Simulation of a stand-alone residential PEMFC power system with sodium borohydride as hydrogen source

Abstract Catalytic hydrolysis of sodium borohydride (NaBH 4 ) has been investigated as a method to generate hydrogen for fuel cell applications. The high purity of the generated hydrogen makes this process a potential source of hydrogen for polymer electrolyte membrane fuel cells (PEMFCs). In this paper, a PEMFC power system employing a NaBH 4 hydrogen generator is designed to supply continuous power to residential power applications as stand-alone loads and simulated using Matlab/Simulink software package. The overall system is sized to meet a real end-use load, representative of standard European domestic medium electric energy consumption, over a 1-week period. Supervisory control strategies are proposed to manage the hydrogen generation and storage, and the power flow. Simulation results show that the proposed supervisory control strategies are effective and the NaBH 4 –PEMFC power system is a technologically feasible solution for stand-alone residential applications.

[1]  Sejin Kwon,et al.  Design and development of a fuel cell-powered small unmanned aircraft , 2012 .

[2]  Xianguo Li,et al.  Effect of contaminants on polymer electrolyte membrane fuel cells , 2011 .

[3]  Graham Ault,et al.  Modeling, analysis and control system development for the Italian hydrogen house , 2009 .

[4]  Ned Djilali,et al.  Experimental assessment of a residential scale renewable–regenerative energy system , 2009 .

[5]  Jianli Hu,et al.  An overview of hydrogen production technologies , 2009 .

[6]  Kodjo Agbossou,et al.  Control analysis of renewable energy system with hydrogen storage for residential applications , 2006 .

[7]  K. Klobut,et al.  Residential fuel cell systems , 2007 .

[8]  Michael T. Kelly,et al.  A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst , 2000 .

[9]  A sodium borohydride hydrogen generation reactor for stationary applications: Experimental and reactor simulation studies , 2012 .

[10]  K. Agbossou,et al.  Performance of a stand-alone renewable energy system based on energy storage as hydrogen , 2004, IEEE Transactions on Energy Conversion.

[11]  P. Thounthong,et al.  Control Algorithm of Fuel Cell and Batteries for Distributed Generation System , 2008, IEEE Transactions on Energy Conversion.

[12]  Sejin Kwon,et al.  Fuel cell system with sodium borohydride as hydrogen source for unmanned aerial vehicles , 2011 .

[13]  Carmen M. Rangel,et al.  Kinetics of hydrolysis of sodium borohydride for hydrogen production in fuel cell applications: A re , 2011 .

[14]  Mahlon Wilson,et al.  Scientific aspects of polymer electrolyte fuel cell durability and degradation. , 2007, Chemical reviews.

[15]  Tzimas Evangelos,et al.  Hydrogen Storage: State-of-the-Art and Future Perspective. , 2003 .

[16]  Sousso Kelouwani,et al.  Model for energy conversion in renewable energy system with hydrogen storage , 2005 .

[17]  S. Nam,et al.  Hydrogen generation system using sodium borohydride for operation of a 400 W-scale polymer electrolyte fuel cell stack , 2007 .

[18]  J. Gore,et al.  Kinetics of Ru-catalyzed sodium borohydride hydrolysis , 2007 .

[19]  W. Steve Shepard,et al.  Experimental investigation of fuel cell dynamic response and control , 2007 .

[20]  B. Richardson,et al.  Sodium borohydride based hybrid power system , 2005 .

[21]  Ziyad M. Salameh,et al.  Dynamic response of a stand-alone wind energy conversion system with battery energy storage to a wind gust , 1997 .

[22]  K. Agbossou,et al.  Development of a control method for a renewable energy system with fuel cell , 2009, AFRICON 2009.

[23]  P. Miele,et al.  Ten-year efforts and a no-go recommendation for sodium borohydride for on-board automotive hydrogen storage , 2009 .

[24]  Taegyu Kim,et al.  Fully-integrated micro PEM fuel cell system with NaBH4 hydrogen generator , 2012 .

[25]  Jongkwang Lee,et al.  Micro PEM fuel cell system with NaBH4 hydrogen generator , 2012 .

[26]  Steffen Møller-Holst,et al.  Transient response of a proton exchange membrane fuel cell , 2007 .

[27]  Carlos Andrés Ramos-Paja,et al.  Mathematical analysis of hybrid topologies efficiency for PEM fuel cell power systems design , 2010 .

[28]  Amin Hajizadeh,et al.  Intelligent power management strategy of hybrid distributed generation system , 2007 .

[29]  A. Vahidi,et al.  A review of the main parameters influencing long-term performance and durability of PEM fuel cells , 2008 .