Inventory of fine particulate organic compound emissions from residential wood combustion in Portugal.

Abstract In the early fall of 2010 a survey questionnaire was conducted to assess residential wood combustion (RWC) practices in the 18 districts of mainland Portugal. This paper describes and analyses the results from a bottom-up approach, based on this telephone survey, which enabled the characterisation of RWC practices in each district. Additionally, emission factors and source profiles obtained from different RWC tests, allowed the estimation of CO, CO2, PM2.5 and particulate organic compound emissions on a country-scale. The type and number of RWC appliances, each with their specific emissions factor and the amount and type of fuel used vary significantly on a district scale. The energy consumption in RWC appliances was estimated to be 35 342 TJ y−1. The estimated emissions of PM2.5 from RWC in Portugal (10.96 kt y−1) represent 30% of the estimate for different source activities reported in a recent inventory. The national emissions of OC and EC were estimated to be 5.32 and 0.53 kt y−1, respectively. It was also estimated that the total CO2 emissions from RWC in Portugal are 1.7 Mt y−1. The levoglucosan emissions contribute with between 7.8% and 16.1% of PM2.5 emissions from RWC.

[1]  G. Cass,et al.  Chemical Characterization of Fine Particle Emissions from the Wood Stove Combustion of Prevalent United States Tree Species , 2004 .

[2]  Maria Helena de Aguiar Pereira e Pestana,et al.  Análise de Dados para Ciências Sociais: a Complementaridade do SPSS , 2008 .

[3]  G R Cass,et al.  Measurement of emissions from air pollution sources. 3. C1-C29 organic compounds from fireplace combustion of wood. , 2001, Environmental science & technology.

[4]  P. Dilara,et al.  Importance of activity data for improving the residential wood combustion emission inventory at regional level , 2011 .

[5]  Alexandre Caseiro,et al.  Chemical characterisation of fine particle emissions from wood stove combustion of common woods growing in mid-European Alpine regions , 2008 .

[6]  Margarita Evtyugina,et al.  Characterisation of PM10 emissions from woodstove combustion of common woods grown in Portugal , 2010 .

[7]  Alexandre Caseiro,et al.  Source apportionment of PM2.5 organic aerosol over Europe: Primary/secondary, natural/anthropogenic, and fossil/biogenic origin , 2007 .

[8]  J. Lelieveld,et al.  The Indian Ocean Experiment: Widespread Air Pollution from South and Southeast Asia , 2001, Science.

[9]  L. Morawska,et al.  Quantification of particle number and mass emission factors from combustion of Queensland trees. , 2006, Environmental science & technology.

[10]  B. Duncan,et al.  Vegetation fire emissions and their impact on air pollution and climate , 2009 .

[11]  Ana Isabel Miranda,et al.  Contribution of residential wood combustion to PM10 levels in Portugal , 2010 .

[12]  J S Lighty,et al.  Combustion Aerosols: Factors Governing Their Size and Composition and Implications to Human Health , 2000, Journal of the Air & Waste Management Association.

[13]  José Lousada,et al.  The explained variation by lignin and extractive contents on higher heating value of wood , 2011 .

[14]  Organic compounds in biomass smoke from residential wood combustion: Emissions characterization at a continental scale , 2002 .

[15]  P. Eng CO2 emissions from fuel combustion: highlights , 2009 .

[16]  Jennica Kjällstrand,et al.  Chimney emissions from small-scale burning of pellets and fuelwood - examples referring to different combustion appliances , 2004 .

[17]  C. Alves Characterisation of solvent extractable organic constituents in atmospheric particulate matter: an overview , 2008 .

[18]  L. Tarelho,et al.  Organic compounds in PM2.5 emitted from fireplace and woodstove combustion of typical Portuguese wood species , 2011 .

[19]  Alexandre Caseiro,et al.  Levoglucosan levels at background sites in Europe for assessing the impact of biomass combustion on the European aerosol background , 2007 .

[20]  Joakim Pagels,et al.  Health effects of residential wood smoke particles: the importance of combustion conditions and physicochemical particle properties , 2009, Particle and Fibre Toxicology.

[21]  S. Hawthorne,et al.  Identification of methoxylated phenols as candidate tracers for atmospheric wood smoke pollution. , 1988, Environmental science & technology.

[22]  Tami C. Bond,et al.  Light absorption by organic carbon from wood combustion , 2007 .

[23]  C. Johansson,et al.  Contribution of residential wood combustion and other sources to hourly winter aerosol in Northern Sweden determined by positive matrix factorization , 2008 .

[24]  Christoph Hueglin,et al.  Source apportionment of submicron organic aerosols at an urban site by factor analytical modelling of aerosol mass spectra , 2007 .

[25]  Allen L Robinson,et al.  Effects of dilution on fine particle mass and partitioning of semivolatile organics in diesel exhaust and wood smoke. , 2006, Environmental science & technology.

[26]  L. Tarelho,et al.  Fireplace and woodstove fine particle emissions from combustion of western Mediterranean wood types , 2011 .

[27]  Z. Klimont,et al.  Primary Emissions of Submicron and Carbonaceous Particles in Europe and the Potential for their Control , 2004 .

[28]  Christopher G. Nolte,et al.  Levoglucosan, a tracer for cellulose in biomass burning and atmospheric particles , 1999 .

[29]  S. Monni Uncertainties in the Finnish 2002 Greenhouse Gas Emission Inventory , 2004 .

[30]  H. Bauer,et al.  Emission factors from residential combustion appliances burning Portuguese biomass fuels. , 2011, Journal of environmental monitoring : JEM.

[31]  G R Cass,et al.  Chemical characterization of fine particle emissions from fireplace combustion of woods grown in the northeastern United States. , 2001, Environmental science & technology.

[32]  B. Simoneit,et al.  Organic matter of the troposphere — V: Application of molecular marker analysis to biogenic emissions into the troposphere for source reconciliations , 1989 .