Successful Integration of Membrane Technologies in a Conventional Purification Process of Tannery Wastewater Streams

The aim of this work is to design and integrate an optimized batch membrane process in a conventional purification process used for the treatment of tannery wastewater. The integration was performed by using two spiral wound membrane modules in series, that is, nanofiltration and reverse osmosis, as substitutes to the biological reactor. The membrane process was designed in terms of sensible fouling issues reduction, which may be observed on the nanofiltration membrane if no optimization is performed. The entity of the fouling phenomena was estimated by pressure cycling measurements, determining both the critical and the threshold flux on the nanofiltration membrane. The obtained results were used to estimate the need of the overdesign of the membrane plant, as well as to define optimized operating conditions in order to handle fouling issues correctly for a long period of time. Finally, the developed membrane process was compared, from a technical and economic point of view, with the conventional biological process, widely offered as an external service near tannery production sites, and, here, proposed to be substituted by membrane technologies.

[1]  W. Hegemann,et al.  Anaerobic treatment of tannery wastewater with simultaneous sulphide elimination , 1998 .

[2]  P. Ciambelli,et al.  Mathematical modelling of photocatalytic degradation of methylene blue under visible light irradiation , 2013 .

[3]  Marco Stoller,et al.  Technical optimization of a dual ultrafiltration and nanofiltration pilot plant in batch operation by means of the critical flux theory: A case study , 2008 .

[4]  W. M. Wiegant,et al.  Full scale experience with tannery water management: an integrated approach , 1999 .

[5]  Marco Stoller,et al.  Reaction-precipitation by a spinning disc reactor: Influence of hydrodynamics on nanoparticles production , 2012 .

[6]  M. Bravi,et al.  Critical flux analyses on differently pretreated olive vegetation waste water streams: Some case studies , 2010 .

[7]  R. M. Napoli,et al.  Fenton's oxidation of various-based tanning materials , 2007 .

[8]  A. Chianese,et al.  Comparison of Critical and Threshold Fluxes on Ultrafiltration and Nanofiltration by Treating 2-Phase or 3- Phase Olive Mill Wastewater , 2013 .

[9]  Marco Stoller,et al.  Optimization of membrane batch processes by means of the critical flux theory , 2006 .

[10]  M. M. Stoop Water management of production systems optimised by environmentally oriented integral chain management : case study of leather manufacturing in developing countries , 2003 .

[11]  C. Merli,et al.  Optimization of a nanofiltration membrane process for tomato industry wastewater effluent treatment , 2009 .

[12]  M. Bravi,et al.  Batch membrane treatment of olive vegetation wastewater from two-phase olive oil production process by threshold flux based methods , 2012 .

[13]  A. Cicci,et al.  About proper membrane process design affected by fouling by means of the analysis of measured threshold flux data , 2013 .

[14]  S. Sözen,et al.  The effect of chemical settling on the kinetics and design of activated sludge for tannery wastewaters , 1998 .

[15]  M. Stoller On the effect of flocculation as pretreatment process and particle size distribution for membrane fouling reduction , 2009 .

[16]  S. Doğruel,et al.  Ozonation of Nonbiodegradable Organics in Tannery Wastewater , 2004, Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering.

[17]  R. Field,et al.  Critical, sustainable and threshold fluxes for membrane filtration with water industry applications. , 2011, Advances in colloid and interface science.

[18]  D. V. S. Murthy,et al.  Effect of toxic substances in anaerobic treatment of tannery wastewaters , 1997 .

[19]  Marco Stoller,et al.  A three year long experience of effective fouling inhibition by threshold flux based optimization methods on a nf membrane module for olive mill wastewater treatment , 2013 .

[20]  Pierre Le-Clech,et al.  Fouling in membrane bioreactors used in wastewater treatment , 2006 .

[21]  John Churchley,et al.  REMOVAL OF DYEW ASTE COLOUR FROM SEW AGE EFFLUENT – THE USE OF A FULL SCALE OZONE PLANT , 1994 .

[22]  M. Bravi,et al.  Threshold flux measurements of a nanofiltration membrane module by critical flux data conversion , 2013 .

[23]  S R Stern,et al.  Anaerobic treatment of textile dyeing wastewater. , 2003, Water science and technology : a journal of the International Association on Water Pollution Research.

[24]  K. Chitra,et al.  Removal of sulphide in anaerobically treated tannery wastewater by wet air oxidation , 1996 .

[25]  A. Chianese,et al.  Photocatalytic Degradation of Organic Dyes under Visible Light onN-Doped Photocatalysts , 2012 .

[26]  R. Field,et al.  Critical flux concept for microfiltration fouling , 1995 .

[27]  Thirumalachari Ramasami,et al.  Sustaining tanning process through conservation, recovery and better utilization of chromium , 2003 .

[28]  C. J. Williams,et al.  Treatment of tannery wastewater by chemical coagulation , 2004 .

[29]  W. Chu,et al.  Dye removal from textile dye wastewater using recycled alum sludge. , 2001, Water research.

[30]  D. Ahn,et al.  Improved treatment of tannery wastewater using Zoogloea ramigera and its extracellular polymer in an activated sludge process , 1996, Biotechnology Letters.

[31]  Marco Stoller,et al.  Effective fouling inhibition by critical flux based optimization methods on a NF membrane module for olive mill wastewater treatment , 2011 .

[32]  A Carucci,et al.  Biological treatment of tannery wastewater in the presence of chromium. , 2004, Journal of environmental management.

[33]  A. López,et al.  Tannery wastewater treatment by sequencing batch biofilm reactor. , 2003, Environmental science & technology.