Study of Ester-Type Liquid Crystals by TSDC and Optical Investigations

We study ester-type liquid crystal, 4′-cyanophenyl 4-n-hexyl benzoate and its homologue 4′-cyanophenyl 4-n-pentyl benzoate. We used the Thermally Stimulated Depolarization Currents method and found information about phase transition temperature, and activation energies. The temperatures of phase transitions were compared to those obtained by classical DSC/DTA measurements. Simultaneously with the TSDC, we measured the optical transmission; we found a decrease of the optical transmission when it was measured after a greater pre-applied polarizing electric field.

[1]  H. Yokoyama,et al.  Thermally Stimulated Depolarization Currents on Colloidal Liquid Crystal Composite System , 2004 .

[2]  M. Godinho,et al.  Thermally Stimulated Depolarization Currents and Optical Transmissionon Liquid Crystal/Cellulose Derivative Composite Devices , 2003 .

[3]  M. Morsy,et al.  DSC studies on p-cyanophenyl p-(n-alkyl)benzoate liquid crystals: evidence for polymorphism and conformational change , 1999 .

[4]  M. Morsy,et al.  Electron Paramagnetic Resonance and ab Initio Structural Studies on Liquid Crystalline Systems , 1998 .

[5]  H. Siesler,et al.  Reorientation of Nematic Liquid-Crystals and Liquid-Crystalline Polymers in an Electric Field Studied by FT-IR Time-Resolved Spectroscopy and 2D-Correlation Analysis , 1997 .

[6]  G. W. Gray,et al.  The Synthesis and Transition Temperatures of Some Fluoro-Substituted 4-Cyanophenyl and 4-Cyanobiphenyl-4′-yl 4-Pentyl- and 4-Butoxy-Benzoates , 1989 .

[7]  C. Foxon,et al.  Topography of AlGaAs/GaAs heterostructures using field-effect liquid crystals , 1988 .

[8]  Z. Raszewski,et al.  Liquid-CrystalIine 4-(trans-4′-n-AIkyIcyclohexyI) Benzoates. The Effect of Terminal and Lateral Substituents on the Mesomorphic, Thermodynamic and Dielectric Properties , 1984 .

[9]  S. Kelly Some novel nematic 4-cyanophenyl esters incorporating a lateral substituent , 1983 .

[10]  M. Schadt,et al.  Synthesis and some Physical Properties of Phenylpyrimidines , 1977 .

[11]  V. Titov,et al.  Liquid Crystalline Compounds: III On Applicability of Schröder-Van Laar Equations to Liquid Crystals Mixtures , 1976 .

[12]  M. Barnik,et al.  Mesomorphism and Dielectric Properties of Phenyl 4 -Alkylbiphenyl-4′ -Carboxylates and Phenyl 4 (4-Alkylphenyl) cyclohexanecarboxylates , 1976 .

[13]  A. V. Bogatskii,et al.  Zh. Obshch. Khim. , 1975 .

[14]  F. N. Sinnadurai,et al.  A surface temperature limit detector using nematic liquid crystals with an application to microcircuits , 1974 .

[15]  J. van Turnhout,et al.  Thermally Stimulated Discharge of Polymer Electrets , 1971 .