Polymeric Piezoresistive Microcantilevers With Reduced Electrical Variability

The observed electrical variability has limited the usage of the carbon black (CB)-SU8 (an epoxy polymer of di-glycidyl ether of bisphenol A) nanocomposite as a piezoresistive element in the microelectromechanical systems-based sensor applications. We report here a simple modification to the CB-SU8 nanocomposite preparation, which improves the dispersion of the CB particles in the SU8 polymer matrix creating a CB-SU8 photopatternable nanocomposite with a stable conductive network. The modified CB-SU8 nanocomposite was used as the piezoresistive element to fabricate microcantilever devices for strain sensing applications. Improved stability of these microcantilever devices is reflected from their electrical characterization. The electromechanical characterization of these microcantilevers demonstrated their piezoresistive behavior.

[1]  D. Ratna,et al.  Thermomechanical Properties and Morphology of Blends of a Hydroxy-Functionalized Hyperbranched Polymer and Epoxy Resin , 2001 .

[2]  V Seena,et al.  Polymer nanocomposite nanomechanical cantilever sensors: material characterization, device development and application in explosive vapour detection , 2011, Nanotechnology.

[3]  M. Knite,et al.  Polyisoprene-carbon black nanocomposites as tensile strain and pressure sensor materials , 2004 .

[4]  V. Rao,et al.  Polymer composite-based OFET sensor with improved sensitivity towards nitro based explosive vapors , 2010 .

[5]  V. Ramgopal Rao,et al.  Photopatternable nano-composite (SU-8/ZnO) thin films for piezo-electric applications , 2012 .

[6]  Rupali Gangopadhyay and,et al.  Conducting Polymer Nanocomposites: A Brief Overview , 2000 .

[7]  Nanocapsules based on carbon nanotubes-graft-polyglycerol hybrid materials. , 2009, Nanotechnology.

[8]  Jan-Chan Huang,et al.  Carbon black filled conducting polymers and polymer blends , 2002 .

[9]  J. Richter,et al.  Epoxy based photoresist/carbon nanoparticle composites , 2008 .

[10]  V. Ramgopal Rao,et al.  Al-doped ZnO thin-film transistor embedded micro-cantilever as a piezoresistive sensor , 2013 .

[11]  Rainer Adelung,et al.  Direction sensitive bending sensors based on multi-wall carbon nanotube/epoxy nanocomposites , 2008, Nanotechnology.

[12]  Young-Ju Kim,et al.  Preparation of piezoresistive nano smart hybrid material based on graphene , 2011 .

[13]  V. Rao,et al.  Polymer microcantilever biochemical sensors with integrated polymer composites for electrical detection , 2009 .

[14]  L. Flandin,et al.  In situ observation of electric field induced agglomeration of carbon black in epoxy resin , 1998 .

[15]  Ning Hu,et al.  Piezoresistive Strain Sensors Made from Carbon Nanotubes Based Polymer Nanocomposites , 2011, Sensors.

[16]  Christopher K. Ober,et al.  Nanocomposite Materials for Optical Applications , 1997 .

[17]  P. Vettiger,et al.  Microfabricated photoplastic cantilever with integrated photoplastic/carbon based piezoresistive strain sensor , 2006 .

[18]  A. Dworak,et al.  Cationic polymerization of glycidol: coexistence of the activated monomer and active chain end mechanism , 1994 .

[19]  E. J. Vandenberg Polymerization of glycidol and its derivatives: A new rearrangement polymerization , 1985 .

[20]  R. Haag,et al.  An Approach to Glycerol Dendrimers and Pseudo-Dendritic Polyglycerols , 2000 .

[21]  P. Vettiger,et al.  Polymer-based stress sensor with integrated readout , 2002 .

[22]  N. Hu,et al.  Investigation on sensitivity of a polymer/carbon nanotube composite strain sensor , 2010 .

[23]  Anja Boisen,et al.  SU-8 Cantilevers for Bio/chemical Sensing; Fabrication, Characterisation and Development of Novel Read-out Methods , 2008, Sensors.

[24]  K. Schulte,et al.  Piezoresistive response of epoxy composites with carbon nanoparticles under tensile load , 2009 .

[25]  Ping Wang,et al.  Temperature dependence of electrical resistivity for carbon black filled ultra-high molecular weight polyethylene composites prepared by hot compaction , 2005 .

[26]  H. Schmidt,et al.  Completely miscible polyethylene nanocomposites. , 2012, Journal of the American Chemical Society.

[27]  Karl Schulte,et al.  Agglomeration and electrical percolation behavior of carbon black dispersed in epoxy resin , 1997 .

[28]  K. Balasubramaniam,et al.  Graphene‐Functionalized Carbon Nanotubes for Conducting Polymer Nanocomposites and Their Improved Strain Sensing Properties , 2013 .

[29]  ZnO Nanowire Embedded Strain Sensing Cantilever: A New Ultra-Sensitive Technology Platform , 2013, Journal of Microelectromechanical Systems.

[30]  Shigeo Asai,et al.  Dispersion of fillers and the electrical conductivity of polymer blends filled with carbon black , 1991 .

[31]  A. N. Nikitin,et al.  Estimating Kinetic Parameters for the Spontaneous Polymerization of Glycidol at Elevated Temperatures , 2012 .