Explosive detection using pixellated X-ray diffraction (PixD)

A novel, pixellated, energy-resolving X-ray detector has been utilised to simultaneously combine angular and energy dispersive X-ray diffraction (XRD). This approach allows a system to measure XRD data using the benefits of both approaches. Data acquisition is fast, and the system contains no moving parts, making it ideal for applications in security, particularly for the detection of explosive materials hidden within packages or baggage. Explosive samples supplied by the Centre for Applied Science and Technology, U.K. were examined using the pixellated diffraction technique, and the XRD data were compared with those from inert materials typically found inside luggage. A method of processing the data was developed, which greatly reduces the amount of data outputted from the detector whilst preserving the angular and energy resolution. Using principal component and discriminant analyses, a model was developed which predicts the correct classification of an unknown sample as either ``explosive'' or ``inert'' for data with acquisition times as low as one second.

[1]  Robert D. Speller,et al.  A CdZnTe array for the detection of explosives in baggage by energy-dispersive X-ray diffraction signatures at multiple scatter angles , 2000 .

[2]  R D Speller,et al.  Pixellated Cd(Zn)Te high-energy X-ray instrument. , 2011, Journal of instrumentation : an IOP and SISSA journal.

[3]  R. D. Luggar,et al.  Multivariate analysis of statistically poor EDXRD spectra for the detection of concealed explosives , 1998 .

[4]  R. Suryanarayanan,et al.  Identification of drugs in pharmaceutical dosage forms by X-ray powder diffractometry. , 1997, Journal of pharmaceutical and biomedical analysis.

[5]  L. George,et al.  Multivariate Data Analysis for Drug Identification Using Energy-Dispersive X-Ray Diffraction , 2009, IEEE Transactions on Nuclear Science.

[6]  R. D. Luggar,et al.  Multivariate calibration for quantitative analysis of EDXRD spectra from a bone phantom. , 1997, Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine.

[7]  B. Kämpfe,et al.  Energy Dispersive X‐Ray Diffraction , 2005 .

[8]  Matthew D. Wilson,et al.  HEXITEC ASIC—a pixellated readout chip for CZT detectors , 2009 .

[9]  Matthew C. Veale,et al.  Pixelated diffraction signatures for explosive detection , 2012, Other Conferences.

[10]  Robert Speller,et al.  Energy dispersive X-ray diffraction as a means to identify illicit materials: a preliminary optimisation study. , 2007, Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine.

[11]  Robert D. Speller,et al.  Multivariate analysis of pixelated diffraction data , 2011 .