E.F.R and Spectroscopic Studies of Cu(3-Piooline)2(N3)2 Crystal

Abstract EPR, UV-Vie, and IR measurements were performed to determine the molecular structure of Cu(3-picoline)2(N3)2 in solid state. Single crystal EPR spectra indicate non-coupled copper (I1) complexes with gn = 2.265 and g⊥ = 2.056. A binuclear complex structure is suggested with end-to-end azido copper (I1) bibridges which are not optimiaed for exchange coupling transmission.

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