Simulation of CO2 plume movement in multilayered saline formations through multilayer injection technology in the Ordos Basin, China

Deep saline aquifers still remain a significant option for the disposal of large amounts of CO2 from the atmosphere as a means of mitigating global climate change. The small scale Carbon Capture and Sequestration demonstration project in Ordos Basin, China, operated by the Shenhua Group, is the only one of its kind in Asia, to put the multilayer injection technology into practice. This paper aims at studying the influence of temperature, injection rate and horizontal boundary effects on CO2 plume transport in saline formation layers at different depths and thicknesses, focusing on the variations in CO2 gas saturation and mass fraction of dissolved CO2 in the formation of brine in the plume’s radial three-dimensional field around the injection point, and interlayer communication between the aquifer and its confining beds of relatively lower permeability. The study uses the ECO2N module of TOUGH2 to simulate flow and pressure configurations in response to small-scale CO2 injection into multilayer saline aquifers. The modelling domain involves a complex multilayer reservoir–caprock system, comprising of a sequence of sandstone aquifers and sealing units of mudstone and siltstone layers extending from the Permian Shanxi to the Upper Triassic Liujiagou formation systems in the Ordos Basin. Simulation results indicate that CO2 injected for storage into deep saline aquifers cause a significant pressure perturbation in the geological system that may require a long duration in the post-injection period to establish new pressure equilibrium. The multilayer simultaneous injection scheme exhibits mutual interference with the intervening sealing layers, especially when the injection layers are very close to each other and the corresponding sealing layers are thin. The study further reveals that injection rate and temperature are the most significant factors for determining the lateral and vertical extent that the CO2 plume reaches and which phase and amount will exist at a particular time during and after the injection. In general, a large number of factors may influence the CO2–water fluid flow system considering the complexity in the real geologic sequence and structural configurations. Therefore, optimization of a CO2 injection scheme still requires pursuance of further studies.

[1]  C. Tsang,et al.  Large-scale impact of CO2 storage in deep saline aquifers: A sensitivity study on pressure response in stratified systems , 2009 .

[2]  Olaf Kolditz,et al.  Thermo-hydro-mechanical modeling of carbon dioxide injection for enhanced gas-recovery (CO2-EGR): a benchmarking study for code comparison , 2012, Environmental Earth Sciences.

[3]  D. Gu,et al.  An experimental study on stress-dependent sensitivity of ultra-low permeability sandstone reservoirs , 2011 .

[4]  Stefan Bachu,et al.  Technical and economic feasibility of CO2 disposal in aquifers within the Alberta sedimentary basin, Canada , 1996 .

[5]  G. Chi,et al.  Effects of hydrocarbon generation on fluid flow in the Ordos Basin and its relationship to uranium mineralization , 2011 .

[6]  Van Genuchten,et al.  A closed-form equation for predicting the hydraulic conductivity of unsaturated soils , 1980 .

[7]  Karsten Pruess,et al.  Reactive geochemical transport simulation to study mineral trapping for CO2 disposal in deep arenaceous formations , 2003 .

[8]  K. Pruess,et al.  TOUGH2 User's Guide Version 2 , 1999 .

[9]  Wenhou Li,et al.  Carbon Isotope Evidence for Ordovician Marine Hydrocarbon Source Rocks in Ordos Basin, North China , 2011 .

[10]  K. Pruess,et al.  Numerical Modeling of Aquifer Disposal of CO2 , 2003 .

[11]  W. Wagner,et al.  A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple‐Point Temperature to 1100 K at Pressures up to 800 MPa , 1996 .

[12]  Ming Li,et al.  Basement faults and volcanic rock distributions in the Ordos Basin , 2010 .

[13]  S. Bachu Screening and ranking of sedimentary basins for sequestration of CO2 in geological media in response to climate change , 2003 .

[14]  Xinshe Liu,et al.  Sulige field in the Ordos Basin: Geological setting, field discovery and tight gas reservoirs , 2008 .

[15]  Bert Metz,et al.  Carbon Dioxide Capture and Storage , 2005 .

[16]  T. Harrison,et al.  The tectonic evolution of Asia , 1996 .

[17]  Xiang Xiao,et al.  Upper Paleozoic petroleum system, Ordos Basin, China , 2005 .

[18]  Xinshan Wei,et al.  Geology and exploration of oil and gas in the Ordos basin , 2004 .

[19]  Yang You-yun The Fluid Dynamic Processes and Its Uranium Mineralization of Sandstone-type in the Ordos Basin,China , 2008 .

[20]  Lincoln Paterson,et al.  Role of Convective Mixing in the Long-Term Storage of Carbon Dioxide in Deep Saline Formations , 2005 .

[21]  Brian McPherson,et al.  Multiphase CO2 flow, transport and sequestration in the Powder River Basin, Wyoming, USA , 2000 .

[22]  Michael P. Klimetz Speculations on the Mesozoic Plate tectonic evolution of eastern China , 1983 .

[23]  Pathegama Gamage Ranjith,et al.  A study of methodologies for CO2 storage capacity estimation of saline aquifers , 2012 .

[24]  Kamy Sepehrnoori,et al.  Simulating CO2 Storage in Deep Saline Aquifers , 2005 .

[25]  M. Azaroual,et al.  Long term predictions of CO2 storage by mineral and solubility trapping in the Weyburn Midale reservoir , 2005 .

[26]  K. Pruess ECO2N: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2 , 2005 .

[27]  Chunxiang Cao,et al.  Development of environmental monitoring satellite systems in China , 2010 .

[28]  Fang Zhiming RANKING AND SCREENING OF CO_2 SALINE AQUIFER STORAGE ZONES IN CHINA , 2006 .

[29]  Matthew Flett,et al.  Heterogeneous saline formations: Long-term benefits for geo-sequestration of greenhouse gases , 2005 .

[30]  B. Metz IPCC special report on carbon dioxide capture and storage , 2005 .

[31]  P. Ranjith,et al.  Advanced core flooding apparatus to estimate permeability and storage dynamics of CO2 in large coal specimens , 2013 .

[32]  Wang Enzhi EXPERIMENTAL STUDY ON COEFFICIENT OF SENSITIVENESS BETWEEN PERCOLATION RATE AND EFFECTIVE PRESSURE FOR LOW PERMEABILITY ROCK , 2007 .

[33]  L. Jones,et al.  Engineering geology of British rocks and soils : mudstones of the Mercia Mudstone Group , 2002 .

[34]  Jan M. Nordbotten,et al.  Estimating effective rates of convective mixing from commercial-scale injection , 2012, Environmental Earth Sciences.

[35]  Shu-jing Xu,et al.  Paleomagnetic results from Triassic sections in the Ordos Basin, North China , 1991 .

[36]  F. Gumrah,et al.  Simulating the Effects of Deep Saline Aquifer Properties for CO Sequestration , 2005 .

[37]  Kamy Sepehrnoori,et al.  CO2 Flow Patterns Under Multiphase Flow: Heterogeneous Field-Scale Conditions , 1994 .

[38]  Keni Zhang,et al.  Investigation of CO2 storage capacity in open saline aquifers with numerical models , 2012 .

[39]  Joan M. Ogden,et al.  Carbon sequestration research and development , 1999 .

[40]  Qi Li,et al.  Application of a health, safety, and environmental screening and ranking framework to the Shenhua CCS project , 2013 .