Reactive transport LBM model for CO2 injection in fractured reservoirs

A geochemical LBM model has been developed to simulate the CO 2 injection in homogeneous porous media in our previous work. That model has the ability to investigate the coupled reactive transport processes with reactants and products ions transport, matrix dissolution, and dissolution induced porosity change. In the present work, the model is extended to study the reactive transport properties in "fractured" media. Two kinds of fractures are investigated: one is straightforward along the centerline, and the other is inclined. The reaction rate distribution and evolution are analyzed at different time steps. The dissolution property of fracture edges is also studied, the bottom edge dissolution rate is generally higher than that of the upper edge in inclined fractured media. The porosity change becomes more and more obvious with the increase of time steps, as well as the edge porosity profiles. For the different fracture width, the dissolution rate and edge porosity become higher with the increase of fracture width. All the results show that the present model has the capability to numerically investigate CO 2 injection and reactive transport in fractured reservoirs. HighlightsA LBM model is extended to study the CO2 reactive transport in fractured media.Two different kinds of fractures are involved in numerical cases.The distribution of dissolution rate and porosity are analysed and compared.The wider fracture can cause more intense dissolution and porosity increase.

[1]  Oleg S. Pokrovsky,et al.  Dissolution kinetics of calcite, dolomite and magnesite at 25 °C and 0 to 50 atm pCO2 , 2005 .

[2]  E. W. Llewellin,et al.  LBflow: An extensible lattice Boltzmann framework for the simulation of geophysical flows. Part II: usage and validation , 2010, Comput. Geosci..

[3]  Karsten Pruess,et al.  CO2-H2O mixtures in the geological sequestration of CO2. I. Assessment and calculation of mutual solubilities from 12 to 100°C and up to 600 bar , 2003 .

[4]  Qinjun Kang,et al.  Taxila LBM: a parallel, modular lattice Boltzmann framework for simulating pore-scale flow in porous media , 2014, Computational Geosciences.

[5]  Michael C. Sukop,et al.  Lattice Boltzmann Modeling: An Introduction for Geoscientists and Engineers , 2005 .

[6]  J. Boon The Lattice Boltzmann Equation for Fluid Dynamics and Beyond , 2003 .

[7]  R. Garrels,et al.  Comparative study of the kinetics and mechanisms of dissolution of carbonate minerals , 1989 .

[8]  LATTICE BOLTZMANN METHOD IN SIMULATION OF THERMAL MICRO-FLOW WITH TEMPERATURE JUMP , 2006 .

[9]  Qi Li,et al.  Coupling and Fusion in Modern Geoscience , 2009, Data Sci. J..

[10]  Zhiwei Tian,et al.  LATTICE BOLTZMANN SIMULATION OF GASEOUS FINITE-KNUDSEN MICROFLOWS , 2010 .

[11]  Zhiwei Tian,et al.  Simulation of microchannel flow using the lattice Boltzmann method , 2009 .

[12]  Q. Kang,et al.  Pore-scale study of dissolution-induced changes in permeability and porosity of porous media , 2014 .

[13]  Dongxiao Zhang,et al.  Unified lattice Boltzmann method for flow in multiscale porous media. , 2002, Physical review. E, Statistical, nonlinear, and soft matter physics.

[14]  Huilin Xing,et al.  Lattice Boltzmann modeling and evaluation of fluid flow in heterogeneous porous media involving multiple matrix constituents , 2014, Comput. Geosci..

[15]  Yunliang Tan,et al.  A NUMERICAL STUDY ON PREMIXED MICROCOMBUSTION BY LATTICE BOLTZMANN METHOD , 2012 .

[16]  Qi Li,et al.  Uncertainty analysis of impact indicators for the integrity of combined caprock during CO2 geosequestration , 2015 .

[17]  Zhaoli Guo,et al.  Lattice Boltzmann model for incompressible flows through porous media. , 2002, Physical review. E, Statistical, nonlinear, and soft matter physics.

[18]  D. L. Parkhurst,et al.  User's guide to PHREEQC (Version 2)-a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations , 1999 .

[19]  Yutaka Murakami,et al.  Experimental and numerical study on the fracture of rocks during injection of CO2-saturated water , 2007 .

[20]  Qinjun Kang,et al.  Lattice Boltzmann simulation of chemical dissolution in porous media. , 2002, Physical review. E, Statistical, nonlinear, and soft matter physics.

[21]  K. Pruess,et al.  MODELING MULTIPHASE NON-ISOTHERMAL FLUID FLOW AND REACTIVE GEOCHEMICAL TRANSPORT IN VARIABLY SATURATED FRACTURED ROCKS: 1. METHODOLOGY , 2001 .

[22]  Shiyi Chen,et al.  LATTICE BOLTZMANN METHOD FOR FLUID FLOWS , 2001 .

[23]  B. Metz IPCC special report on carbon dioxide capture and storage , 2005 .

[24]  T. N. Narasimhan,et al.  A PRACTICAL METHOD FOR MODELING FLUID AND HEAT FLOW IN FRACTURED POROUS MEDIA , 1985 .

[25]  David L. Parkhurst,et al.  The kinetics of calcite dissolution in CO 2 -water systems at 5 degrees to 60 degrees C and 0.0 to 1.0 atm CO 2 , 1978 .

[26]  O. Pokrovsky,et al.  Calcite, dolomite and magnesite dissolution kinetics in aqueous solutions at acid to circumneutral pH, 25 to 150 °C and 1 to 55 atm pCO2: New constraints on CO2 sequestration in sedimentary basins , 2009 .

[27]  Qinjun Kang,et al.  Lattice Boltzmann pore-scale model for multicomponent reactive transport in porous media , 2006 .

[28]  E. W. Llewellin,et al.  LBflow: An extensible lattice Boltzmann framework for the simulation of geophysical flows. Part I: theory and implementation , 2010, Comput. Geosci..

[29]  Zhishen Wu,et al.  Thermo-hydro-mechanical Modeling of CO2 Sequestration System Around Fault Environment , 2006 .

[30]  Irina Gaus,et al.  Role and impact of CO2–rock interactions during CO2 storage in sedimentary rocks , 2010 .

[31]  H. Xing,et al.  A coupled lattice Boltzmann model for simulating reactive transport in CO2 injection , 2014 .

[32]  Mohamed Azaroual,et al.  Geochemical and solute transport modelling for CO2 storage, what to expect from it? , 2008 .

[33]  Qi Li Coupled Reactive Transport Model for Heat and Density Driven Flow in CO2 Storage in Saline Aquifers , 2011 .

[34]  M. Dusseault,et al.  Coupled THMC modeling of CO2 injection by finite element methods , 2011 .

[35]  Chuguang Zheng,et al.  Lattice Boltzmann scheme for simulating thermal micro-flow , 2007 .

[36]  Hari S. Viswanathan,et al.  Pore Scale Modeling of Reactive Transport Involved in Geologic CO2 Sequestration , 2010 .

[37]  Zhiwei Tian,et al.  Simulation of thermal micro-flow using lattice Boltzmann method with Langmuir slip model , 2010 .