Laser surface texturing for adaptive solid lubrication

Solid lubricant systems were developed to provide friction and wear reduction in variable environmental conditions. The mechanisms employed to achieve cross-environment capability include “on demand” solid lubricant supply from reservoirs in hard wear protective coatings. This research explores recent advances in a precision laser machining to generate arrays of micrometer sized dimple reservoirs with controlled size, location, and density. These micro-reservoirs were machined by a focused UV laser beam on the surface of hard TiCN coatings produced by a cathodic vacuum arc deposition. Different dimple diameters and spacing were used to achieve area coverage with micro-reservoirs between 0.5% and 50% of the entire tribological contact surface. Solid lubricants based on MoS2 and graphite were then applied by burnishing and sputtering to such laser textured surfaces. Sliding friction tests were performed against steel balls in humid air and dry nitrogen environments. The results indicate that there is an optimum dimple surface coverage of about 10%. The life of the solid lubricants on dimpled surfaces was an order of magnitude longer than on the unmodified TiCN coating surface. The laser-processed micro-reservoirs also helped to renew lubricant supply for tests with multiple cycling between humid air and dry nitrogen. Tribological surface adaptation to the test environment was investigated by micro-Raman, which demonstrated a repeated change from hexagonal MoS2 to graphite carbon in the wear track with each dry/humid environment cycle. Solid lubricant composition inside the micro-reservoirs did not change.

[1]  Valerio Romano,et al.  Laser surface microstructuring to improve tribological systems , 2003, Other Conferences.

[2]  P. N. Gibson,et al.  Low-friction TiN–MoS2 coatings produced by dc magnetron co-deposition , 1998 .

[3]  Andrey A. Voevodin,et al.  Combined magnetron sputtering and pulsed laser deposition of carbides and diamond‐like carbon films , 1996 .

[4]  J. Zabinski,et al.  Mechanistic study of the synergism between Sb2O3 and MoS2 lubricant systems using Raman spectroscopy , 1993 .

[5]  Ali Erdemir,et al.  Review of engineered tribological interfaces for improved boundary lubrication , 2005 .

[6]  Andrey A. Voevodin,et al.  Supertough wear-resistant coatings with ‘chameleon’ surface adaptation , 2000 .

[7]  P. N. Gibson,et al.  Preparation and characterisation of low-friction TiB2-based coatings by incorporation of C or MoS2 , 1998 .

[8]  A. A. Voevodin,et al.  Nanocomposite tribological coatings with “chameleon” surface adaptation , 2002 .

[9]  M. Sentis,et al.  Femtosecond laser ablation of diamond-like carbon films , 2004 .

[10]  Naofumi Hiraoka,et al.  Effect of discontinuous hard under-coating on the life of solid film lubricant under extreme contact pressure , 1997 .

[11]  P. W. Centers Tribological performance of MoS2 compacts containing MoO3, Sb2O3 OR MoO3 and Sb2O3 , 1988 .

[12]  I. Etsion State of the art in Laser Surface Texturing , 2004 .

[13]  A. Voevodin,et al.  Hybrid Plasma Deposition Methods for Synthesis of Nanostructured Materials , 2005 .

[14]  J. Zabinski,et al.  Microstructure and lubrication mechanism of multilayered MoS2/Sb2O3 thin films , 2006 .

[15]  I. Ford,et al.  Interpretation of friction and wear properties of MoS2 coated steel substrates , 1994 .

[16]  E. Roberts,et al.  The effect of substrate surface roughness on the friction and wear of sputtered MoS2 films , 1992 .

[17]  R. Fusaro Effect of Substrate Surface Finish on the Lubrication and Failure Mechanisms of Molybdenum Disulfide Films , 1982 .

[18]  E. Levashov,et al.  Nanostructured thin films and nanodispersion strengthened coatings , 2004 .

[19]  Woo Y. Lee,et al.  Preparation and friction characteristics of self-lubricating TiN-MoS2 composite coatings , 1995 .

[20]  A. Voevodin,et al.  Smart Nanocomposite Coatings with Chameleon Surface Adaptation in Tribological Applications , 2004 .

[21]  A. Voevodin,et al.  Investigation into three-dimensional laser processing of tribological coatings , 1998 .

[22]  J. Zabinski,et al.  Multi-environmental lubrication performance and lubrication mechanism of MoS2/Sb2O3/C composite films , 2006 .

[23]  Andreas Ruf,et al.  Hole formation process in laser deep drilling with short and ultrashort pulses , 2002, International Symposium on Laser Precision Microfabrication.