate,et al.  State of the art powder-in-tube niobium–tin superconductors , 2008 .

[6]  M. Di Michiel,et al.  Phase transformations during the reaction heat treatment of powder-in-tube Nb3Sn superconductors , 2007 .

[7]  M. Tomsic,et al.  Composition Profiles and Upper Critical Field Measurement of Internal-Sn and Tube-Type Conductors , 2007, IEEE Transactions on Applied Superconductivity.

[8]  D. Larbalestier,et al.  Measurements of the microstructural, microchemical and transition temperature gradients of A15 layers in a high-performance Nb3Sn powder-in-tube superconducting strand , 2006 .

[9]  D. Larbalestier,et al.  The influence of the starting Cu-Sn phase on the superconducting properties of subsequently reacted internal-Sn Nb/sub 3/Sn conductors , 2001 .

[10]  C. Thieme,et al.  Grain boundary compositions, transport and flux pinning of multifilamentary Nb/sub 3/Sn wires , 1995, IEEE Transactions on Applied Superconductivity.

[11]  W. Jansen,et al.  Chemical compositions at and near the grain boundaries in bronze‐processed superconducting Nb3Sn , 1983 .

[12]  H. Veringa,et al.  Growth kinetics and characterization of superconducting properties of multifilament materials made by the ECN powder method , 1983 .

[13]  C. M. Fischer INVESTIGATION OF THE RELATIONSHIPS BETWEEN SUPERCONDUCTING PROPERTIES AND Nb 3 Sn REACTION CONDITIONS IN POWDER-IN-TUBE NB 3 SN CONDUCTORS , 2002 .

[14]  J. Charlesworth,et al.  Experimental work on the niobium-tin constitution diagram and related studies , 1970 .