High-temperature carrier transport in n-type epitaxial GaAs

Abstract Resistivity and Hall coefficient have been measured in the temperature range 300-1250 K on samples of n -type epitaxial GaAs from which the substrates have been removed to eliminate substrate conduction at high temperatures. These data are useful for determining energy band parameters as well as for modeling epitaxial growth and other high temperature phenomena. The mobilities of electrons in the Γ 6 c minimum and L 6 c minima and the mobility of holes in the Γ 8 v maxima were calculated for the temperature range 300-970 K. From these calculations the mobility in the L 6 c minima was found to decrease faster with increasing temperature than the mobility in the Γ 6 c minimum. Using the temperature dependence of the mobilities, the Γ 6 c − L 6 c − X 6 c ordering of the conduction band minima, and a calculated intrinsic carrier concentration, a self-consistent model for four-band carrier transport was obtained.

[1]  D. Nasledov Energy of Spectrum and Scattering of Current Carriers in Gallium Arsenide , 1961 .

[2]  D. Lynch,et al.  Ordering and Absolute Energies of the L6c and X6c Conduction Band Minima in GaAs , 1976 .

[3]  J. R. Knight,et al.  The preparation of high purity gallium arsenide by vapour phase epitaxial growth , 1965 .

[4]  D. Effer Epitaxial Growth of Doped and Pure GaAs in an Open Flow System , 1965 .

[5]  D. E. Aspnes,et al.  GaAs lower conduction-band minima: Ordering and properties , 1976 .

[6]  L. Aukerman,et al.  High‐Temperature Hall Coefficient in GaAs , 1960 .

[7]  G. E. Stillman,et al.  Electrical characterization of epitaxial layers , 1976 .

[8]  W. Fawcett,et al.  Monte Carlo determination of electron transport properties in gallium arsenide , 1970 .

[9]  D. E. Hill,et al.  Electroluminescence and Electrical Properties of High‐Purity Vapor‐Grown GaP , 1971 .

[10]  C. M. Wolfe,et al.  Magnetospectroscopy of shallow donors in GaAs , 1969 .

[11]  C. D. Thurmond The Standard Thermodynamic Functions for the Formation of Electrons and Holes in Ge, Si, GaAs , and GaP , 1975 .

[12]  R. Dingle,et al.  Polariton Reflectance and Photoluminescence in High-Purity GaAs , 1973 .

[13]  D. Rode Electron Mobility in Direct-Gap Polar Semiconductors , 1970 .

[14]  D. Rode,et al.  Electron Transport in GaAs , 1971 .

[15]  G. D. Pitt,et al.  Electrical Properties of the GaAs X 1 C Minima at Low Electric Fields from a High-Pressure Experiment , 1970 .

[16]  P. Blood Electrical Properties of n -Type Epitaxial GaAs at High Temperatures , 1972 .

[17]  D. E. Aspnes,et al.  Schottky-Barrier Electroreflectance: Application to GaAs , 1973 .

[18]  J. Gibbons,et al.  Multilayered encapsulation of GaAs , 1978 .

[19]  H. Ehrenreich Band Structure and Transport Properties of Some 3–5 Compounds , 1961 .

[20]  M. Cardona,et al.  Temperature dependence of the band structure of germanium- and zinc-blende-type semiconductors , 1974 .

[21]  H. C. Casey,et al.  Temperature Dependence of the Energy Gap in GaAs and GaP , 1969 .

[22]  K. Wecht,et al.  Concentration dependence of the refractive index for n ‐ and p ‐type GaAs between 1.2 and 1.8 eV , 1974 .

[23]  C. M. Wolfe,et al.  Impurity gradients caused by surface states and substrate doping in epitaxial GaAs , 1977 .

[24]  S. Dvoretskii,et al.  Electrophysical properties of non‐doped epitaxial GaAs in the range from 10 to 1100°K , 1974 .

[25]  Y. P. Varshni Temperature dependence of the energy gap in semiconductors , 1967 .

[26]  H. Ikoma High-Temperature Transport Properties of n-Type GaAs , 1970 .

[27]  G. E. Stillman,et al.  Electron Mobility in High‐Purity GaAs , 1970 .

[28]  H. Ikoma,et al.  Electron Traps in n-GaAs Revealed by High-Temperature Hall Measurements , 1969 .

[29]  G. E. Stillman,et al.  Hall coefficient factor for polar mode scattering in n-type GaAs☆ , 1970 .

[30]  P. J. Dean,et al.  Intrinsic Optical Absorption of Gallium Phosphide between 2.33 and 3.12 eV , 1967 .

[31]  J. M. Whelan,et al.  The preparation and properties of gallium arsenide single crystals , 1958 .

[32]  F. E. Roberts High temperature hall measurements on GaAs , 1965 .

[33]  R. Zucca,et al.  Electrical compensation in semi‐insulating GaAs , 1977 .

[34]  Conyers Herring,et al.  Transport properties of a many-valley semiconductor , 1955 .