Ring closing metathesis in protic media by means of a neutral and polar ruthenium benzylidene complex.

The ring closing olefine metathesis in protic solvents using a new ruthenium benzylidene complex is described.

[1]  W. Leitner,et al.  Olefin metathesis in supercritical carbon dioxide. , 2001, Journal of the American Chemical Society.

[2]  R. Grubbs,et al.  Novel reactivity of ruthenium alkylidenes in protic solvents: degenerate alkylidene proton exchange. , 2001, Journal of the American Chemical Society.

[3]  R. Grubbs,et al.  The development of L2X2Ru=CHR olefin metathesis catalysts: an organometallic success story. , 2001, Accounts of chemical research.

[4]  M. Peruzzini,et al.  Water-Soluble Ruthenium Vinylidene and Allenylidene Complexes: Potential Catalysts for Ring-Opening Metathesis , 2000 .

[5]  Alois Fürstner.  Olefinmetathese und mehr , 2000 .

[6]  R. Grubbs,et al.  Water-Soluble Ruthenium Alkylidenes: Synthesis, Characterization, and Application to Olefin Metathesis in Protic Solvents , 2000 .

[7]  R. Grubbs,et al.  Increased ring closing metathesis activity of ruthenium-based olefin metathesis catalysts coordinated with imidazolin-2-ylidene ligands , 1999 .

[8]  Jinkun Huang,et al.  Olefin Metathesis-Active Ruthenium Complexes Bearing a Nucleophilic Carbene Ligand , 1999 .

[9]  M. Picquet,et al.  Room temperature operating allenylidene precatalyst [LnRuξCξCξCR2]+X- for olefin metathesis: dramatic influence of the counter anion X- , 1999 .

[10]  R. H. Grubbs,et al.  Die Ringschluß‐Olefin‐Metathese als hocheffiziente Methode zur Synthese kovalent querverbrückter Peptide , 1998 .

[11]  R. Grubbs,et al.  Ring-Closing Metathesis in Methanol and Water , 1998 .

[12]  W. Herrmann,et al.  EINE NEUE GENERATION VON RUTHENIUMKATALYSATOREN FUR DIE OLEFINMETATHESE , 1998 .

[13]  Robert H. Grubbs,et al.  Recent advances in olefin metathesis and its application in organic synthesis , 1998 .

[14]  R. Grubbs,et al.  Living Ring-Opening Metathesis Polymerization in Water , 1998 .

[15]  S. Blechert,et al.  Die Olefinmetathese in der organischen Synthese , 1997 .

[16]  Scott J. Miller,et al.  Application of Ring-Closing Metathesis to the Synthesis of Rigidified Amino Acids and Peptides , 1996 .

[17]  R. Grubbs,et al.  Synthesis of Water-Soluble, Aliphatic Phosphines and Their Application to Well-Defined Ruthenium Olefin Metathesis Catalysts , 1996 .

[18]  J. Ziller,et al.  Synthesis and Applications of RuCl2(CHR‘)(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity , 1996 .

[19]  Joseph W. Ziller,et al.  A Series of Well‐Defined Metathesis Catalysts–Synthesis of [RuCl2(CHR′)(PR3)2] and Its Reactions , 1995 .

[20]  W. A. Nugent,et al.  Practical catalyst for cyclic metathesis. Synthesis of functional and/or enantiopure cycloalkenes. , 1995 .

[21]  W. Herrmann,et al.  Wasserlösliche Liganden, Metallkomplexe und Komplexkatalysatoren: Synergismen aus Homogen‐ und Heterogenkatalyse , 1993 .

[22]  R. Grubbs,et al.  The application of catalytic ring-closing olefin metathesis to the synthesis of unsaturated oxygen heterocycles , 1992 .

[23]  M. Mullins,et al.  Reactive triflate alkylating agents , 1977 .

[24]  E. A. Fehnel.  Thiapyran Derivatives. III. The Preparation, Properties and Reactions of ▵2-Dihydrothiapyran 1,1-Dioxide , 1952 .

[25]  E. A. Fehnel,et al.  Thiapyran Derivatives. II. The Preparation, Properties, and Reactions of Δ3-Dihydrothiapyran 1,1-Dioxide1 , 1951 .

[26]  M. Carmack,et al.  Studies in the thiapyran series; the preparation, properties and reactions of 1,4-thiapyrone-1-dioxide. , 1948, Journal of the American Chemical Society.