Synthesis of Flame-Retardant Polypropylene/LDH-Borate Nanocomposites

New nanocomposites have been prepared using unmodified polypropylene (PP) and a new type of highly dispersed [Zn2Al(OH6)][B4O5(OH)4]0.5 (Zn2Al-borate) and [Mg3Al(OH)8][B4O5(OH)4]0.5 (Mg3Al-borate) layered double hydroxides (LDHs). PP/LDHs nanocomposites with LDH loadings of 1, 3, 6, 9, 15, and 30 wt % have been prepared by a novel solvent mixing method. Scanning electron microscopy (SEM) analysis shows that the precipitated nanocomposites materials form spherical particles with an average size of ca. 10 μm and that the LDH nanoparticles were well dispersed within the PP matrix. XRD analysis of the nanocomposites indicates that the LDHs are completely exfoliated. The thermal stability and flame retardancy properties of these new materials have been evaluated as a function of the nature of LDH and the LDH loadings. Cone calorimetry analysis indicates that PP/Zn2Al-borate nanocomposites exhibited superior performance than the equivalent PP/Mg3Al-borate nanocomposites; a 15 wt % of the highly dispersed Zn2Al-...

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