Ultrastable particle-stabilized foams.

Pump up the volume: Wet foams prepared with surfactants are thermodynamically unstable systems that undergo rapid disproportionation, drainage, and coalescence. Ultrastable foams have now been prepared using colloidal particles as stabilizers (left picture). The stabilization results from the irreversible adsorption at the air–water interface of particles surface-modified with short-chain amphiphiles (right picture).

[1]  B. Binks Particles as surfactants—similarities and differences , 2002 .

[2]  T. Gao,et al.  The optimum wetting angle for the stabilization of liquid-metal foams by ceramic particles: Experimental simulations , 2002 .

[3]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[4]  H. Christenson,et al.  Direct Measurements of the Force between Hydrophobic Surfaces in Water , 2001 .

[5]  Reinhard Miller,et al.  Dynamic surface and interfacial tensions of surfactant and polymer solutions , 1994 .

[6]  C. Prestidge,et al.  Hydrophobic Interactions in Concentrated Colloidal Suspensions: A Rheological Investigation , 2004 .

[7]  Larry L Hench,et al.  Third-Generation Biomedical Materials , 2002, Science.

[8]  D. Fuerstenau,et al.  Flocculation and flotation characteristics of fine hematite with sodium oleate , 2003 .

[9]  Rammile Ettelaie,et al.  Factors controlling the formation and stability of air bubbles stabilized by partially hydrophobic silica nanoparticles. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[10]  B. Murray,et al.  Foam stability: proteins and nanoparticles , 2004 .

[11]  D. Fuerstenau,et al.  Self-association and reverse hemimicelle formation at solid–water interfaces in dilute surfactant solutions , 1999 .

[12]  G. Kaptay Interfacial criteria for stabilization of liquid foams by solid particles , 2003 .

[13]  Vesselin N Paunov,et al.  Foam superstabilization by polymer microrods. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[14]  M. Ashby,et al.  Metal Foams: A Design Guide , 2000 .

[15]  B. Binks,et al.  Aqueous foams stabilized solely by silica nanoparticles. , 2005, Angewandte Chemie.

[16]  J. Israelachvili,et al.  The hydrophobic interaction is long range, decaying exponentially with distance , 1982, Nature.

[17]  M. Bos,et al.  Network forming properties of various proteins adsorbed at the air/water interface in relation to foam stability. , 2002, Journal of colloid and interface science.

[18]  A. R. Bausch,et al.  Colloidosomes: Selectively Permeable Capsules Composed of Colloidal Particles , 2002, Science.

[19]  Rossen,et al.  Anomalous Capillary Pressure, Stress, and Stability of Solids-Coated Bubbles. , 1999, Journal of colloid and interface science.

[20]  L. Gauckler,et al.  Influence of the Dispersant Structure on Properties of Electrostatically Stabilized Aqueous Alumina , 1997 .

[21]  Bernard P. Binks,et al.  Emulsions stabilised solely by colloidal particles , 2003 .

[22]  A. Vrij,et al.  Synthesis and characterization of colloidal dispersions of fluorescent, monodisperse silica spheres , 1992 .

[23]  Bernard P. Binks,et al.  Outstanding Stability of Particle-Stabilized Bubbles , 2003 .

[24]  Shaoxian Song,et al.  Hydrophobic interaction in flocculation and flotation 1. Hydrophobic flocculation of fine mineral particles in aqueous solution , 1991 .

[25]  Phil Attard,et al.  BUBBLES, CAVITIES, AND THE LONG-RANGED ATTRACTION BETWEEN HYDROPHOBIC SURFACES , 1994 .

[26]  Bruno Carré,et al.  Role of surfactant structure on surface and foaming properties , 2001 .

[27]  D. Fuerstenau,et al.  The adsorption of alkyl and alkylbenzene sulfonates at mineral oxide–water interfaces , 2003 .