Microstructures and mechanical properties of a welded CoCrFeMnNi high-entropy alloy

ABSTRACT The response of the CoCrFeMnNi high-entropy alloy to weld thermal cycles was investigated to determine its applicability as an engineering structural material. Two processes were used: high-energy-density, low-heat-input electron beam (EB) welding and low-energy-density, high-heat-input gas tungsten arc (GTA) welding. Weldability was determined through comprehensive microstructural and mechanical property characterisation of the welds. The welds did not develop solidification cracking or heat-affected zone cracks. The microstructures in weld fusion zones are similar to that in the as-cast materials, consisting of large columnar grains with dendrite. The dendrite arm spacing and the extent of elemental segregation were less in the welds than in the cast ingot, and also were less pronounced in the EB weld than in the GTA weld. Compositional microsegregation between dendritic cores and interdendritic regions of the welds was insignificant. Both welds exhibited slightly higher yield strengths than the base metal. The EB weld possessed comparable tensile strength and ductility to that of the base metal. In comparison, the GTA weld maintained ∼80% of the base metal’s tensile strength and 50% of the ductility.

[1]  P. Liaw,et al.  Refractory high-entropy alloys , 2010 .

[2]  P. W. Fuerschbach,et al.  On the weldability, composition, and hardness of pulsed and continuous Nd:YAG laser welds in aluminum alloys 6061,5456, and 5086 , 1988 .

[3]  T. DebRoy,et al.  Current Issues and Problems in Welding Science , 1992, Science.

[4]  Nikita Stepanov,et al.  High temperature deformation behavior and dynamic recrystallization in CoCrFeNiMn high entropy alloy , 2015 .

[5]  Louthan,et al.  Fracture Toughness Characterization of 304L and 316L Austenitic Stainless Steels and Alloy 718 After Irradiation in High-Energy, Mixed Proton/Neutron Spectrum , 2001 .

[6]  S. David,et al.  Weldability and hot cracking in thorium-doped iridium alloys , 1980 .

[7]  J. Mazumder,et al.  Control of Magnesium Loss During Laser Welding of Al-5083 Using a Plasma Suppression Technique , 1985 .

[8]  Yanfei Gao,et al.  Thermal activation mechanisms and Labusch-type strengthening analysis for a family of high-entropy and equiatomic solid-solution alloys , 2016 .

[9]  John C. Lippold,et al.  Welding Metallurgy and Weldability , 2014 .

[10]  J. M. Vitek,et al.  Correlation between solidification parameters and weld microstructures , 1989 .

[11]  T. DebRoy,et al.  Mechanism of alloying element vaporization during laser welding , 1987 .

[12]  David T. Read,et al.  Fracture and strength properties of selected austenitic stainless steels at cryogenic temperatures , 1981 .

[13]  E. George,et al.  Tensile properties of high- and medium-entropy alloys , 2013 .

[14]  K. Vecchio,et al.  The influence of stacking fault energy on the mechanical behavior of Cu and Cu-Al alloys: Deformation twinning, work hardening, and dynamic recovery , 2001 .

[15]  Lajos Kator,et al.  Plastic Deformation of Metals , 1953, Nature.

[16]  G. Eggeler,et al.  The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy , 2013 .

[17]  S. Kou,et al.  The effect of quenching on the solidification structure and transformation behavior of stainless steel welds , 1982 .

[18]  Y. Champion,et al.  Insights into the phase diagram of the CrMnFeCoNi high entropy alloy , 2015 .

[19]  L. Rémy Kinetics of f.c.c. deformation twinning and its relationship to stress-strain behaviour , 1978 .

[20]  C. Tasan,et al.  Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off , 2016, Nature.

[21]  W. J. Mills,et al.  Fracture toughness of type 304 and 316 stainless steels and their welds , 1997 .

[22]  S. David,et al.  Welding and weldability of candidate ferritic alloys for future advanced ultrasupercritical fossil power plants , 2013 .

[23]  J. M. Vitek,et al.  Phenomenological Modeling of Fusion Welding Processes , 1994 .

[24]  Gunther Eggeler,et al.  Microstructural evolution of a CoCrFeMnNi high-entropy alloy after swaging and annealing , 2015 .

[25]  J. B. Sande,et al.  Rapid solidification of a droplet-processed stainless steel , 1984 .

[26]  Structural Steels,et al.  Welding Metallurgy of , 1987 .

[27]  J. Lippold Welding Metallurgy and Weldability: Lippold/Welding Metallurgy and Weldability , 2015 .

[28]  K. Nishimoto,et al.  Study on laser surface modification of stainless steels. (Report 1). Effects of rapid solidification by laser surface melting on solidification modes. , 1989 .

[29]  S. K. Kim,et al.  Orientation dependence of twinning and strain hardening behaviour of a high manganese twinning induced plasticity steel with polycrystalline structure , 2011 .

[30]  S. Kalidindi,et al.  Strain hardening regimes and microstructural evolution during large strain compression of low stacking fault energy fcc alloys that form deformation twins , 1997 .

[31]  Robert O. Ritchie,et al.  Nanoscale origins of the damage tolerance of the high-entropy alloy CrMnFeCoNi , 2015, Nature Communications.

[32]  Y. Shindo,et al.  Cryogenic fracture and adiabatic heating of austenitic stainless steels for superconducting fusion magnets , 2003 .

[33]  L. Remy,et al.  Twinning and strain-induced f.c.c. → h.c.p. transformation on the mechanical properties of CoNiCrMo alloys , 1976 .

[34]  D. Raabe,et al.  Dislocation and twin substructure evolution during strain hardening of an Fe-22 wt.% Mn-0.6 wt.% C TWIP steel observed by electron channeling contrast imaging , 2011 .

[35]  T. Nieh,et al.  In-situ neutron diffraction study of deformation behavior of a multi-component high-entropy alloy , 2014 .

[36]  G. Lesoult,et al.  Influence des conditions de solidification sur le déroulement de la solidification des aciers inoxydables austénitiques , 1988 .

[37]  Jacob L. Jones,et al.  Entropy-stabilized oxides , 2015, Nature Communications.

[38]  J. Yeh,et al.  Wear resistance and high-temperature compression strength of Fcc CuCoNiCrAl0.5Fe alloy with boron addition , 2004 .

[39]  H. Bei,et al.  Nano-twin Mediated Plasticity in Carbon-containing FeNiCoCrMn High Entropy Alloys , 2015 .

[40]  G. M. Stocks,et al.  Tailoring the physical properties of Ni-based single-phase equiatomic alloys by modifying the chemical complexity , 2016, Scientific Reports.

[41]  A. Block-bolten,et al.  Metal vaporization from weld pools , 1984 .

[42]  M. Grossbeck Effects of radiation on materials : 21th international symposium , 2001 .

[43]  B. Cantor,et al.  Microstructural development in equiatomic multicomponent alloys , 2004 .

[44]  H. W. Kerr,et al.  Grain structures in aluminum alloy GTA welds , 1980 .

[45]  G. Pharr,et al.  Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures , 2014 .

[46]  Stan A David,et al.  Physical processes in fusion welding , 1995 .

[47]  J. Yeh,et al.  In-situ neutron diffraction studies on high-temperature deformation behavior in a CoCrFeMnNi high entropy alloy , 2015 .

[48]  R. Ritchie,et al.  A fracture-resistant high-entropy alloy for cryogenic applications , 2014, Science.

[49]  T. Shun,et al.  Nanostructured High‐Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes , 2004 .

[50]  Bernd Gludovatz,et al.  Exceptional damage-tolerance of a medium-entropy alloy CrCoNi at cryogenic temperatures , 2016, Nature Communications.

[51]  T. DebRoy,et al.  Alloying element vaporization and weld pool temperature during laser welding of AlSl 202 stainless steel , 1984 .

[52]  G. M. Stocks,et al.  Thermophysical properties of Ni-containing single-phase concentrated solid solution alloys , 2017 .

[53]  J. M. Vitek,et al.  Microstructural modification of austenitic stainless steels by rapid solidification , 1983 .

[54]  S. Kou,et al.  Alternating grain orientation and weld solidification cracking , 1985 .

[55]  S. David,et al.  Grain refinement in castings and welds : proceedings of a symposium , 1983 .

[56]  Zhili Feng,et al.  Weldability of a high entropy CrMnFeCoNi alloy , 2016 .

[57]  Priti Wanjara,et al.  Hybrid fiber laser – Arc welding of thick section high strength low alloy steel , 2011 .

[58]  Dann. E. Passoja,et al.  The effect of heat treatment on microstructure and cryogenic fracture properties in 5Ni and 9Ni steel , 1980 .

[59]  C. Syn,et al.  Cryogenic fracture toughness of 9Ni steel enhanced through grain refinement , 1976 .