Non‐Volatile Photochemical Gating of an Epitaxial Graphene/Polymer Heterostructure

A novel heterostructure based on epitaxial graphene grown on silicon carbide combined with two polymers is demonstrated, with a neutral spacer and a photoactive layer that provides potent electron acceptors under UV light exposure. UV exposure of this heterostructure enables control of the electrical parameters of graphene in a non-invasive, non-volatile, and reversible way.

[1]  Mikael Syväjärvi,et al.  Towards a quantum resistance standard based on epitaxial graphene. , 2010, Nature nanotechnology.

[2]  F. Guinea,et al.  The electronic properties of graphene , 2007, Reviews of Modern Physics.

[3]  L. Vandersypen,et al.  Gate-induced insulating state in bilayer graphene devices. , 2007, Nature materials.

[4]  R. Murali,et al.  Single step, complementary doping of graphene , 2010 .

[5]  Edward McCann Asymmetry gap in the electronic band structure of bilayer graphene , 2006 .

[6]  T. Tang,et al.  Direct observation of a widely tunable bandgap in bilayer graphene , 2009, Nature.

[7]  Masaya Notomi,et al.  Quantum Wire Fabrication by E-Beam Elithography Using High-Resolution and High-Sensitivity E-Beam Resist ZEP-520 , 1992 .

[8]  Klaus von Klitzing,et al.  Four-terminal magneto-transport in graphene p-n junctions created by spatially selective doping. , 2009, Nano letters.

[9]  V. Saile,et al.  Radiation damage of poly(methylmethacrylate) thin films analyzed by UPS , 1998 .

[10]  T. Ohta,et al.  Controlling the Electronic Structure of Bilayer Graphene , 2006, Science.

[11]  Fengnian Xia,et al.  Utilization of a buffered dielectric to achieve high field-effect carrier mobility in graphene transistors. , 2009, Nano letters.

[12]  V. Fal’ko,et al.  Charge transfer between epitaxial graphene and silicon carbide , 2010, 1007.4340.

[13]  H. Kurz,et al.  Electrical observation of a tunable band gap in bilayer graphene nanoribbons at room temperature , 2010, 1001.5213.

[14]  SUPARNA DUTTASINHA,et al.  Graphene: Status and Prospects , 2009, Science.

[15]  K. Jenkins,et al.  Operation of graphene transistors at gigahertz frequencies. , 2008, Nano letters.

[16]  Ute Zschieschang,et al.  Graphene on a hydrophobic substrate: doping reduction and hysteresis suppression under ambient conditions. , 2009, Nano letters.

[17]  J. Moon,et al.  Epitaxial Graphenes on Silicon Carbide , 2010, 1002.0873.

[18]  Heiko B. Weber,et al.  Quantum oscillations and quantum Hall effect in epitaxial graphene , 2010 .

[19]  Vladimir I Fal'ko,et al.  Landau-level degeneracy and quantum Hall effect in a graphite bilayer. , 2006, Physical review letters.

[20]  H. Ikeura-Sekiguchi,et al.  Characterization and degradation of ZEP520 resist film by TOF-PSID and NEXAFS , 2005 .