A new multiple-stage electrocoagulation process on anaerobic digestion effluent to simultaneously reclaim water and clean up biogas.

A new multiple-stage treatment process was developed via integrating electrocoagulation with biogas pumping to simultaneously reclaim anaerobic digestion effluent and clean up biogas. The 1st stage of electrocoagulation treatment under the preferred reaction condition led to removal efficiencies of 30%, 81%, 37% and >99.9% for total solids, chemical oxygen demand, total nitrogen and total phosphorus, respectively. Raw biogas was then used as a reactant and pumped into the effluent to simultaneously neutralize pH of the effluent and remove H2S in the biogas. The 2nd stage of electrocoagulation treatment on the neutralized effluent showed that under the selected reaction condition, additional 60% and 10% of turbidity and chemical oxygen demand were further removed. The study concluded a dual-purpose approach for the first time to synergistically combine biogas purification and water reclamation for anaerobic digestion system, which well addresses the downstream challenges of anaerobic digestion technology.

[1]  Mahmut Bayramoglu,et al.  Treatment of poultry slaughterhouse wastewaters by electrocoagulation. , 2006, Journal of hazardous materials.

[2]  M. Ozacar,et al.  Treatment of dairy wastewaters by electrocoagulation using mild steel electrodes. , 2006, Journal of hazardous materials.

[3]  Mohammad Y A Mollah,et al.  Fundamentals, present and future perspectives of electrocoagulation. , 2004, Journal of hazardous materials.

[4]  Nicolas Abatzoglou,et al.  A review of biogas purification processes , 2009 .

[5]  Xiaohui Lei,et al.  Electrochemical treatment of anaerobic digestion effluent using a Ti/Pt-IrO2 electrode. , 2007, Bioresource technology.

[6]  L. Travieso,et al.  Biogas purification process using intensive microalgae cultures , 1993, Biotechnology Letters.

[7]  Wei Liao,et al.  Integration of sewage sludge digestion with advanced biofuel synthesis. , 2013, Bioresource technology.

[8]  N. Adhoum,et al.  Decolourization and removal of phenolic compounds from olive mill wastewater by electrocoagulation , 2004 .

[9]  Teresa J. Bandosz,et al.  A Role of Sodium Hydroxide in the Process of Hydrogen Sulfide Adsorption/Oxidation on Caustic-Impregnated Activated Carbons , 2002 .

[10]  M Y Mollah,et al.  Electrocoagulation (EC)--science and applications. , 2001, Journal of hazardous materials.

[11]  Yung-Tse Hung,et al.  Electrocoagulation in Wastewater Treatment , 2011 .

[12]  Guohua Chen Electrochemical technologies in wastewater treatment , 2004 .

[13]  R B Dean Processes for water reclamation. , 1991, Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA.

[14]  K. Yetilmezsoy,et al.  Decolorization and COD reduction of UASB pretreated poultry manure wastewater by electrocoagulation process: a post-treatment study. , 2009, Journal of hazardous materials.

[15]  J. Parga,et al.  Electrocoagulation mechanism for COD removal , 2007 .

[16]  C. Kennes,et al.  Effects of pH, CO2, and flow pattern on the autotrophic degradation of hydrogen sulfide in a biotrickling filter. , 2005, Biotechnology and bioengineering.

[17]  Zoubir Derriche,et al.  Experimental investigation of chemical oxygen demand and turbidity removal from cardboard paper mill effluents using combined electrocoagulation and adsorption processes , 2012 .

[18]  G. Soreanu,et al.  Removal of hydrogen sulfide from gas streams using biological processes - a review. , 2006 .

[19]  Yasar Avsar,et al.  Comparison of classical chemical and electrochemical processes for treating rose processing wastewater. , 2007, Journal of hazardous materials.

[20]  A. Da̧browski,et al.  Adsorption of phenolic compounds by activated carbon--a critical review. , 2005, Chemosphere.

[21]  Scott Lynn,et al.  A medium-temperature process for removal of hydrogen sulfide from sour gas streams with aqueous metal sulfate solutions , 1992 .

[22]  J. Belgaied,et al.  Treatment of electroplating wastewater containing Cu2+, Zn2+ and Cr(VI) by electrocoagulation. , 2004, Journal of hazardous materials.

[23]  Geoffrey W. Barton,et al.  A quantitative comparison between chemical dosing and electrocoagulation , 2002 .

[24]  Teresa J. Bandosz,et al.  Analysis of the Relationship between H2S Removal Capacity and Surface Properties of Unimpregnated Activated Carbons , 2000 .

[25]  Vinay Kumar Tyagi,et al.  Enhancement of Coagulation Flocculation Process Using Anionic Polymer for the Post Treatment of UASB Reactor Effluent , 2010 .

[26]  Guohua Chen,et al.  Combined electrocoagulation and electroflotation for removal of fluoride from drinking water. , 2008, Journal of hazardous materials.

[27]  R. Niessner,et al.  Removal of siloxanes in biogases. , 2001, Journal of hazardous materials.

[28]  Wei Liao,et al.  Anaerobic treatment of lignocellulosic material to co-produce methane and digested fiber for ethanol biorefining. , 2013, Bioresource technology.