Predicting and confirming the lifetime of o-rings

Abstract We derive an empirical method for estimating the equilibrium sealing force appropriate to o-rings under their application (e.g., squeezed) conditions. Another empirical approach allows us to estimate the equilibrium compression set for o-rings once they have been released from their compressed state. Comparing the two equilibrium values for three different butyl o-ring materials aged under both laboratory accelerated aging conditions and under long-term field aging conditions indicates an approximately linear relationship between equilibrium set and equilibrium sealing force. When the results are combined with modulus measurements, the approximate linearity is shown to be consistent with a 60-year-old theory derived by Tobolsky and co-workers. These results allow us to use ∼20-year field aging results to quantitatively confirm accelerated aging predictions derived in an earlier publication. In addition, we describe experiments that allow us to quantitatively estimate that the sealing force per unit sealing length must drop below ∼1 N/cm before seal leakage is indicated. Combining this result with the accelerated aging predictions allows us to make lifetime predictions versus aging temperature for the butyl o-rings.

[1]  K. Gillen,et al.  The wear-out approach for predicting the remaining lifetime of materials , 2000 .

[2]  Kenneth T. Gillen,et al.  An ultrasensitive technique for testing the Arrhenius extrapolation assumption for thermally aged elastomers , 1995 .

[3]  Arthur Victor Tobolsky Properties and Structure of Polymers. , 1960 .

[4]  S. G. Burnay,et al.  Prediction of service lifetimes of elastomeric seals during radiation ageing , 1985 .

[5]  K. Gillen,et al.  Modulus profiling of polymers , 1987 .

[6]  K. Murakami,et al.  Chemorheology of polymers , 1979 .

[7]  Michael R. Keenan,et al.  Methods for Predicting More Confident Lifetimes of Seals in Air Environments , 2000 .

[8]  Mohammed Tahir,et al.  Appraisal of the current standards for stress relaxation measurements in compression for rubbers , 1986 .

[9]  P. Pincus,et al.  A theoretical basis for viscoelastic relaxation of elastomers in the long-time limit , 1983 .

[10]  K. Gillen Effect of cross-links which occur during continuous chemical stress-relaxation , 1988 .

[11]  A. A. Collyer,et al.  Irradiation effects on polymers , 1991 .

[12]  Aurelio Savadori,et al.  Impact testing of plastics: présent knowledge , 1985 .

[13]  J. Stein,et al.  Stress relaxation studies of model silicone RTV networks , 1988 .

[14]  The Theory of Permanent Set at Elevated Temperatures in Natural and Synthetic Rubber Vulcanizates , 1946 .

[15]  M. Keenan,et al.  New method for predicting lifetime of seals from compression-stress relaxation experiments , 1998 .

[16]  J. Ferry Viscoelastic properties of polymers , 1961 .

[17]  K. Gillen,et al.  Modulus Mapping of Rubbers Using Micro- and Nano-Indentation Techniques , 2001 .

[18]  Kenneth T. Gillen,et al.  Extrapolation of Accelerated Aging Data - Arrhenius or Erroneous? , 1997 .

[19]  A. Birley,et al.  Stress-relaxation measurements on rubbers in Compression Equipment and methodology , 1986 .

[20]  Robert Bernstein,et al.  Validation of improved methods for predicting long-term elastomeric seal lifetimes from compression stress-relaxation and oxygen consumption techniques. , 2003 .

[21]  A. Birley,et al.  A new concept for stress relaxation measurements of rubbers in compression , 1983 .