On relative permeability data uncertainty and CO2 injectivity estimation for brine aquifers

Performance assessment of possible CO2 storage schemes is often investigated through numerical simulation of the CO2 injection process. An important criterion of interest is the maximum sustainable injection rate. Relevant numerical models generally employ a multi-phase extension to Darcy's law, requiring data concerning the evolution of relative permeability for CO2 and brine mixtures with increasing CO2 saturation. Relative permeability data is acutely scarce for many geographical regions of concern and often cited as a major source of uncertainty. However, such data is expensive and time consuming to acquire. With a view to improving our understanding concerning the significance of relative permeability uncertainty on injectivity, this article presents a sensitivity analysis of sustainable CO2 injection rate with respect to permeability, porosity and relative permeability. Based on available relative permeability data obtained from 25 sandstone and carbonate cores discussed in the literature, injectivity uncertainty associated with relative permeability is found to be as high as ±57% for open aquifers and low permeability closed aquifers ( 100 mD), aquifer compressibility plays a more important role and the uncertainty due to relative permeability is found to reduce to ±6%.

[1]  Franklin M. Orr,et al.  Theory of Gas Injection Processes , 2005 .

[2]  Karsten Pruess,et al.  CO2-H2O mixtures in the geological sequestration of CO2. I. Assessment and calculation of mutual solubilities from 12 to 100°C and up to 600 bar , 2003 .

[3]  Eric James Mackay,et al.  Simulation of near-well pressure build-up in models of CO2 injection , 2012 .

[4]  Robert W. Zimmerman,et al.  Approximate Solutions for Pressure Buildup During CO2 Injection in Brine Aquifers , 2009 .

[5]  McMillan Burton,et al.  Time-Dependent Injectivity During CO2 Storage in Aquifers , 2008 .

[6]  C. Tsang,et al.  A method for quick assessment of CO2 storage capacity in closed and semi-closed saline formations , 2008 .

[7]  Stefan Bachu,et al.  Effects of in-situ conditions on relative permeability characteristics of CO2-brine systems , 2008 .

[8]  W. Wakeham,et al.  The Viscosity of Carbon Dioxide , 1998 .

[9]  McMillan Burton,et al.  CO2 injectivity into brine aquifers: Why relative permeability matters as much as absolute permeability , 2009 .

[10]  Zhijing Wang,et al.  Seismic properties of pore fluids , 1992 .

[11]  Sally M. Benson,et al.  Relative permeability and trapping of CO2 and water in sandstone rocks at reservoir conditions , 2012 .

[12]  K. Pruess ECO2N: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2 , 2005 .

[13]  N. Müller Supercritical CO2-Brine Relative Permeability Experiments in Reservoir Rocks—Literature Review and Recommendations , 2011 .

[14]  S. Durucan,et al.  Experimental investigation into salt precipitation during CO2 injection in saline aquifers , 2011 .

[15]  K. Pruess,et al.  Thermohydrological conditions and silica redistribution near high‐level nuclear wastes emplaced in saturated geological formations , 1988 .

[16]  Sally M. Benson,et al.  An Experimental Study on the Influence of Sub-Core Scale Heterogeneities on CO2 Distribution in Reservoir Rocks , 2010 .

[17]  Jan M. Nordbotten,et al.  Injection and Storage of CO2 in Deep Saline Aquifers: Analytical Solution for CO2 Plume Evolution During Injection , 2005 .

[18]  Jeffrey A. Cunningham,et al.  Temporal variations in near-wellbore pressures during CO2 injection in saline aquifers , 2011 .

[19]  William Guy Allinson,et al.  CO2 Storage Capacity - Combining Geology, Engineering and Economics , 2010 .

[20]  Eric James Mackay,et al.  A Sensitivity Study on CO2 Storage in Saline Aquifers , 2011 .

[21]  Robert W. Zimmerman,et al.  Pressure Buildup During CO2 Injection into a Closed Brine Aquifer , 2011 .

[22]  Stefan Bachu,et al.  Drainage and Imbibition Relative Permeability Relationships for Supercritical CO2/Brine and H2S/Brine Systems in Intergranular Sandstone, Carbonate, Shale, and Anhydrite Rocks , 2008 .

[23]  A. Bismarck,et al.  Interfacial Tension Measurements of the (H2O + CO2) System at Elevated Pressures and Temperatures† , 2010 .

[24]  Karsten Pruess,et al.  Formation dry‐out from CO2 injection into saline aquifers: 1. Effects of solids precipitation and their mitigation , 2009 .

[25]  C. Ehlig-Economides,et al.  Sequestering carbon dioxide in a closed underground volume , 2010 .

[26]  Kamy Sepehrnoori,et al.  Three-Phase Gas/Oil/Brine Relative Permeabilities Measured under CO2 Flooding Conditions , 1993 .

[27]  David William Keith,et al.  Analytical Solution to Evaluate Salt Precipitation during CO2 Injection in Saline Aquifers , 2009 .

[28]  F. G. McCaffery,et al.  An Improved Unsteady-State Procedure for Determining the Relative-Permeability Characteristics of Heterogeneous Porous Media (includes associated papers 8028 and 8777 ) , 1979 .

[29]  E. F. Johnson,et al.  Calculation of Relative Permeability from Displacement Experiments , 1959 .

[30]  Karsten Pruess,et al.  ECO2N – A fluid property module for the TOUGH2 code for studies of CO2 storage in saline aquifers , 2007 .

[31]  Van Genuchten,et al.  A closed-form equation for predicting the hydraulic conductivity of unsaturated soils , 1980 .

[32]  Karsten Pruess,et al.  CO2-H2O Mixtures in the Geological Sequestration of CO2. II. Partitioning in Chloride Brines at 12-100oC and up to 600 bar , 2004 .

[33]  Jun-Ho Oh,et al.  Characteristics of Salt-Precipitation and the Associated Pressure Build-Up during CO2 Storage in Saline Aquifers , 2012, Transport in Porous Media.

[34]  S. Holloway,et al.  Flow processes and pressure evolution in aquifers during the injection of supercritical CO2 as a greenhouse gas mitigation measure , 2009 .

[35]  Seyyed A. Hosseini,et al.  Role of partial miscibility on pressure buildup due to constant rate injection of CO2 into closed and open brine aquifers , 2011 .