Assessment of spatial and seasonal water quality variation of Oum Er Rbia River (Morocco) using multivariate statistical techniques

Abstract The aim of this study is to assess the spatial and temporal water quality variation and to determine the main contamination sources in the Oum Er Rbia River and its main tributary, El Abid River. The water quality data were collected during 2000–2012 from fourteen sampling stations distributed along the river. The water quality indicators used were TEMP, pH, EC, turbidity, TSS, DO, NH4+, NH3–, TP, BOD5, COD and F. coli. The water quality data was analyzed using multivariate statistical methods including Pearson's correlation, PCA, and CA. The results showed that in some stations the water quality parameters were over Moroccan water standards. PCA applied to compare the compositional patterns among the analyzed water samples, identified and four factors accounting for almost 63% of the total variation in the data. This suggests that the variations in water compounds’ concentration are mainly related to point source contamination (domestic and industrial wastewater), non-point source contamination (agriculture activities), as well as natural processes (weathering of soil and rock). CA showed relatively spatial and seasonal changes in surface water quality, which are usually indicators of contamination with rainfalls or other sources. Overall, this study showed that the water was potentially hazardous to health of the consumers and highlighted the need to treat industrial and municipal wastewater and to encourage sustainable agricultural practices to prevent adverse health effects. We therefore suggest wise management of anthropogenic activities in the catchment of Oum Er Bia River and their tributaries.

[1]  Yong Liu,et al.  Application of Multivariate Statistical Methods to Water Quality Assessment of the Watercourses in Northwestern New Territories, Hong Kong , 2006, Environmental monitoring and assessment.

[2]  Subhankar Karmakar,et al.  Design of sampling locations for river water quality monitoring considering seasonal variation of point and diffuse pollution loads , 2015, Environmental Monitoring and Assessment.

[3]  R. Bouhlila,et al.  Hydrogeochemical characteristics and assessment of drinking water quality in Zeuss–Koutine aquifer, southeastern Tunisia , 2011, Environmental monitoring and assessment.

[4]  P. Martín-Alvarez,et al.  Evolution of the water quality of a managed natural wetland: Tablas de Daimiel National Park (Spain) , 2000 .

[5]  C. Mouneyrac,et al.  Tolerance and biomarkers as useful tools for assessing environmental quality in the Oued Souss estuary (Bay of Agadir, Morocco). , 2006, Comparative biochemistry and physiology. Toxicology & pharmacology : CBP.

[6]  L. Benaabidate,et al.  Diagnostic of physicochemical and bacteriological quality of fez wastewaters rejected in Sebou River: Morocco , 2011 .

[7]  Trung Hieu Nguyen,et al.  Temporal and spatial assessment of river surface water quality using multivariate statistical techniques: a study in Can Tho City, a Mekong Delta area, Vietnam , 2015, Environmental Monitoring and Assessment.

[8]  J. López-López,et al.  Multi-way analysis for decadal pollution trends assessment: the Guadalquivir River estuary as a case study. , 2014, Chemosphere.

[9]  H. Boyacıoğlu,et al.  Water pollution sources assessment by multivariate statistical methods in the Tahtali Basin, Turkey , 2008 .

[10]  D. Ducci,et al.  Impact of Past Mining Activity on the Quality of Water and Soil in the High Moulouya Valley (Morocco) , 2012, Water, Air, & Soil Pollution.

[11]  M. Varol,et al.  Assessment of surface water quality using multivariate statistical techniques: a case study of Behrimaz Stream, Turkey , 2009, Environmental monitoring and assessment.

[12]  Sunil Kumar Srivastava,et al.  Geochemical assessment of groundwater quality in vicinity of Bhalswa landfill, Delhi, India, using graphical and multivariate statistical methods , 2008 .

[13]  M. Fekhaoui,et al.  Impact of anthropogenic and natural processes on the degradation of water and sediment quality of the Mghohga River estuary (northern Morocco). , 2015 .

[14]  A. Rudolph,et al.  Dissolved Oxygen Content as an Index of Water Quality in San Vicente Bay, Chile (36°′S) , 2002 .

[15]  M. Exner,et al.  Microbial Load of Drinking Water Reservoir Tributaries during Extreme Rainfall and Runoff , 2002, Applied and Environmental Microbiology.

[16]  J. A. Baig,et al.  Assessment of water quality of polluted lake using multivariate statistical techniques: a case study. , 2009, Ecotoxicology and environmental safety.

[17]  B. S. Bali,et al.  Morphotectonic analysis of the Madhumati watershed, northeast Kashmir Valley , 2016, Arabian Journal of Geosciences.

[18]  R. Bouza-Deaño,et al.  Trend study and assessment of surface water quality in the Ebro River (Spain) , 2008 .

[19]  L. Benaabidate,et al.  RESEARCH ARTICLE Monitoring of heavy metals in the sediments of the Inaouene River, Morocco , 2011 .

[20]  Mohammad Firuz Ramli,et al.  Characterization of spatial patterns in river water quality using chemometric pattern recognition techniques. , 2012, Marine pollution bulletin.

[21]  H. Dahms,et al.  Multivariate water quality assessment from the Tamiraparani river basin, Southern India , 2014, Environmental Earth Sciences.

[22]  A. Ginebreda,et al.  Water toxicity assessment and spatial pollution patterns identification in a Mediterranean River Basin District. Tools for water management and risk analysis. , 2011, The Science of the total environment.

[23]  A. Barakat,et al.  Assessment of Heavy Metal in Surface Sediments of Day River at Beni-Mellal Region, Morocco , 2012 .

[24]  Ahmad Abrishamchi,et al.  Evaluation of spatial and temporal variation in water quality by pattern recognition techniques: A case study on Jajrood River (Tehran, Iran). , 2010, Journal of environmental management.

[25]  V. Lenoble,et al.  Organic carbon, and major and trace element dynamic and fate in a large river subjected to poorly-regulated urban and industrial pressures (Sebou River, Morocco). , 2015, The Science of the total environment.

[26]  Zhemin Shen,et al.  Water quality characteristics along the course of the Huangpu River (China). , 2007, Journal of environmental sciences.

[27]  Riffat Naseem Malik,et al.  Spatio-temporal variations in water quality of Nullah Aik-tributary of the river Chenab, Pakistan , 2008, Environmental monitoring and assessment.

[28]  Kao-Hung Lin,et al.  Application of factor analysis in the assessment of groundwater quality in a blackfoot disease area in Taiwan. , 2003, The Science of the total environment.

[29]  Kun Lei,et al.  Multivariate analysis of surface water quality in the Three Gorges area of China and implications for water management. , 2011, Journal of environmental sciences.

[30]  M. Fekhaoui,et al.  TYPOLOGY OF WATER QUALITY IN THE LOUKKOS RIVER ESTUARY (MOROCCO) , 2013 .

[31]  Manish Kumar,et al.  Identification and evaluation of hydrogeochemical processes in the groundwater environment of Delhi, India , 2006 .

[32]  Johnz Willett Similarity and Clustering in Chemical Information Systems , 1987 .

[33]  M. Forina,et al.  Clustering with dendrograms on interpretation variables , 2002 .

[34]  D. Chapman Selection of Water Quality Variables , 1996 .

[35]  Ashwani Kumar,et al.  Water quality index for assessment of water quality of river ravi at Madhopur (India) , 2010 .

[36]  Luis Deban,et al.  Assessment of seasonal and polluting effects on the quality of river water by exploratory data analysis , 1998 .

[37]  J. Mahlknecht,et al.  Groundwater chemistry and mass transfers in the Independence aquifer, central Mexico, by using multivariate statistics and mass-balance models , 2004 .

[38]  H. Juahir,et al.  Chemometric application in identifying sources of organic contaminants in Langat river basin , 2011, Environmental Monitoring and Assessment.

[39]  Asmaa Mourhir,et al.  River water quality index for Morocco using a fuzzy inference system , 2014, Environmental Systems Research.

[40]  S. Shrestha,et al.  Assessment of surface water quality using multivariate statistical techniques: A case study of the Fuji river basin, Japan , 2007, Environ. Model. Softw..

[41]  Carolina Mendiguchía,et al.  Using chemometric tools to assess anthropogenic effects in river water. A case study: Guadalquivir River (Spain) , 2004 .

[42]  Guangming Zeng,et al.  Assessment of surface water quality using multivariate statistical techniques in red soil hilly region: a case study of Xiangjiang watershed, China , 2009, Environmental monitoring and assessment.

[43]  Lin-zhang Yang,et al.  Anthropogenic Impact on Surface Water Quality in Taihu Lake Region, China , 2009 .

[44]  L. Benaabidate,et al.  Assessment of water quality and toxicity of polluted Rivers Fez and Sebou in the region of Fez (Morocco). , 2004, Environmental pollution.

[45]  Deborah V. Chapman,et al.  Water Quality Assessments: A Guide to the Use of Biota, Sediments and Water in Environmental Monitoring , 1996 .

[46]  B. D. Tripathi,et al.  Chemometric characterization of river water quality , 2013, Environmental Monitoring and Assessment.

[47]  A. Malik,et al.  WATER QUALITY ASSESSMENT AND APPORTIONMENT OF POLLUTION SOURCES OF GOMTI RIVER(INDIA) USING MULTIVARIATE STATISTICAL TECHNIQUES- A CASE STUDY , 2005 .

[48]  N. Chahinian,et al.  Water quality assessment of highly polluted rivers in a semi-arid Mediterranean zone Oued Fez and Sebou River (Morocco) , 2014 .

[49]  X. Xia,et al.  Trends of water quantity and water quality of the Yellow River from 1956 to 2009: implications for the effect of climate change , 2014, Environmental Systems Research.

[50]  Mohd Yawar Ali Khan,et al.  Assessment of surface water quality and its spatial variation. A case study of Ramganga River, Ganga Basin, India , 2015, Arabian Journal of Geosciences.

[51]  Rafael Borja,et al.  Use of the water quality index and dissolved oxygen deficit as simple indicators of watersheds pollution , 2007 .

[52]  B. Whitton,et al.  NITROGEN AND PHOSPHORUS IN EAST COAST BRITISH RIVERS: SPECIATION, SOURCES, AND BIOLOGICAL SIGNIFICANCE , 1998 .

[53]  G. Ozolins,et al.  Rolling Revision of the WHO Guidelines for Drinking-Water Quality , 2004 .

[54]  H. Kaiser The Application of Electronic Computers to Factor Analysis , 1960 .

[55]  Pei-Yu Liao,et al.  Spatial pattern assessment of river water quality: implications of reducing the number of monitoring stations and chemical parameters , 2014, Environmental Monitoring and Assessment.

[56]  S. Carpenter,et al.  NONPOINT POLLUTION OF SURFACE WATERS WITH PHOSPHORUS AND NITROGEN , 1998 .

[57]  V. Simeonov,et al.  Assessment of the surface water quality in Northern Greece. , 2003, Water research.

[58]  Desire L. Massart,et al.  The Interpretation of Analytical Chemical Data by the Use of Cluster Analysis , 1983 .

[59]  G. Ciudad,et al.  Nitrification-denitrification via nitrite accumulation for nitrogen removal from wastewaters. , 2006, Bioresource technology.

[60]  R. Hakkou,et al.  Impact of human activities on the physico-chemical quality of surface water and groundwater in the north of Marrakech (Morocco) , 2012, Environmental technology.

[61]  Other,et al.  Mediterranean climate variability , 2006 .

[62]  A. L. Lund,et al.  砂浜海岸の生息場所でOlivella minuta(腹足類,マクラガイ)やHastula cimerea(腹足類,タケノコガイ)をTBTの指標に利用した監視 , 2015 .

[63]  Prateek Sharma,et al.  Application of Multivariate Statistical Techniques in Determining the Spatial Temporal Water Quality Variation of Ganga and Yamuna Rivers Present in Uttarakhand State, India , 2015, Water Quality, Exposure and Health.

[64]  A. M. Idris Combining multivariate analysis and geochemical approaches for assessing heavy metal level in sediments from Sudanese harbors along the Red Sea coast , 2008 .

[65]  N. Samani,et al.  Geochemical evolution and quality assessment of water resources in the Sarcheshmeh copper mine area (Iran) using multivariate statistical techniques , 2013, Environmental Earth Sciences.

[66]  M. Yoneda,et al.  Does Embankment Improve Quality of a River? A Case Study in To Lich River Inner City Hanoi, with Special Reference to Heavy Metals , 2013 .