Acoustic wave liquid sensors enhanced with glancing angle-deposited thin films

Abstract The application of nanostructured thin films grown by glancing angle deposition (GLAD) to enhance the sensitivity of Love wave liquid sensors was investigated. The effect of high-angle GLAD films, with and without nanostructure modification by ion milling and clustering, on device response was studied. Ion milling was used to prevent clustering of individual nanostructured posts, and was compared to films that were intentionally clustered. Both sets of modified films were shown to eliminate signal losses due to damping from the non-rigid, as-deposited posts. Sensitivity enhancement was tested by viscous loading with varying mixtures of glycerol and de-ionized water. Frequency shifts were found to be non-linear with the square root of the density–viscosity product, ( ρη ) 1/2 , and were modeled with exponentials. The sensitivity was shown to increase with film thickness, but decreased with increasing values of ( ρη ) 1/2 . There was also an increase in signal loss with film thickness under a liquid environment. The balance between sensitivity enhancement and signal loss must be carefully optimized with consideration for the intended application.

[1]  Michele Penza,et al.  Carbon nanotubes as SAW chemical sensors materials , 2004 .

[2]  Ricardas Rotomskis,et al.  Fast-response surface acoustic wave humidity sensor based on hematoporphyrin film , 2009 .

[3]  W. M. Haynes CRC Handbook of Chemistry and Physics , 1990 .

[4]  F Bender,et al.  Sensitivity of the acoustic waveguide biosensor to protein binding as a function of the waveguide properties. , 2003, Biosensors & bioelectronics.

[5]  Yiping Zhao,et al.  Nanocarpet Effect: Pattern Formation during the Wetting of Vertically Aligned Nanorod Arrays , 2004 .

[6]  Geoffrey L. Harding,et al.  An experimental study of Love-wave acoustic sensors operating in liquids , 1997 .

[7]  C. Lowe,et al.  A novel Love-plate acoustic sensor utilizing polymer overlayers , 1992, IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control.

[8]  Michael J. Brett,et al.  Nanostructure engineering in porous columnar thin films: recent advances , 2007 .

[9]  T. Meen,et al.  ZnO thin film with nanorod arrays applied to fluid sensor. , 2012, Ultrasonics.

[10]  S Hunklinger,et al.  Viscoelastic behavior of antibody films on a shear horizontal acoustic surface wave sensor. , 1998, Analytical chemistry.

[11]  Yinghu Yang,et al.  The influence of calcium doped ZnO films on Love wave sensor characteristics , 2006 .

[12]  Bastian E. Rapp,et al.  Surface acoustic wave biosensors: a review , 2008, Analytical and bioanalytical chemistry.

[13]  W. Water,et al.  Using ZnO nanorods to enhance sensitivity of liquid sensor , 2009 .

[14]  S. Büttgenbach,et al.  Separate determination of liquid density and viscosity with sagittally corrugated Love-mode sensors , 1999 .

[15]  Michael J. Vellekoop,et al.  A love wave sensor for (bio)chemical sensing in liquids , 1994 .

[16]  Michael I. Newton,et al.  ST Quartz Acoustic Wave Sensors with Sectional Guiding Layers , 2008, Sensors.

[17]  Siegfried Hunklinger,et al.  A SAW immunosensor for operation in liquid using a SiO2 protective layer , 2001 .

[18]  Jun Kondoh,et al.  Parametric study of SH-SAW device response to various types of surface perturbations , 2009 .

[19]  F Bender,et al.  Guided shear horizontal surface acoustic wave sensors for chemical and biochemical detection in liquids. , 2001, Analytical chemistry.

[20]  G. L. Harding,et al.  Design and properties of quartz-based Love wave acoustic sensors incorporating silicon dioxide and PMMA guiding layers , 1997 .

[21]  Wojtek Wlodarski,et al.  A ZnO nanorod based layered ZnO/64° YX LiNbO3 SAW hydrogen gas sensor , 2007 .

[22]  Tsung-Tsong Wu,et al.  A room temperature surface acoustic wave hydrogen sensor with Pt coated ZnO nanorods , 2009, Nanotechnology.

[23]  Glen McHale,et al.  Experimental study of Love wave devices with thick guiding layers , 2004 .

[24]  Michael J. Brett,et al.  Glancing angle deposition: Fabrication, properties, and applications of micro- and nanostructured thin films , 2007 .

[25]  Eric Borguet,et al.  TiO(2)/LiCl-based nanostructured thin film for humidity sensor applications. , 2011, ACS applied materials & interfaces.

[26]  F. Sarry,et al.  PANI/ZnO/Quartz structure for Love wave gas sensor , 2009 .

[27]  Venkataramani Anandan,et al.  Nanopillar array structures for enhancing biosensing performance , 2006, International journal of nanomedicine.

[28]  Surface acoustic wave gas sensors based on polyisobutylene and carbon nanotube composites , 2011 .

[29]  G. L. Harding,et al.  A study of Love-wave acoustic sensors , 1996 .

[30]  Dominique Rebière,et al.  Love-wave bacteria-based sensor for the detection of heavy metal toxicity in liquid medium. , 2010, Biosensors & bioelectronics.

[31]  J. C. Sit,et al.  The use of ion-milling to control clustering of nanostructured, columnar thin films. , 2010, Nanotechnology.

[32]  B. Drafts Acoustic wave technology sensors , 2001 .

[33]  J. C. Sit,et al.  High sensitivity Love-wave humidity sensors using glancing angle deposited thin films , 2012 .

[34]  Glen McHale,et al.  Resonant conditions for Love wave guiding layer thickness , 2001 .

[35]  Tsung-Tsong Wu,et al.  A high sensitivity nanomaterial based SAW humidity sensor , 2008 .

[36]  Electra Gizeli,et al.  Design considerations for the acoustic waveguide biosensor , 1997 .

[37]  Michael Thompson,et al.  Acoustic Wave-Based Detection in Bioanalytical Chemistry: Competition for Surface Plasmon Resonance? , 2008 .