Demonstration of Experimental Infrastructure for Studying Cell-to-Cell Failure Propagation in Lithium-Ion Batteries

Abstract : A 5 cubic meter decompression chamber was repurposed as a test chamber to conduct failure abuse experiments on commercial 18650-type lithium-ion batteries. Various modifications were performed to enable remote control and monitoring of chamber functions, along with collection of data from instrumentation during tests including high speed and infrared cameras, a Fourier transform infrared spectrometer, real-time gas analyzers, and compact reconfigurable input and output devices. Single- and multi-cell packages of LiCoO2 and LiFePO4 chemistry 18650 lithium-ion batteries were constructed and data was obtained and analyzed for abuse and failure tests. Observations from recorded camera videos, thermocouples, heat flux gauges, and gas analyses revealed qualitative insights into failure mechanisms and heat propagation from cell to cell. Future directions based on these observations are also proposed.

[1]  Dinh Vinh Do,et al.  Thermal modeling of a cylindrical LiFePO4/graphite lithium-ion battery , 2010 .

[2]  K. Smith Battery Thermal Modeling and Testing (Presentation) , 2011 .

[3]  W. Bessler,et al.  Low-temperature charging of lithium-ion cells part I: Electrochemical modeling and experimental investigation of degradation behavior , 2014 .

[4]  Dmitry Belov,et al.  Investigation of the kinetic mechanism in overcharge process for Li-ion battery , 2008 .

[5]  T. P. Kumar,et al.  Safety mechanisms in lithium-ion batteries , 2006 .

[6]  Karen E. Swider-Lyons,et al.  Impedance Diagnostic for Overcharged Lithium-Ion Batteries , 2012 .

[7]  Daniel Hoffpauir NASA Engineering and Safety Center (NESC) , 2015 .

[8]  K. S. Nanjundaswamy,et al.  Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium Batteries , 1997 .

[9]  T. Fuller,et al.  A Critical Review of Thermal Issues in Lithium-Ion Batteries , 2011 .

[10]  Patricia A. Tatem,et al.  User Manual for Graphical User Interface Version 2.10 with Fire and Smoke Simulation Model (FSSIM) Version 1.2 , 2006 .

[11]  Nigel P. Brandon,et al.  Coupled thermal–electrochemical modelling of uneven heat generation in lithium-ion battery packs , 2013 .

[12]  Jason B. Siegel,et al.  A lumped-parameter electro-thermal model for cylindrical batteries , 2014 .

[13]  Ahmad Pesaran,et al.  Overview of Computer-Aided Engineering of Batteries and Introduction to Multi-Scale, Multi-Dimensional Modeling of Li-Ion Batteries (Presentation) , 2012 .