Wearable alcohol monitoring device with auto-calibration ability for high chemical specificity

Multimodal electrochemical method comprising open circuit potential and amperometric technique has been implemented to improve the specificity of the ethanol detection in a fuel cell sensor system. A miniaturized device with LMP91000 potentiostat and a processing unit has been constructed containing simple auto-calibration algorithm. The developed processing unit consist of a low power microcontroller (MSP430F5529LP). The sensing unit composed of a three electrode proton exchange membrane (PEM) fuel cell sensor, where Nafion is the PEM. In these studies, the signal due to interference has been eliminated with the support of algorithm and multimodal electrochemical method. The results show that the sensor can detect ethanol as low as 5ppm. The constructed device was validated by comparing it with the commercially available potentiostat, and the response was similar in both devices.

[1]  Brent A. Mantooth,et al.  Determination of Ethanol in Alcohol Samples Using a Modular Raman Spectrometer , 2001 .

[2]  Ulrich Stimming,et al.  Model catalyst studies on hydrogen and ethanol oxidation for fuel cells , 2013 .

[3]  R. J. Long,et al.  Validity of transdermal alcohol monitoring: fixed and self-regulated dosing. , 2006, Alcoholism, clinical and experimental research.

[4]  Vladimir Rajs,et al.  Miniature low cost electrochemical sensor module for measurement of gas concentration , 2014, 2014 22nd Telecommunications Forum Telfor (TELFOR).

[5]  Xu Liangfei,et al.  Water management in a self-humidifying PEM fuel cell system by exhaust gas recirculation , 2014, 2014 IEEE Conference and Expo Transportation Electrification Asia-Pacific (ITEC Asia-Pacific).

[6]  James C. Fell,et al.  Transdermal Alcohol Monitoring: Case Studies , 2012 .

[7]  Ahmad Ashrif A Bakar,et al.  Reflectance response of tapered optical fiber coated with graphene oxide nanostructured thin film for aqueous ethanol sensing , 2014 .

[8]  E. Antolini Catalysts for direct ethanol fuel cells , 2007 .

[9]  J. Mercy,et al.  Alcohol use and interpersonal violence: alcohol detected in homicide victims. , 1986, American journal of public health.

[10]  J. H. Lee,et al.  Highly sensitive and selective gas sensors using p-type oxide semiconductors: Overview , 2014 .

[11]  Wojtek Wlodarski,et al.  Nb2O5 Schottky based ethanol vapour sensors : effect of metallic catalysts , 2014 .

[12]  Murthy Chavali,et al.  Performance evaluation of ZnO–CuO hetero junction solid state room temperature ethanol sensor , 2012 .

[13]  Global status report on alcohol and health , 2022 .

[14]  Shinuk Cho,et al.  Synthesis and characterization of an ester-terminated organic semiconductor for ethanol vapor detection , 2014 .