Rhenium sulfide cluster chemistry

Rhenium sulfides are still very rare except for octahedral cluster compounds. The chemistry of trinuclear, tetranuclear and octahedral cluster compounds is reviewed in comparison with that of molybdenum sulfide clusters and in the light of the relationships between molecular and solid state cluster compounds. A promising outlook is expected.

[1]  J. Long,et al.  Ligand Substitution Reactions of [Re6S8Br6]4-: A Basis Set of Re6S8 Clusters for Building Multicluster Assemblies , 1998 .

[2]  Zhiping Zheng,et al.  Cluster Condensation by Thermolysis: Synthesis of a Rhomb-Linked Re12Se16 Dicluster and Factors Relevant to the Formation of the Re24Se32 Tetracluster , 1997 .

[3]  S. Shin,et al.  Synthesis of octahedral rhenium cluster chalcobromides Re6X4Br10 and Re6X8Br2(X = S, Se, Te) by condensation from triangular rhenium bromide Re3Br9 , 1997 .

[4]  Jeffrey R. Long,et al.  A Basis Set of Re6Se8 Cluster Building Blocks and Demonstration of Their Linking Capability: Directed Synthesis of an Re12Se16 Dicluster , 1997 .

[5]  V. Fedorov,et al.  The first complex with TeI2 ligands: synthesis and structure of [Re6Te8(TeI2)6]I2 , 1997 .

[6]  J. Ibers,et al.  Syntheses and Characterizations of the New Tetranuclear Rhenium Cluster Compounds Re4(μ3-Q)4(TeCl2)4Cl8 (Q = S, Se, Te) , 1997 .

[7]  J. Ibers,et al.  Cocrystallized Mixtures and Multiple Geometries: Syntheses, Structures, and NMR Spectroscopy of the Re6 Clusters [NMe4]4[Re6(Te8-nSen)(CN)6] (n = 0−8) , 1997 .

[8]  W. Bronger,et al.  Cs6Re6Se15, Darstellung und Atomanordnung sowie die Einordnung in eine Struktursystematik ternärer Chalkogenide des Rheniums und Technetiums , 1997 .

[9]  M. Sergent,et al.  Tetra-Anionic Units in Octahedral Re6 Thiobromides: The Structure of Cs4KRe6S8Br7. , 1997 .

[10]  L. G. Bulusheva,et al.  X-ray emission and X-ray photoelectron study of the electronic structure of polymeric cubanocluster compounds Re4−xMoxS4Te4 , 1996 .

[11]  G. Wiegers,et al.  The crystal structure of some rhenium and technetium dichalcogenides , 1996 .

[12]  J. Orduna,et al.  μ3‐Imido‐Functionalized Chevrel–Sergent‐Type Molecular Clusters, a New Class of Inorganic–Organic Hybrid Compounds: Preparations and Alkylation Reactions , 1996 .

[13]  J. Long,et al.  A Solid-State Route to Molecular Clusters: Access to the Solution Chemistry of [Re6Q8]2+ (Q = S, Se) Core-Containing Clusters via Dimensional Reduction , 1996 .

[14]  J. Ibers,et al.  The New Inorganic Ligands TeCl2 and TeBr2: Syntheses and Crystal Structures of Re6Te6Cl6(TeCl2)2 and [Re6Te8(TeBr2)6]Br2 , 1996 .

[15]  V. Fedorov,et al.  Molecular octahedral sulfido-bromide rhenium clusters: Synthesis and crystal structure of (PPh4)2[Re6S6Br8] ∗d CH3C6H5 and (PPh4)3[Re6S7Br7] , 1996 .

[16]  J. Strähle,et al.  Synthese und Struktur von Re4(μ3‐Te)4(TeBr2)4Br8 , 1996 .

[17]  V. Fedin,et al.  High-yield synthesis of the cuboidal rhenium cluster [Re4S4(CN)12]4− by reaction of the triangular cluster [Re3S7Br6]+ with cyanide , 1996 .

[18]  Taro Saito.  Group 6 Metal Chalcogenide Cluster Complexes and their Relationships to Solid-State Cluster Compounds , 1996 .

[19]  Taro Saito,et al.  SYNTHESIS, STRUCTURE, AND MOLECULAR ORBITAL CALCULATION OF THE BICAPPED TRIANGULAR MOLYBDENUM CLUSTER COMPLEX MO3S5(PME3)6 , 1995 .

[20]  J. Long,et al.  Dimensional Reduction of Re6Se8Cl2: Sheets, Chains, and Discrete Clusters Composed of Chloride‐Terminated [Re6Q8]2+ (Q S, Se) Cores , 1995 .

[21]  W. Bronger,et al.  Rb4Re6S12, darstellung und struktur , 1994 .

[22]  B. Harbrecht,et al.  Rheniumselenidtelluride Re2SexTe5–x: Die Struktur von Re6Se8Te7† , 1994 .

[23]  S. Kelty,et al.  Structure of Rhenium Disulfide , 1994 .

[24]  S. I. Tkachenko,et al.  Discovery of a pure rhenium mineral at Kudriavy volcano , 1994, Nature.

[25]  A. Müller,et al.  A Building Principle of Amorphous Chalcogenides of Transition Metals: The “Extrusion” of the Electron‐Rich Cluster [Re4S2(SO2)4(CN)10]8− from a‐Re2S7 , 1994 .

[26]  A. Fujishima,et al.  Photoelectrochemical characterization of a rhenium octahedral cluster compound [Re6Se7Br4] , 1994 .

[27]  V. Fedorov,et al.  Re4S4Te4—A new mixed rhenium chalcogenide containing a tetrahedral Re4 cluster , 1994 .

[28]  W. Bronger,et al.  Isolierte [M6S14]‐Baueinheiten in ternären Sulfiden des Technetiums und Rheniums , 1993 .

[29]  A. Orlandini,et al.  Dimerization of the stellated octahedral unit Co6S8P6: synthesis and x-ray crystal structure of [Co12(μ3-S)14(μ4-S)2(PEt3)10][TCNQ]2, where TCNQ=tetracyanoquinodimethane , 1993 .

[30]  J. Gabriel,et al.  Molecular hexanuclear clusters in the system rhenium-sulfur-chlorine : solid state synthesis, solution chemistry, and redox properties , 1993 .

[31]  A. Pénicaud,et al.  Hydrogen-bond tuning of macroscopic transport properties from the neutral molecular component site along the sries of metallic organic-inorganic solvates (BEDT-TTF)4Re6Se5Cl9.[guest], [guest = DMF, THF, dioxane] , 1993 .

[32]  T. Shibahara.  Syntheses of sulphur-bridged molybdenum and tungsten coordination compounds , 1993 .

[33]  W. Bronger,et al.  IR- und ramanspektren der rheniumclusterverbindungen Rb4Re6S13 und Cs4Re6S13,5 , 1993 .

[34]  S. Kelty,et al.  Scanning Probe Microscopy Study of Layered Dichalcogenide ReS2 , 1993 .

[35]  Taro Saito,et al.  Synthesis of [Mo4S6(SH)2(PMe3)6] and [Mo6S10(SH)2(PEt3)6] consisting of fused molybdenum-sulfur Mo3(.mu.3-S) cluster units , 1992 .

[36]  N. Alonso‐Vante,et al.  Structure and photoelectrochemical properties of semiconducting rhenium cluster chalcogenides: Re6X8Br2 (X S, Se) , 1992 .

[37]  M. Yamasaki,et al.  Cubane-type mixed-metal clusters with molybdenum-nickel-sulfur Mo3NiS4 cores. Syntheses, characterization, and x-ray structures of [Mo3NiS4(H2O)10](CH3C6H4SO3)4.7H2O and Ca2.5[Mo3NiS4(Hnta)(nta)2Cl].14H2O , 1991 .

[38]  A. Perrin.  Hexanuclear Rhenium Clusters: From Solid State to Solution Chemistry. The Crystal Structure of KRe6Se5Cl7(OH)2, H2O, and Its Implications , 1991 .

[39]  R. H. Holm,et al.  Nonmolecular Metal Chalcogenide/Halide Solids and Their Molecular Cluster Analogues , 1990 .

[40]  W. Bronger,et al.  Cs4Re6S13 und Cs4Re6S13,5 – zwei Verbindungen mit [Re6S8]-Baueinheiten in geringfügig variierten Gerüststrukturen† , 1990 .

[41]  W. Bronger,et al.  Cs6Re6S15 – eine Verbindung, in der [Re6S8]-Baueinheiten über Disulfidbrücken verknüpft eine Gerüststruktur bilden† , 1990 .

[42]  F. Lévy,et al.  Single Crystal Growth, Structure and Characterization of the Octahedral Cluster Compound Re6Se8Br2 , 1988 .

[43]  H. Tributsch,et al.  Influence of d-state density and chemistry of transition metal cluster selenides on electrocatalysis , 1988 .

[44]  M. Greenblatt,et al.  New ternary rhenium chalcogenides with isolated [Re6X8]-cluster units: Preparation and properties , 1988 .

[45]  M. Sergent,et al.  Octahedral clusters in molybdenum(II) and rhenium(III) chalcohalide chemistry , 1988 .

[46]  M. Sergent,et al.  Rhenium clusters in inorganic chemistry: structures and metal-metal bonding , 1988 .

[47]  A. Müller,et al.  Einstieg in die Chemie einfacher Rhenium‐Schwefel‐Komplexe und ‐Cluster. Darstellung und Kristall‐Struktur von R[ReS4], R′[ReS9], (NH4)4[Re4S22]·2H2O, R′2[Cl2Fe(MoS4)FeCl2]x [Cl2Fe(ReS4)FeCl2]1‐x′ R′2 [(ReS4)Cu3l4] und RR′2[(ReS4)Cu5Br7] (R NEt4; R′ PPh4; x = 0,3, 0,5) , 1987 .

[48]  Taro Saito,et al.  First synthesis of octahedral tungsten cluster chloro complexes with trialkylphosphines and their conversion to .eta.1-ethyl derivatives , 1987 .

[49]  U. Müller,et al.  Thiochloroanionen von Molybdän(IV). Die Kristallstruktur von (NEt4)3[Mo3(μ3-S)(μ-S2)3Cl6]Cl · CH2Cl2 Kristallstruktur, EPR-Spektrum und magnetische Eigenschaften von (NEt4)2[Mo2(μ-S2)(μ-Cl)2Cl6] , 1986 .

[50]  Y. Yamagata,et al.  Synthesis of hexanuclear molybdenum cluster alkyl complexes coordinated with trialkylphosphines: Crystal structures of trans-[(Mo6Cl8)Cl4{P(n-C4H 9)3}2] and all-trans-[(Mo6Cl8)Cl2(C2H 5)2{P(n-C4H ... , 1986 .

[51]  V. Fedorov,et al.  A physico-chemical characterization of the cluster-type rhenium telluride Re6Te15 , 1986 .

[52]  A. Müller,et al.  [Re 4IVS22]4−, a Highly Symmetrical Metal‐Sulfur Cluster with Six S 32− Ligands , 1986 .

[53]  W. Bronger,et al.  Alkalimetallrheniumsulfide und ‐selenide mit [Re6X8]‐Baueinheiten , 1985 .

[54]  A. V. Mishchenko,et al.  Cluster Transition Metal Chalcogenide Halides , 1985 .

[55]  W. Bronger,et al.  Darstellung und kristallstruktur von Li4Re6S11 , 1985 .

[56]  J. Marzik,et al.  Photoelectronic properties of ReS2 and ReSe2 single crystals , 1984 .

[57]  A. Müller,et al.  [MO4IIIS4(CN)12]8-, A CLUSTER WITH HIGH NEGATIVE CHARGE AND CUBANE-LIKE MO4S4-MOIETY - ON THE SIGNIFICANCE OF CYANOTHIOMOLYBDATES FOR THE PREBIOTIC EVOLUTION , 1982 .

[58]  W. Bronger,et al.  Synthesis and crystal structures of Ba2Re6S11 and Sr2Re6S11, compounds containing [Re6S8] clusters , 1982 .

[59]  R. Chianelli,et al.  Hydrodesulfurization Catalysis by Transition Metal Sulfides , 1981 .

[60]  W. Bronger,et al.  Na2Re3S6 und K2Re3S6, zwei thiorhenate mit [Re6S8]-clustern , 1980 .

[61]  W. Bronger,et al.  Ternäre Rheniumsulfide mit [Re6S8]‐Clustern , 1978 .

[62]  O. Fischer,et al.  New compounds of the type Mo2Re4X8 (M = S, Se) containing octahedral Mo2Re4 clusters , 1978 .

[63]  E. Diemann.  Radiale Verteilungsfunktionen. IV Zur Struktur der nichtkristallinen Phasen Re2S7 und Re2Se7 , 1977 .

[64]  J. C. Sheldon.  Polynuclear Complexes of Molybdenum(II) , 1959, Nature.

[65]  R. Bell,et al.  Preparation and Characterization of a New Crystalline Form of Molybdenum Disulfide , 1957 .

[66]  N. L. Jarvis,et al.  Rhenium Sulfides as Liquid-Phase Hydrogenation Catalysts. A Comparison with Molybdenum Sulfide and Cobalt Polysulfide , 1954 .