论文信息 - Electronic States of the 4,4′-Dinitrobiphenyl–Benzidine Complex

Electronic States of the 4,4′-Dinitrobiphenyl–Benzidine Complex

The charge transfer complex composed of 4,4′-dinitrobiphenyl and benzidine was studied by measuring and analyzing the UV crystalline spectra. The deep coloration of this complex was found to be due to the charge transfer bands appearing at 21000 and 25000 cm−1, while the long axes of the component molecules are known to be perpendicular to each other.

Masashi Tanaka

[1] G. Saito,et al. Diffuse Reflection Spectra of Some Dinitrobiphenyl Complexes , 1968 .

[2] D. Roessler,et al. Kramers-Kronig analysis of reflection data , 1965 .

[3] H. J. Bowlden,et al. Evaluation of the One-Angle Reflection Technique for the Determination of Optical Constants , 1963 .

[4] D. H. Saunder. The crystal structure of some molecular complexes of 4:4'-dinitrodiphenyl II. The complexes with benzidine, NN:N'N'-tetramethylbenzidine, 4:4'-dihydroxydiphenyl, 4-iododiphenyl and 4-bromodiphenyl , 1947, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.