Fabrication and mechanical properties of (Mo0.9W0.1)(Si0.4Al0.6)2 composites reinforced by TiC

TiC-(Mo0.9W0.1)(Si0.4Al0.6)2 composites were prepared from Mo, W, Si, Al and TiC powders via self-propagating high-temperature synthesis and hot pressing. The propagation mode of the combustion synthesis reaction and the influence of different TiC contents (0, 5, 10, 15, 20, 25 and 30 vol%) on the mechanical properties of (Mo0.9W0.1)(Si0.4Al0.6)2 were investigated. The results showed that the combustion propagation mode was steady from 0.00 to 2.06 s and unsteady from 2.06 to 6.45 s. The composites were mainly composed of MoSi2 (C11b) and TiC. The bending strength, Vickers hardness, and fracture toughness of the 0–30 vol% TiC-(Mo0.9W0.1)(Si0.4Al0.6)2 composites were 270–433 MPa, 9.60–14.85 GPa and 6.40–9.73 MPa · m1/2, respectively. These results indicated that TiC doping could effectively improve the mechanical properties of (Mo0.9W0.1)(Si0.4Al0.6)2.

[1]  S. Ramay,et al.  Study of magnetic, thermoelectric and optical behaviors of PbMO3 (M = V, Mn) perovskites using DFT approach , 2019, Materials Research Express.

[2]  H. Gasan,et al.  Microstructures and mechanical properties of graphene platelets-reinforced spark plasma sintered tantalum diboride-silicon carbide composites , 2019, Materials Research Express.

[3]  M. Siadati,et al.  Nanocomposites of Al5083/SiC; strength and wear behaviors , 2019, Materials Research Express.

[4]  Lai-fei Cheng,et al.  Improved fracture toughness of laminated ZrB2-SiC-MoSi2 ceramics using SiC whisker , 2018, Ceramics International.

[5]  Yueguang Wei,et al.  Crack deflection occurs by constrained microcracking in nacre , 2018 .

[6]  Xiaozhi Yan,et al.  High-pressure sintering of bulk MoSi 2 : microstructural, physical properties and mechanical behavior , 2018 .

[7]  F. Akhtar,et al.  In situ fabrication and properties of 0.4MoB-0.1SiC-xMoSi2 composites by self-propagating synthesis and hot-press sintering , 2018 .

[8]  Xiaohong Wang,et al.  Synthesis and oxidation behavior of (Mo0.97Nb0.03)(Si0.97Al0.03)2 ceramic , 2017 .

[9]  Xiaohong Wang,et al.  Synthesis, microstructure and mechanical properties of (Mo,Ti)Si2/Al2O3 composites prepared by thermite-reaction-assisted combustion synthesis , 2016 .

[10]  Xiao Jin,et al.  Fabrication and Composition Investigation of WSi2/MoSi2 Composite Powders Obtained by a Self-Propagating High-Temperature Synthesis Method , 2016 .

[11]  Xiaohong Wang,et al.  Fabrication and Characterization of (Mo1‐xNix) (Si1‐xAlx)2 (x = 0.025, 0.05, and 0.1) Alloys , 2016 .

[12]  Mehdi Shahedi Asl,et al.  Hardness and toughness of hot pressed ZrB2–SiC composites consolidated under relatively low pressure , 2015 .

[13]  F. Akhtar,et al.  Synthesis, microstructure and properties of MoSi2–5 vol%Al2O3 composites , 2014 .

[14]  A. Sharif Effects of Re- and Al-alloying on mechanical properties and high-temperature oxidation of MoSi2 , 2012 .

[15]  M. Zakeri,et al.  Synthesis of MoSi2–TiC nanocomposite powder via mechanical alloying and subsequent annealing , 2012 .

[16]  Wen-ming Guo,et al.  Investigation of MoSi2 melt infiltrated RSiC and its oxidation behavior , 2012 .

[17]  Yicheng Ge,et al.  Effect of the W addition content on valence electron structure and properties of MoSi2-based solid solution alloys , 2011 .

[18]  Xiaohong Wang,et al.  Effects of boron addition on the formation of MoSi2 by combustion synthesis mode , 2010 .

[19]  A. Umarji,et al.  Improved ductility and oxidation resistance in Nb and Al co-substituted MoSi2 , 2008 .

[20]  N. Prasad,et al.  Microstructure and mechanical behaviour of reaction hot pressed multiphase Mo–Si–B and Mo–Si–B–Al intermetallic alloys , 2006 .

[21]  R. Mitra Mechanical behaviour and oxidation resistance of structural silicides , 2006 .

[22]  D. Jiang,et al.  Microstructure and Mechanical Properties of In Situ Produced TiC/TiB2/MoSi2 Composites , 2005 .

[23]  Shengrong Yang,et al.  Preparation and properties of MoSi2 composites reinforced by TiC, TiCN, and TiB2 , 2005 .

[24]  Jinsheng Pan,et al.  Wear behavior of TiC–MoSi2 composites , 2003 .

[25]  Xinyu Liu,et al.  Synthesis and properties of MoSi2 alloyed with aluminum , 2003 .

[26]  Jinsheng Pan,et al.  Fabrication and characterization of TiC-particle-reinforced MoSi2 composites , 2002 .

[27]  Jinsheng Pan,et al.  Fabrication and characterization of TiCw/MoSi2 and SiCw/MoSi2 composites , 2002 .

[28]  M. Kang,et al.  Microstructures and mechanical properties of hot-pressed MoSi2-matrix composites reinforced with SiC and ZrO2 particles , 2001 .

[29]  K. Niihara,et al.  Strong monolithic and composite MoSi2 materials by nanostructure design , 1999 .

[30]  A. K. Vasudevan,et al.  Key developments in high temperature structural silicides , 1999 .

[31]  R. Mitra,et al.  Effect of small aluminum additions on microstructure and mechanical properties of molybdenum di-silicide , 1999 .

[32]  T. Mitchell,et al.  MICROSTRUCTURES AND MECHANICAL PROPERTIES OF AM o 3 Si-Mo 5 Si 3 COMPOSITE , 1999 .

[33]  T. Mitchell,et al.  Microstructures and mechanical properties of a Mo3Si-Mo5Si3 composite , 1998 .

[34]  P. Peralta,et al.  Mechanical properties of monocrystalline C11b MoSi2 with small aluminum additions , 1997 .

[35]  K. Nagata,et al.  Effect of third elements on the pesting suppression of Mo-Si-X intermetallics (X = Al, Ta, Ti, Zr and Y) , 1996 .

[36]  K. Nagata,et al.  Isothermal and Cyclic Oxidation of Mo(Si 1− x , Al x ) 2 up to 2048 K , 1993 .

[37]  T. Nieh,et al.  Mechanism of MoSi_2 pest during low temperature oxidation , 1993 .

[38]  R. M. Aikin Strengthening of discontinuously reinforced MoSi2 composites at high temperatures , 1992 .

[39]  A. K. Vasudevan,et al.  Sic Reinforced-Mosi2 Alloy Matrix Composites , 1990 .

[40]  D. Schwartz,et al.  Silicide-matrix materials for high-temperature applications , 1989 .