Bidirectional optical sorting of gold nanoparticles.

We present a generic technique allowing size-based all-optical sorting of gold nanoparticles. Optical forces acting on metallic nanoparticles are substantially enhanced when they are illuminated at a wavelength near the plasmon resonance, as determined by the particle's geometry. Exploiting these resonances, we realize sorting in a system of two counter-propagating evanescent waves, each at different wavelengths that selectively guide nanoparticles of different sizes in opposite directions. We validate this concept by demonstrating bidirectional sorting of gold nanoparticles of either 150 or 130 nm in diameter from those of 100 nm in diameter within a mixture.

[1]  T. Imasaka,et al.  Theory of optical chromatography. , 1997, Analytical chemistry.

[2]  Romain Quidant,et al.  Tunable optical sorting and manipulation of nanoparticles via plasmon excitation. , 2006, Optics letters.

[3]  W. Chan,et al.  Synthesis and surface modification of highly monodispersed, spherical gold nanoparticles of 50-200 nm. , 2009, Journal of the American Chemical Society.

[4]  R. Argazzi,et al.  Size sorting of citrate reduced gold nanoparticles by sedimentation field-flow fractionation. , 2009, Journal of chromatography. A.

[5]  Ke Xiao,et al.  Multidimensional optical fractionation of colloidal particles with holographic verification. , 2009, Physical review letters.

[6]  Paul Steinvurzel,et al.  Scannable plasmonic trapping using a gold stripe. , 2010, Nano letters.

[7]  M. Nieto-Vesperinas,et al.  Optical manipulation of plasmonic nanoparticles , 2007 .

[8]  Arezou A Ghazani,et al.  Determining the size and shape dependence of gold nanoparticle uptake into mammalian cells. , 2006, Nano letters.

[9]  E. Coronado,et al.  The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment , 2003 .

[10]  Tomáš Čižmár,et al.  A dual beam photonic crystal fiber trap for microscopic particles , 2008 .

[11]  S Kawata,et al.  Movement of micrometer-sized particles in the evanescent field of a laser beam. , 1992, Optics letters.

[12]  M Mazilu,et al.  Numerical investigation of passive optical sorting of plasmon nanoparticles. , 2011, Optics express.

[13]  Karen Volke-Sepúlveda,et al.  Modulated optical sieve for sorting of polydisperse microparticles , 2006 .

[14]  K. Dholakia,et al.  Microfluidic sorting in an optical lattice , 2003, Nature.

[15]  Kishan Dholakia,et al.  Extended organization of colloidal microparticles by surface plasmon polariton excitation , 2006 .

[16]  J. Kimling,et al.  Turkevich method for gold nanoparticle synthesis revisited. , 2006, The journal of physical chemistry. B.

[17]  David G Grier,et al.  Transport and fractionation in periodic potential-energy landscapes. , 2004, Physical review. E, Statistical, nonlinear, and soft matter physics.

[18]  C. Mirkin,et al.  Nanoparticles with Raman spectroscopic fingerprints for DNA and RNA detection. , 2002, Science.

[19]  J. West,et al.  Near-infrared resonant nanoshells for combined optical imaging and photothermal cancer therapy. , 2007, Nano letters.

[20]  Kishan Dholakia,et al.  Near-field optical micromanipulation with cavity enhanced evanescent waves , 2006 .

[21]  G. Frens Controlled Nucleation for the Regulation of the Particle Size in Monodisperse Gold Suspensions , 1973 .

[22]  Kishan Dholakia,et al.  Light-induced cell separation in a tailored optical landscape , 2005 .

[23]  M Mazilu,et al.  Optical deflection and sorting of microparticles in a near-field optical geometry. , 2008, Optics express.

[24]  Lawrence Tamarkin,et al.  Colloidal Gold: A Novel Nanoparticle Vector for Tumor Directed Drug Delivery , 2004, Drug delivery.

[25]  Ernst-Ludwig Florin,et al.  High precision and continuous optical transport using a standing wave optical line trap. , 2011, Optics express.

[26]  Pavel Zemánek,et al.  Light at work: The use of optical forces for particle manipulation, sorting, and analysis , 2008, Electrophoresis.

[27]  Warren C W Chan,et al.  Elucidating the mechanism of cellular uptake and removal of protein-coated gold nanoparticles of different sizes and shapes. , 2007, Nano letters.

[28]  P. Jain,et al.  Calculated absorption and scattering properties of gold nanoparticles of different size, shape, and composition: applications in biological imaging and biomedicine. , 2006, The journal of physical chemistry. B.

[29]  Warren C W Chan,et al.  Nanoparticle-mediated cellular response is size-dependent. , 2008, Nature nanotechnology.

[30]  S. Kawata,et al.  Dynamic SERS imaging of cellular transport pathways with endocytosed gold nanoparticles. , 2011, Nano letters.

[31]  S. Gambhir,et al.  Gold nanoparticles: a revival in precious metal administration to patients. , 2011, Nano letters.

[32]  Olivier J F Martin,et al.  Excitation and reemission of molecules near realistic plasmonic nanostructures. , 2011, Nano letters.

[33]  Romain Quidant,et al.  Heat generation in plasmonic nanostructures: Influence of morphology , 2009 .

[34]  Sabine Neuss,et al.  Size-dependent cytotoxicity of gold nanoparticles. , 2007, Small.

[35]  S Keen,et al.  Comparison of Faxén's correction for a microsphere translating or rotating near a surface. , 2009, Physical review. E, Statistical, nonlinear, and soft matter physics.

[36]  Martin Siler,et al.  Optical sorting and detection of submicrometer objects in a motional standing wave , 2006 .

[37]  Jinwoo Cheon,et al.  Biocompatible heterostructured nanoparticles for multimodal biological detection. , 2006, Journal of the American Chemical Society.

[38]  P. Zemánek,et al.  Static optical sorting in a laser interference field , 2008 .

[39]  S. Franzen,et al.  Purification of molecularly bridged metal nanoparticle arrays by centrifugation and size exclusion chromatography. , 2001, Analytical chemistry.