论文信息 - MECHANISM OF CHARGE-TRANSFER POLYMERIZATION: PHOTOSENSITIZED CHARGE-TRANSFER COPOLYMERIZATIONS OF N-VINYLINDOLE WITH ELECTRON-ACCEPTING MONOMERS

MECHANISM OF CHARGE-TRANSFER POLYMERIZATION: PHOTOSENSITIZED CHARGE-TRANSFER COPOLYMERIZATIONS OF N-VINYLINDOLE WITH ELECTRON-ACCEPTING MONOMERS

It was found for the first time that N-vinylindole was copolymerized with such electron-accepting monomers as fumaronitrile or diethyl fumarate to yield 1:1 alternating copolymers by photopoirradiation. The initiation process of the photolymerization was suggested to involve the charge-transfer or probably electron transfer from N-vinylindole to the electron-accepting monomer in the electronically excited state.

H. Mikawa | Y. Shirota | Y. Oshiro

[1] H. Mikawa,et al. Mechanism of Charge-Transfer Polymerization. IV. Multiplicity of the Reaction Course in the Photosensitized Reaction of N-Vinylcarbazole in the Presence of the Organic Electron Acceptor , 1973 .

[2] E. Gipstein,et al. Polymerization and Copolymerization of N-Vinylindole and N-Vinylmethylindoles , 1969 .