Sodium-Based Chitosan Polymer Embedded with Copper Selenide (CuSe) Flexible Film for High Electromagnetic Interference (EMI) Shielding Efficiency

Efficient shielding materials are extremely important to minimize the effect of electromagnetic interference. Currently, various composite materials are being investigated with different shielding efficiencies reported. In this paper, a flexible and free-standing sodium-based chitosan (CH/Na) polymer with copper selenide (CuSe) filler was prepared for electromagnetic shielding. The CH/Na/CuSe polymer matrix was prepared via the direct casting technique at different wt% of CuSe, varying from 2 to 20 wt%. The polymer matrix was then characterised by using Fourier transform infrared (FTIR) spectroscopy to confirm the interaction between the CH/Na and CuSe. The XRD results revealed that the CH/Na/CuSe polymer was successfully formed. Improvement in the electrical conductivity was confirmed by an impedance spectroscopy measurement. The highest electrical conduction recorded was at 3.69 × 10−5 S/cm for CH/Na/CuSe polymer matrix with 20 wt% CuSe. An increase in total electromagnetic interference (EMI) shielding efficiency (SET) of up to 20 dB (99% EM power shield) was achieved, and it can be increased up to 34 dB (99.9% EM power shield) with the thickness of the polymer increased.

[1]  M. M. Ramli,et al.  Chitosan-Bentonite crosslinked film as indicator for copper (II) ions adsorption , 2021, The European Physical Journal Applied Physics.

[2]  J. Militký,et al.  Resistance against Penetration of Electromagnetic Radiation for Ultra-light Cu/Ni-Coated Polyester Fibrous Materials , 2020, Polymers.

[3]  Yeongcheol Park,et al.  Electromagnetic Interference Shield of Highly Thermal-Conducting, Light-Weight, and Flexible Electrospun Nylon 66 Nanofiber-Silver Multi-Layer Film , 2020, Polymers.

[4]  Haishun Du,et al.  Polypyrrole and cellulose nanofiber based composite films with improved physical and electrical properties for electromagnetic shielding applications. , 2020, Carbohydrate polymers.

[5]  M. Brza,et al.  Glycerolized Li+ Ion Conducting Chitosan-Based Polymer Electrolyte for Energy Storage EDLC Device Applications with Relatively High Energy Density , 2020, Polymers.

[6]  Qian Ma,et al.  Ag NPs-Assisted Synthesis of Stable Cu NPs on PET Fabrics for Antibacterial and Electromagnetic Shielding Performance , 2020, Polymers.

[7]  Bo Mi Kim,et al.  An effective utilization of MXene and its effect on electromagnetic interference shielding: flexible, free-standing and thermally conductive composite from MXene–PAT–poly(p-aminophenol)–polyaniline co-polymer , 2020, RSC advances.

[8]  Ayesha Afzal,et al.  Fabrication of reduced graphene oxide (RGO) and nanocomposite with thermoplastic polyurethane (TPU) for EMI shielding application , 2019, Journal of Materials Science: Materials in Electronics.

[9]  Z. Zainal,et al.  Structural and transport mechanism studies of copper selenide nanoparticles , 2019, Semiconductor Science and Technology.

[10]  Yali Zhang,et al.  Fabrication and investigation on the ultra-thin and flexible Ti3C2Tx/co-doped polyaniline electromagnetic interference shielding composite films , 2019, Composites Science and Technology.

[11]  K. Şendur,et al.  Surface Roughness Effects on the Broadband Reflection for Refractory Metals and Polar Dielectrics , 2019, Materials.

[12]  M. Kadir,et al.  Increase of metallic silver nanoparticles in Chitosan:AgNt based polymer electrolytes incorporated with alumina filler , 2019, Results in Physics.

[13]  W. B. Sediawan,et al.  Influence of salt addition and freezing-thawing on particle size and zeta potential of nano-chitosan , 2019, IOP Conference Series: Earth and Environmental Science.

[14]  Chiu-Yen Wang,et al.  Tunable optical and magnetic properties of Ni-doped CuSe nanowires using an anodic aluminum oxide template assisted hydraulic method , 2019, Nanotechnology.

[15]  Na Lu,et al.  Electromagnetic Interference Shielding Polymers and Nanocomposites - A Review , 2019, Polymer Reviews.

[16]  S. Sankaran,et al.  Recent advances in electromagnetic interference shielding properties of metal and carbon filler reinforced flexible polymer composites: A review , 2018, Composites Part A: Applied Science and Manufacturing.

[17]  R. Kannan,et al.  Influence of heat treatment on the properties of thermally evaporated copper selenide thin films , 2018, Materials Letters.

[18]  K. Khirouni,et al.  Frequency and temperature-dependence of dielectric permittivity and electric modulus studies of the solid solution Ca0.85Er0.1Ti1−xCo4x/3O3 (0 ≤ x ≤ 0.1) , 2018, RSC advances.

[19]  T. A. Hameed,et al.  Preparation and characterization of optical and electrical properties of copper selenide sulfide polycrystalline thin films , 2018 .

[20]  Pengbo Liu,et al.  Electromagnetic interference shielding effectiveness of microcellular polyimide/in situ thermally reduced graphene oxide/carbon nanotubes nanocomposites , 2018 .

[21]  M. Kadir,et al.  A conceptual review on polymer electrolytes and ion transport models , 2018 .

[22]  Shuhui Yu,et al.  Graphene paper for exceptional EMI shielding performance using large-sized graphene oxide sheets and doping strategy , 2017 .

[23]  M. A. Rasheed,et al.  Effect of High Salt Concentration (HSC) on Structural, Morphological, and Electrical Characteristics of Chitosan Based Solid Polymer Electrolytes , 2017, Polymers.

[24]  S. Dhakate,et al.  Integration of MCMBs/MWCNTs with Fe3O4 in a flexible and light weight composite paper for promising EMI shielding applications , 2017 .

[25]  B. Benguella,et al.  Adsorption of ammonia from wastewater using low-cost bentonite/chitosan beads , 2016 .

[26]  Yury Gogotsi,et al.  Electromagnetic interference shielding with 2D transition metal carbides (MXenes) , 2016, Science.

[27]  J. Kaur,et al.  Influence of different deposition potential on the structural and optical properties of copper selenide nanowires , 2016 .

[28]  A. Chandra,et al.  Ion-Electron-Conducting Polymer Composites: Promising Electromagnetic Interference Shielding Material. , 2016, ACS applied materials & interfaces.

[29]  Xianping Fan,et al.  Facile synthesis of CuSe nanoparticles and high-quality single-crystal two-dimensional hexagonal nanoplatelets with tunable near-infrared optical absorption , 2016 .

[30]  S. Dhakate,et al.  Lightweight and Easily Foldable MCMB-MWCNTs Composite Paper with Exceptional Electromagnetic Interference Shielding. , 2016, ACS applied materials & interfaces.

[31]  D. Yi,et al.  Ultrathin carbon foams for effective electromagnetic interference shielding , 2016 .

[32]  C. Martinez-Cisneros,et al.  Development of sodium-conducting polymer electrolytes: comparison between film-casting and films obtained via green processes , 2016 .

[33]  S. Sagadevan,et al.  A study of structural, morphological, optical and electrical properties of Zinc Selenide (ZnSe) thin film☆ , 2016 .

[34]  G. Madhu,et al.  Adsorption of Ammonium Nitrogen from Aqueous Systems Using Chitosan-Bentonite Film Composite , 2016 .

[35]  F. Reicha,et al.  Preparation of Chitosan Copper Complexes: Molecular Dynamic Studies of Chitosan and Chitosan Copper Complexes , 2015 .

[36]  I. Nainggolan,et al.  Ammonia Gas Sensor Based on Chitosan Biopolymer , 2015 .

[37]  Lihua Zhang,et al.  Polyimide/graphene composite foam sheets with ultrahigh thermostability for electromagnetic interference shielding , 2015 .

[38]  M. Kadir,et al.  Incorporation of NH4Br in PVA-chitosan blend-based polymer electrolyte and its effect on the conductivity and other electrical properties , 2014, Ionics.

[39]  G. Sivakumar,et al.  Influence of Equimolar Concentration on Structural and Optical Properties of Binary Selenides Nanoparticles , 2014 .

[40]  S. G. Kulkarni,et al.  Nanocomposites based on transition metal oxides in polyvinyl alcohol for EMI shielding application , 2014, Polymer Bulletin.

[41]  Rajvinder Singh,et al.  Graphene nanoribbon–PVA composite as EMI shielding material in the X band , 2013, Nanotechnology.

[42]  B. Mamba,et al.  Chitosan-based nanomaterials: a state-of-the-art review. , 2013, International journal of biological macromolecules.

[43]  G. Zou,et al.  Solution synthesis of copper selenide nanocrystals and their electrical transport properties , 2012 .

[44]  B. Mellander,et al.  Evaluation of Mobility, Diffusion Coefficient and Density of Charge Carriers in Ionic Liquids and Novel Electrolytes Based on a New Model for Dielectric Response , 2011 .

[45]  Mohammed H Al-Saleh,et al.  Copper nanowire/polystyrene nanocomposites: Lower percolation threshold and higher EMI shielding , 2011 .

[46]  Mohammed H Al-Saleh,et al.  Highly electrically conductive and high performance EMI shielding nanowire/polymer nanocomposites by miscible mixing and precipitation , 2011 .

[47]  Zhaoguang Wang,et al.  Controllable synthesis of copper selenide nanocrystals through a green paraffin-acetate method , 2010 .

[48]  L. A. Patil,et al.  Structural, optical and electrical properties of chemically deposited copper selenide films , 2009 .

[49]  D. C. Trivedi,et al.  EMI shielding: Methods and materials—A review , 2009 .

[50]  A. Sharma,et al.  Structural and electrical studies of sodium iodide doped poly(vinyl alcohol) polymer electrolyte films for their application in electrochemical cells , 2007 .

[51]  A. Arof,et al.  Conductivity studies of a chitosan-based polymer electrolyte , 2006 .

[52]  Etienne Sicard,et al.  Issues in electromagnetic compatibility of integrated circuits: emission and susceptibility , 2005, Microelectron. Reliab..

[53]  A. H. Bhuiyan,et al.  Structural, electrical and optical properties of copper selenide thin films deposited by chemical bath deposition technique , 2005 .

[54]  A. Arof,et al.  Studies on lithium acetate doped chitosan conducting polymer system , 2002 .

[55]  I. Grozdanov,et al.  Chemical Deposition and Characterization of Cu3Se2 and CuSe Thin Films , 2001 .

[56]  Y. Koyama,et al.  Preparation and microstructure analysis of chitosan/hydroxyapatite nanocomposites. , 2001, Journal of biomedical materials research.

[57]  Y. Qian,et al.  A convenient, low temperature route to nanocrystalline SnSe , 1999 .

[58]  V. Davidenko,et al.  Percolation conductivity of polymer composites filled with dispersed conductive filler , 1995 .

[59]  R. D. Heyding THE COPPER/SELENIUM SYSTEM , 1966 .