High-resolution electrohydrodynamic jet printing.

Efforts to adapt and extend graphic arts printing techniques for demanding device applications in electronics, biotechnology and microelectromechanical systems have grown rapidly in recent years. Here, we describe the use of electrohydrodynamically induced fluid flows through fine microcapillary nozzles for jet printing of patterns and functional devices with submicrometre resolution. Key aspects of the physics of this approach, which has some features in common with related but comparatively low-resolution techniques for graphic arts, are revealed through direct high-speed imaging of the droplet formation processes. Printing of complex patterns of inks, ranging from insulating and conducting polymers, to solution suspensions of silicon nanoparticles and rods, to single-walled carbon nanotubes, using integrated computer-controlled printer systems illustrates some of the capabilities. High-resolution printed metal interconnects, electrodes and probing pads for representative circuit patterns and functional transistors with critical dimensions as small as 1 mum demonstrate potential applications in printed electronics.

[1]  Stephen R. Forrest,et al.  The path to ubiquitous and low-cost organic electronic appliances on plastic , 2004, Nature.

[2]  Geoffrey Ingram Taylor,et al.  Disintegration of water drops in an electric field , 1964, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[3]  D. J. Rose,et al.  Inkjet dispensing technology: applications in drug discovery. , 1998, Current opinion in biotechnology.

[4]  R. Street,et al.  Hydrogenated amorphous silicon thin-film transistor arrays fabricated by digital lithography , 2003, IEEE Electron Device Letters.

[5]  Vivek Subramanian,et al.  Film Morphology and Thin Film Transistor Performance of Solution-Processed Oligothiophenes , 2004 .

[6]  J. Rogers,et al.  High-performance electronics using dense, perfectly aligned arrays of single-walled carbon nanotubes. , 2007, Nature nanotechnology.

[7]  Tatsuya Shimoda,et al.  Solution-processed silicon films and transistors , 2006, Nature.

[8]  Oleg V. Salata,et al.  Tools of Nanotechnology: Electrospray , 2005 .

[9]  John A Rogers,et al.  Spatially selective guided growth of high-coverage arrays and random networks of single-walled carbon nanotubes and their integration into electronic devices. , 2006, Journal of the American Chemical Society.

[10]  P. Calvert Inkjet Printing for Materials and Devices , 2001 .

[11]  James C. Sturm,et al.  Local tuning of organic light-emitting diode color by dye droplet application , 1998 .

[12]  Richard H. Friend,et al.  Lithography‐Free, Self‐Aligned Inkjet Printing with Sub‐Hundred‐Nanometer Resolution , 2005 .

[13]  M. Heller DNA microarray technology: devices, systems, and applications. , 2002, Annual review of biomedical engineering.

[14]  Qian Wang,et al.  Electrical contacts to carbon nanotubes down to 1nm in diameter , 2005 .

[15]  小口 寿彦 IS & T's NIP 19 International Conference on Digital Printing Technologies報告 , 2003 .

[16]  Ilhan A. Aksay,et al.  Scaling laws for pulsed electrohydrodynamic drop formation , 2006 .

[17]  M. Edirisinghe,et al.  Electric-field driven jetting from dielectric liquids , 2004 .

[18]  Wolfgang Kowalsky,et al.  Large Area Electronics Using Printing Methods , 2005, Proceedings of the IEEE.

[19]  H. Sirringhaus,et al.  High-Resolution Ink-Jet Printing of All-Polymer Transistor Circuits , 2000, Science.

[20]  John A Rogers,et al.  In situ deposition and patterning of single-walled carbon nanotubes by laminar flow and controlled flocculation in microfluidic channels. , 2006, Angewandte Chemie.

[21]  H. Sirringhaus,et al.  Self-Aligned, Vertical-Channel, Polymer Field-Effect Transistors , 2003, Science.

[22]  Martin Hegner,et al.  Rapid functionalization of cantilever array sensors by inkjet printing , 2004 .

[23]  Yang Yang,et al.  Multicolor Organic Light-Emitting Diodes Processed by Hybrid Inkjet Printing** , 1999 .

[24]  Yang Yang,et al.  Ink-Jet Printing, Self-Assembled Polyelectrolytes, and Electroless Plating: Low Cost Fabrication of Circuits on a Flexible Substrate at Room Temperature , 2005 .

[25]  Zhenan Bao,et al.  Thin Film Deposition, Patterning, and Printing in Organic Thin Film Transistors , 2004 .

[26]  Jian Gu,et al.  Low-cost fabrication of submicron all polymer field effect transistors , 2006 .

[27]  M. Rubner,et al.  Reversibly erasable nanoporous anti-reflection coatings from polyelectrolyte multilayers , 2002, Nature materials.

[28]  I. Hayati,et al.  Investigations into the mechanisms of electrohydrodynamic spraying of liquids. I: Effect of electric field and the environment on pendant drops and factors affecting the formation of stable jets and atomization , 1987 .

[29]  John A Rogers,et al.  A printable form of single-crystalline gallium nitride for flexible optoelectronic systems. , 2005, Small.

[30]  Observation of strong direct-like oscillator strength in the photoluminescence of Si nanoparticles , 2005 .

[31]  Hiroyuki Kawamoto,et al.  Fundamental investigation on electrostatic ink jet phenomena in pin-to-plate discharge system , 2005 .

[32]  James R. Sheats,et al.  Manufacturing and commercialization issues in organic electronics , 2004 .

[33]  Jie Zhang,et al.  Fine-line conductor manufacturing using drop-on demand PZT printing technology , 2002 .

[34]  Paul Smaglik,et al.  Proteomics technology: Character references , 2001, Nature.

[35]  U. Schubert,et al.  Inkjet Printing of Polymers: State of the Art and Future Developments , 2004 .

[36]  Katsuyuki Morii,et al.  Inkjet Printing of Light-Emitting Polymer Displays , 2003 .

[37]  Donald Hayes,et al.  Wafer level optoelectronic device packaging using MEMS (Invited Paper) , 2005, SPIE Microtechnologies.

[38]  J. Rogers,et al.  A printable form of silicon for high performance thin film transistors on plastic substrates , 2004 .

[39]  H. Sirringhaus,et al.  Inkjet Printing of Polymer Thin-Film Transistor Circuits , 2003 .

[40]  A. Vertes,et al.  Flexing the electrified meniscus: the birth of a jet in electrosprays. , 2004, Analytical chemistry.

[41]  Colin Nuckolls,et al.  Jet-printed electrodes and semiconducting oligomers for elaboration of organic thin-film transistors , 2006 .

[42]  Phaedon Avouris,et al.  The role of metal-nanotube contact in the performance of carbon nanotube field-effect transistors. , 2005, Nano letters.

[43]  L. Creagh,et al.  Design and Performance of Inkjet Print Heads for Non-Graphic-Arts Applications , 2003 .

[44]  John McGregor,et al.  Mix and Match , 2008, J. Object Technol..